首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1111篇
  免费   159篇
  国内免费   181篇
测绘学   100篇
大气科学   173篇
地球物理   312篇
地质学   442篇
海洋学   182篇
天文学   115篇
综合类   66篇
自然地理   61篇
  2024年   7篇
  2023年   27篇
  2022年   65篇
  2021年   55篇
  2020年   36篇
  2019年   49篇
  2018年   18篇
  2017年   23篇
  2016年   60篇
  2015年   32篇
  2014年   52篇
  2013年   36篇
  2012年   52篇
  2011年   63篇
  2010年   54篇
  2009年   64篇
  2008年   83篇
  2007年   53篇
  2006年   55篇
  2005年   73篇
  2004年   55篇
  2003年   67篇
  2002年   36篇
  2001年   34篇
  2000年   53篇
  1999年   43篇
  1998年   28篇
  1997年   40篇
  1996年   12篇
  1995年   31篇
  1994年   25篇
  1993年   15篇
  1992年   16篇
  1991年   1篇
  1990年   9篇
  1989年   4篇
  1988年   7篇
  1987年   2篇
  1986年   1篇
  1985年   4篇
  1984年   5篇
  1981年   2篇
  1980年   3篇
  1976年   1篇
排序方式: 共有1451条查询结果,搜索用时 31 毫秒
1.
2.
This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.
Luigi Marini (Corresponding author)Email:
  相似文献   
3.
Klauea historical summit lavas have a wide range in matrix 18OVSMOWvalues (4·9–5·6) with lower values in rockserupted following a major summit collapse or eruptive hiatus.In contrast, 18O values for olivines in most of these lavasare nearly constant (5·1 ± 0·1). The disequilibriumbetween matrix and olivine 18O values in many samples indicatesthat the lower matrix values were acquired by the magma afterolivine growth, probably just before or during eruption. BothMauna Loa and Klauea basement rocks are the likely sources ofthe contamination, based on O, Pb and Sr isotope data. However,the extent of crustal contamination of Klauea historical magmasis probably minor (< 12%, depending on the assumed contaminant)and it is superimposed on a longer-term, cyclic geochemicalvariation that reflects source heterogeneity. Klauea's heterogeneoussource, which is well represented by the historical summit lavas,probably has magma 18O values within the normal mid-ocean ridgebasalt mantle range (5·4–5·8) based on thenew olivine 18O values. KEY WORDS: Hawaii; Klauea; basalt; oxygen isotopes; crustal contamination  相似文献   
4.
一种新的波浪变形三维数值模式──0-1混合型边界元   总被引:4,自引:0,他引:4  
为提高边界元法模拟三维波场波浪变形的数值计算精度,借鉴常数元和线性元剖分方式、波势函数及波势函数法向导数对单元节点设定的各自适应性,提出了一种新的单元剖分模式──0-1混合型边界元,以控制和减缓由于计算误差累计而造成的波浪数值计算上的“横向振动”,借此结合边界元法的分区模式可实现较大范围的波场线性波浪变形计算,并为时域内的波浪非线性变形计算提供时间步长的数值保证.  相似文献   
5.
The numerical mode of nonlinear wave transformation based on both the Laplace equation for water field and the Bemoulli equation for water surface is a kind of time-domain boundary problem with initial conditions. And the basis for establishing the numerical mode of nonlinear wave in time domain is to trace the position of wave free surface and to calculale the instantaneous surface height and surface potential function. This paper firstly utilizes the ‘0-1‘ combined BEM to separate the boundary by means of discretization of Green‘ s integral equation based on the Laplace equation, then separates the free surface of wave with FEM and derives the FEM equation of wave surface that satisfies the nonlinear boundary conditions. By jointly solving the above BEM and FEM equations, the wave potential and surface height could be obtained with iteration in time domain. Thus a new kind of nonlinear numerical mode is established for calculating wave transformation. The wave test in the numerical wave tank shows that the numerical simulation with this mode is of high accuracy.  相似文献   
6.
以1,4—苯二酚和不同的短链脂肪酸为基本原料,经溴代、加成、形成酰卤和酰化等反应,合成了六种新的溴化脂肪酸—2,3,5,6—四溴—1,4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析,以及红外吸收光谱和氢核磁共振谱的研究,验证了化合物的结构。  相似文献   
7.
Samples of O isotopic tracer were mlleMed at Sections P3,P25,PcM-t/2-E and PCM-1/2.w in both the Fast China Sea and the area to the east of the Ryūkyū-gunto during October-November,1991.Analytical results of the δ18O are as follows: (1) In the Kuroshio area,the δ18O isolines are almost parallel to the 200 m isobath.The value of δ18O is negative and reaches minimum mt the main axis of the Kuroshio,and increases on both sides.(2) In the Taiwan Warm Current (TWC) area there is a high δ18O tongue extending to the northeast.(3) In the area near the coast,the distribution of δ18O isoline shows that the Changjiang River runoff diffuses seaward and the land-ocean isotopic effect from the nearshore to the offshore.(4) The values of δ18O are from -1.0×10-3 to -0.5×10-3 in the shelf.(5) There is a low mre of δ18O value(<-1.6×10-3) at the 600 m layer in the Kuroshio area,which is quite in accord with the existence of a low salinity mre (S G 34.30) between the 600 and 800 m layers in the same area.Finally,the mrrelations of the δ18O with the salinity and temperature,the upwelling and so on are discussed.  相似文献   
8.
用6-DMAP抑制受精卵第二极体排放的方法诱导缢蛏三倍体的试验.结果表明:6-DMAP在100~500μmol/dm^3处理浓度范围内均可以诱导出三倍体,随着药物处理浓度和处理时间的提高,三倍体倍化率和D形幼虫畸形率有不同程度的提高,而D形幼虫孵化率会随之下降.综合来看,在30%卵子受精并出现第一极体,6-DMAP浓度为300μmol/dm^3和处理持续时间为20min时的处理组的处理效果优于其他处理组组合.  相似文献   
9.
不同生长期坛紫菜多糖中组分含量的变化   总被引:3,自引:0,他引:3  
于1990-1991年,运用^13C-NMR和化学分析方法研究南方产和移植北方养殖的不同生长发育阶段坛紫菜多糖的组分变化,结果表明,随着藻体生长发育,坛紫菜琼胶中3,6-内醚-L-半乳糖和6-OCH3-D-半乳糖的含量逐渐增加,而硫酸基的含量呈现先增加后减少的规律;北移坛紫菜琼胶中3,6-内醚-L-半乳糖的含量高于南方坛紫菜,而硫酸基和6-OCH3-D-半乳糖的含量低于南方坛紫菜。  相似文献   
10.
用m-氨基苯甲酸作原料,经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤,合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯,即;双(2,4,6-三溴苯甲酸)-2',3',5',6'-四溴-1',4'-苯二酯,2,4,6-三溴苯甲酸-2',3',4',5',6'-五溴苯酯,2,4,6-三溴苯甲酸-2',4',6'-三溴苯酯,2,4,6-三溴苯甲酸-4'-溴苯酯,2,4,6-三溴苯甲酸-4'-甲基苯酯和2,4,6-三溴苯甲酸苯酯.通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究,验证了合成产物的结构。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号