首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   580篇
  免费   95篇
  国内免费   89篇
测绘学   23篇
大气科学   18篇
地球物理   88篇
地质学   539篇
海洋学   8篇
综合类   57篇
自然地理   31篇
  2024年   1篇
  2023年   1篇
  2022年   8篇
  2021年   11篇
  2020年   12篇
  2019年   11篇
  2018年   9篇
  2017年   21篇
  2016年   15篇
  2015年   14篇
  2014年   34篇
  2013年   28篇
  2012年   32篇
  2011年   39篇
  2010年   32篇
  2009年   46篇
  2008年   53篇
  2007年   45篇
  2006年   43篇
  2005年   29篇
  2004年   26篇
  2003年   29篇
  2002年   30篇
  2001年   23篇
  2000年   26篇
  1999年   20篇
  1998年   13篇
  1997年   17篇
  1996年   15篇
  1995年   9篇
  1994年   8篇
  1993年   8篇
  1992年   8篇
  1991年   4篇
  1990年   5篇
  1989年   4篇
  1988年   4篇
  1987年   5篇
  1986年   5篇
  1985年   6篇
  1984年   9篇
  1983年   2篇
  1982年   1篇
  1980年   1篇
  1978年   1篇
  1976年   1篇
排序方式: 共有764条查询结果,搜索用时 31 毫秒
1.
Coal seams burning underneath the surface are recognized all over the world and have drawn increasing public attention in the past years. Frequently, such fires are analyzed by detecting anomalies like increased exhaust gas concentrations and soil temperatures at the surface. A proper analysis presumes the understanding of involved processes, which determine the spatial distribution and dynamic behavior of the anomalies.In this paper, we explain the relevance of mechanical and energy transport processes with respect to the occurrence of temperature anomalies at the surface. Two approaches are presented, aiming to obtain insight into the underground coal fire situation: In-situ temperature mapping and numerical simulation. In 2000 to 2005, annual temperature mapping in the Wuda (Inner Mongolia, PR China) coal fire area showed that most thermal anomalies on the surface are closely related to fractures, where hot exhaust gases from the coal fire are released. Those fractures develop due to rock mechanical failure after volume reduction in the seams. The measured signals at the surface are therefore strongly affected by mechanical processes.More insight into causes and effects of involved energy transport processes is obtained by numerical simulation of the dynamic behavior of coal fires. Simulations show the inter-relation between release and transport of thermal energy in and around underground coal fires. Our simulation results show a time delay between the coal fire propagation and the observed appearance of the surface temperature signal. Additionally, the overall energy flux away from the burning coal seam into the surrounding bedrock is about 30-times higher than the flux through the surface. This is of particular importance for an estimation of the energy released based on surface temperature measurements. Finally, the simulation results also prove that a fire propagation rate estimated from the interpretation of surface anomalies can differ from the actual rate in the seam.  相似文献   
2.
Supercritical gas sorption on moist coals   总被引:2,自引:1,他引:1  
The effect of moisture on the CO2 and CH4 sorption capacity of three bituminous coals from Australia and China was investigated at 55 °C and at pressures up to 20 MPa. A gravimetric apparatus was used to measure the gas adsorption isotherms of coal with moisture contents ranging from 0 to about 8%. A modified Dubinin–Radushkevich (DR) adsorption model was found to fit the experimental data under all conditions. Moisture adsorption isotherms of these coals were measured at 21 °C. The Guggenheim–Anderson–de Boer (GAB) model was capable of accurately representing the moisture isotherms over the full range of relative pressures.Moist coal had a significantly lower maximum sorption capacity for both CO2 and CH4 than dry coal. However, the extent to which the capacity was reduced was dependent upon the rank of the coal. Higher rank coals were less affected by the presence of moisture than low rank coals. All coals exhibited a certain moisture content beyond which further moisture did not affect the sorption capacity. This limiting moisture content was dependent on the rank of the coal and the sorbate gas and, for these coals, corresponded approximately to the equilibrium moisture content that would be attained by exposing the coal to about 40–80% relative humidity. The experimental results indicate that the loss of sorption capacity by the coal in the presence of water can be simply explained by volumetric displacement of the CO2 and CH4 by the water. Below the limiting moisture content, the CO2 sorption capacity reduced by about 7.3 kg t− 1 for each 1% increase in moisture. For CH4, sorption capacity was reduced by about 1.8 kg t− 1 for each 1% increase in moisture.The heat of sorption calculated from the DR model decreased slightly on addition of moisture. One explanation is that water is preferentially attracted to high energy adsorption sites (that have high energy by virtue of their electrostatic nature), expelling CO2 and CH4 molecules.  相似文献   
3.
Composition and quality of coals in the Huaibei Coalfield, Anhui, China   总被引:3,自引:0,他引:3  
The Huaibei Coalfield, Anhui Province, China, is one of the largest coalfields in China. The coals of Permian age are used mainly for power generation. Coal compositions and 47 trace elements of the No. 10 Coal of the Shanxi Formation, the No. 7, 5, and 4 Coals of the Lower Shihezi Formation, and the No. 3 Coal of the Upper Shihezi Formation from the Huaibei Coalfield were studied. The results indicate that the Huaibei coals have low ash, moisture, and sulfur contents, but high volatile matter and calorific value. The ash yield increases stratigraphically upwards, but the volatile matter and total sulfur contents show a slight decrease from the lower to upper seams. Magmatic intrusion into the No. 5 Coal resulted in high ash, volatile matter, and calorific value, but low moisture value in the coal. Among the studied 47 trace elements, Ba, Co, Cr, Cu, Hg, Mo, Ni, Pb, Sb, Th, U, V, and Zn are of environmental concerns. Four elements Hg, Mo, Zn, and Sb are clearly enriched in the coals as compared with the upper continental crust.  相似文献   
4.
西气东输天然气管道工程途经兖州市,穿越杨庄、杨村、兴隆庄等煤矿矿区,压覆煤层埋深变化较大。该文采用预测法对各煤矿在不同开采条件下分煤层对管道运营安全的危害程度进行了评价分析。通过计算表明,煤矿开采埋深越浅,煤层越厚,对管道危害越严重。兴隆庄煤矿3煤层、杨村煤矿煤16t、煤17开采对管道影响强烈,杨庄煤矿煤16t、煤17开采对管道影响中等,兴隆庄煤矿煤16t、煤17开采对管道运营影响小。  相似文献   
5.
含煤层地质环境下地震波场的数值模拟   总被引:3,自引:2,他引:1  
本文对含低速煤层地质环境下弹性波场多波多分量地震资料进行了二维数值模拟研究,对人工边界反射进行了有效处理,频散效应得到了有效的压制,对几种不同激发与观测排列方式下的弹性波资料进行了模型计算与分析。  相似文献   
6.
尹红美  魏永齐 《地下水》2005,27(3):198-199
濮阳市是新兴的石油化工基地,国家级卫生城市和园林城市,由于人口的增长、工农业的迅猛发展,地下水超量开采而引起的地面沉降、地裂缝等一系列环境地质问题,针对所出现的环境地质问题提出相应的防治措施.  相似文献   
7.
Controls on coal metamorphism can be complex. In this paper, we examine four Paleozoic coalfields: the western Kentucky portion of the Illinois Basin, the Pennsylvania anthracite fields, the South Wales Coalfield, and the Bowen Basin. An increase in temperature with depth of burial is certainly a factor in coal metamorphism. In many coalfields, however, including the coalfields reviewed here, it has become apparent that such a simple mechanism does not explain the coal rank patterns observed. The flow of hydrothermal fluids through the coals has been proposed as a cause of coal metamorphism. Evidence includes inverted rank gradients, elevated CFL as an indicator of brine fluids, isotopic evidence for hydrothermal fluids, and vein and cleat mineral assemblages. In any case, multiple hypotheses must often be evaluated in the examination of any coalfield since the simple paradigm of coal rank increases with a simple increase in temperature with increasing depth does not fit the evidence observed in many cases.  相似文献   
8.
明邵军 《湖南地质》2002,21(3):207-210
华容县注滋口大桥12#墩钻孔灌注桩工程条件极差,经多种方法试验,最后采用了经济合理的冲击与回旋相结合的处理措施,成功地解决了上部大厚度、大体积的块石层及下部砂砾层整体失稳等技术难题。  相似文献   
9.
Mine development along a 15-mile (24 km) section of the Warfield Fault in Mingo County, West Virginia has broadened the geological understanding of the fault and its related structures. The fault has been exposed in two new road cuts, one in the northeast-trending segment at Neely Branch and one in the eastern east-trending segment at the head of Marrowbone Creek. Both exposures show a well-defined normal fault with a 45° to 55° N dip, juxtaposing sandstone/shale packages from the roof and the floor of the Coalburg seam. The fault is associated with a thin gouge zone, some drag folding, and parallel jointing. Its trace tends to run parallel to the crest of the adjacent Warfield Anticline. Based on underground mine development and detailed core drilling, the vertical offset along the fault plane ranges from a maximum of 240 ft (73 m) in the central part of the area near the structural bend to less than 100 ft (30 m) in western and eastern directions. The fault is located along the relatively steeply dipping (locally in excess of 25%) southern limb of the Warfield Anticline, and appears related to a late phase of extension involving folded Pennsylvanian strata. On a regional scale, the lithological variations across the fault do not suggest any appreciable strike-slip component.Underground room and pillar mines in the Coalburg seam north and south of the fault have been greatly impacted by the Warfield structures. Due to the combined (and opposite) effects of the folding and faulting, the northern mines are located up to 400 ft (125 m) higher in elevation than the southern ones. Overland conveyor belts connect mining blocks separated by the fault. The practical mining limit along the steep slopes toward the fault is around 15%. Subsidiary normal faults with offsets in the 5- to 15-ft (1.5–4.5 m) range are fairly common and form major roof control and production hurdles. Overall, the Warfield structures pose an extra challenge to mine development in this part of the Appalachian Coalfields.  相似文献   
10.
The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (St,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe+ (54Fe+, 56Fe+, 57Fe+), other fragment ions were detected in bacteriogenic pyrites, such as 27Al+, Si+ (28Si+, 29Si+, 30Si+), 40Ca+, Cu+ (63Cu+, 65Cu+), Zn+ (64Zn+, 66Zn+, 67Zn+, 68Zn+), Ni+ (58Ni+, 60Ni+, 62Ni+), and C3H7+. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as 27Al+, 28Si+, 29Si+, AlO+, CH2+, C3H3+, C3H5+, and C4H7+, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of 28Si+ and 27Al+ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest 28Si+/23Na+ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C3H3+, C3H5+, C3H7+, and C4H7+, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P+ peak was observed only in the fracture-filling pyrite and the highest 28Si+/23Na+ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger 40Ca+ in nodular pyrite than other pyrite forms shows seawater influence during its formation.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号