Theoretical and experimental lifetime and oscillator strength determination in singly ionized neodymium (Nd ii)     

H. L. Xu  S. Svanberg  R. D. Cowan  P.-H. Lefèbvre  P. Quinet  E. Biémont 《Monthly notices of the Royal Astronomical Society》2003,346(2):433-440

Radiative lifetime measurements were performed with time-resolved laser-induced fluorescence techniques for 24 levels of Nd  ii in the energy range 20 500–32 500 cm⁻¹. For 17 levels, no previous experimental data exist. These results have allowed the testing of new theoretical calculations with the relativistic Hartree–Fock method taking configuration interactions and core-polarization effects into account, and a satisfying agreement has been found for this complex ion. A new set of calculated oscillator strengths, accurate within a few per cent for the strongest transitions, is presented for 107 lines of astrophysical interest appearing in the wavelength range 358.0–1100.0 nm. These results will be useful to evaluate abundance values of neodymium in chemically peculiar stars in relation with cosmochronology.  相似文献   

The electron pressure in the outer atmosphere of ε Eri (K2 V)     

C. Jordan  S.A. Sim  A.D. McMurry  M. Aruvel 《Monthly notices of the Royal Astronomical Society》2001,326(1):303-312

Observations of ε Eri (K2 V) have been made with the Space Telescope Imaging Spectrograph on the Hubble Space Telescope . The spectra obtained show a number of emission lines which can be used to determine, or place limits on, the electron density and pressure. Values of the electron pressure are required in order to make quantitative models of the transition region and inner corona from absolute line fluxes, and to constrain semi-empirical models of the chromosphere. Using line flux ratios in Si  iii and O  iv a mean electron pressure of P _e= N _e T _e=4.8×10¹⁵ cm⁻³ K is derived. This value is compatible with the lower and upper limits to P _e found from flux ratios in C  iii , O  v and Fe  xii . Some inconsistencies which may be because of small uncertainties in the atomic data used are discussed.  相似文献   

Effective collision strengths with inclusion of resonance for hyperfine-structure transitions in H- and Li-like ions     

Hong Lin Zhang  Douglas H. Sampson 《Monthly notices of the Royal Astronomical Society》2001,322(3):433-437

Calculations are made of the resonance contribution to electron-impact excitation of H-like ¹³C and Li-like ²³Na, ²⁵Mg, ²⁷Al and ²⁹Si to the upper hyperfine levels that produce millimetre (mm) lines of likely astrophysical interest. The resonance contribution is found to be very important for these Li-like ions, considerably more important than for Li-like ⁵⁷Fe considered previously. However, resonances are found to be rather unimportant for H-like ¹³C. The effect of radiative decay on the resonance contribution is found to be insignificant in all of the present calculations.  相似文献   

雾化进样石墨炉原子吸收光谱法的研究 Ⅰ.直接雾化进样装置及其性能     

侯书恩  常诚 《岩矿测试》1993,(1)

介绍一种自行设计和加工的直接雾化石墨炉进样装置的结构、工作原理和操作方法。该装置由微机控制与石墨炉加热程序同步工作,可以实现自动控制和自动测量。对雾化进样石墨炉分析的仪器参数和实验条件进行了研究和选择。结果表明,该装置与石墨炉结合具有自动化程度高、重现性好、样品利用率高和分析速度快等特点。  相似文献   

Radiative association in Li+H revisited: the role of quasi-bound states     

O. J. Bennett  A. S. Dickinson  T. Leininger  F. X. Gadéa 《Monthly notices of the Royal Astronomical Society》2003,341(1):361-368

The role in radiative association of narrow resonances arising from quasi-bound levels is examined. For the rate coefficient the contribution from such levels is readily calculated in terms of the Einstein A -coefficient from bound rovibrational levels generated using a suitable alternative boundary condition. By locating systematically all the quasi-bound levels, an enhancement by more than an order of magnitude of the rate coefficient for Li(2s) + H(1s) association above about 600 K is obtained. The effect on the LiH abundance in the early Universe is no more than an increase of a factor of 3 for limited ranges of values of the redshift. For the Li(2p) state the effect of narrow resonances appears to have been taken into account in previous calculations.  相似文献   

Distance estimate and progenitor characteristics of SN 2005cs in M51     

K. Takáts  J. Vinkó 《Monthly notices of the Royal Astronomical Society》2006,372(4):1735-1740

We present the excitation energies and lifetimes for the  3 s 3 p 3 d  ⁴ F  _7/2,9/2  levels for five aluminium-like ions of the iron group. Apart from the wavelengths, this also includes the transition probabilities and branching ratios for the electric-dipole allowed (E1) and forbidden (M1, E2, M2) lines into the energetically lower lying levels of the  3 s ²3 d , 3 s 3 p ²  and  3 s 3 p 3 d   configurations. Applying systematically enlarged multiconfiguration Dirac–Fock (MCDF) wavefunctions, here the effects of relativity and the electron–electron correlation are treated within the same (computational) model.  相似文献   

On the influence of magnetic fields on level populations     

Z. Q. Qu  C. L. Xu  X. Y. Zhang  X. L. Yan  C. L. Jin 《Monthly notices of the Royal Astronomical Society》2006,370(4):1790-1796

The influence of magnetic fields on the energy level populations of atoms is firstly studied by analysing the Stokes profiles of Fe  i 6302.5 forming in the solar magnetized atmosphere, with the aid of a departure factor defined to evaluate the deviation from the normal Boltzmann distribution without a magnetic field. This factor is directly related to the ratio of line-source function to the continuum one. The relationship between the departure and the magnetic field reveals an effect that the magnetic field induces an exponential increase in the level population of the lower level of Fe  i 6302.5 (Landé factor   g = 2.5  ) with the field strength. This indicates that the magnetic field can cause the redistribution of populations of those levels whose Landé factors are non-zero. Therefore, this effect should be included in the calculation of the statistical equilibrium. Secondly, an experiment utilizing the Hg5461 line in the laboratory on the Earth is carried out to reveal that the exponential relation is independent of variations in temperature, and the excitation is completely magneto-induced. Finally, the exponential relation is explained by taking account of the magnetic energy in the Boltzmann distribution.  相似文献   

Measurement of radiative lifetimes and determination of transition probabilities of astrophysical interest in Ho iii     

E. Biémont  P. Palmeri  P. Quinet  G. Paquin  Z. G. Zhang  G. Somesfalean  S. Svanberg 《Monthly notices of the Royal Astronomical Society》2001,328(4):1085-1090

Lifetimes of six levels belonging to the 4f¹⁰6p configuration of Ho  iii have been measured for the first time using the time-resolved laser-induced fluorescence method. They are compared with multiconfigurational pseudo-relativistic Hartree–Fock calculations. A very good agreement is found. Using the experimental lifetimes and theoretical branching fractions, a first set of transition probabilities of astrophysical interest has been obtained for this ion.  相似文献   

Oscillator strength calculations in neutral technetium     

P. Palmeri  C. Froese Fischer  J.-F. Wyart  M. R. Godefroid 《Monthly notices of the Royal Astronomical Society》2005,363(2):452-458

  相似文献   

微型氢化物发生装置在冷原子吸收分光光度法测汞中的应用     

赵延庆 《岩矿测试》2008,27(1):69-70

采用微型氢化物发生装置-冷原子吸收分光光度法测定了焊锡料及纽扣电池中的汞。在酸性介质中,用硼氢化钾将汞离子还原为汞原子,用载气将汞蒸气导入石英管,原子吸收分光光度计在波长253.7 nm处进行测定。选择了实验条件,对共存离子的干扰等进行了考察。方法的检出限为0.34 ng/mL,11次测定的相对标准偏差(RSD)小于6%,加标回收率为94.4%~104.7%。  相似文献