运用3DEEMs及荧光偏振方法研究pH、离子强度及浓度效应对腐殖酸荧光光谱特性的影响   总被引：6，自引：0，他引：6  

梅毅  吴丰昌  王立英  白英臣 《地球化学》2008,37(2):165-173

利用三维荧光激发.发射光谱(3DEEMs)及荧光偏振法研究了3例腐殖酸和1例湖泊溶解有机物(DOM)在不同腐殖酸浓度、离子强度和pH条件下的荧光光谱特性.实验结果表明,随着浓度增大,各腐殖酸样的荧光强度增大,其中垃圾渗滤液腐殖酸和Pahokee泥炭腐殖酸的荧光峰出现红移.随着浓度进一步增大,腐殖酸的荧光偏振值增大,由此推断在此浓度范围内腐殖酸由于分子间的排斥作用使其构型出现伸展.离子强度增大导致腐殖酸及阿哈湖DOM的荧光强度降低.随着氯化钾(KCI)浓度增大,Fluka腐殖酸的荧光峰A蓝移,荧光峰B的荧光偏振值出现减小,推测是由于静电中和作用使其荧光基团发生卷曲造成的.离子强度对其余腐殖酸样和阿哈湖DOM的其他荧光特性没有明显的影响.总的来说,pH值的变化对腐殖酸和湖泊DOM的荧光特征的影响是很明显的.随着pH值增大,腐殖酸和湖泊DOM的荧光强度增强.而pH值减小时,Fluka腐殖酸和Pahokee泥炭腐殖酸的荧光峰(A峰)蓝移,当pH值降到5时,Fhka腐殖酸的荧光峰突然红移到最大,随后又继续蓝移;垃圾渗滤液腐殖酸和阿哈湖DOM的荧光峰位无明显的漂移.所有样品的荧光偏振值都减小(但阿哈湖DOM的A峰变化不大),但在pHi≤5时又增大,这种现象表明随着pH值降低,腐殖酸和湖泊DOM中有机大分子发生卷曲,但在pH≤5时由于羧基的质子化又以平面伸展构型出现在溶液中.  相似文献   

海洋真菌及其生物活性物质多样性研究   总被引：13，自引：0，他引：13  

王祥敏  李明  骆祝华  赵昌会  黄翔玲  叶德赞 《海洋湖沼通报》2007,(3):69-74

海洋微生物种类繁多,是筛选新药的丰富资源宝库。近些年来,作为海洋微生物中重要的组成部分的海洋真菌正成为研究的热点,越来越受到国内外学者的关注。本文详细概述了海洋真菌的定义、分布、海洋真菌研究的历史和现状、其所产生的生物活性物质多样性以及存在的问题。  相似文献   

In-situ Formation of Light-Absorbing Organic Matter in Cloud Water   总被引：1，自引：0，他引：1  

A. Gelencsér  A. Hoffer  G. Kiss  E. Tombácz  R. Kurdi  L. Bencze 《Journal of Atmospheric Chemistry》2003,45(1):25-33

Current climate models seem to underestimate the flux of solar energy absorbed by the global troposphere. All of these models are constrained with the assumption that cloud droplets consist of pure water. Here we demonstrate in a simple laboratory experiment that aromatic hydroxy-acids which are found in continental fine aerosol can react with hydroxyl radicals under typical conditions prevalent in cloud water influenced by biomass burning. The reactions yield colored organic species which do absorb solar radiation. We also suggest that the products of such reactions may be humic-like substances whose presence in continental aerosol has been confirmed but their source mechanisms are still much sought after. We also attempt to give a first order estimate of the enhancement of water absorption at a visible wavelength under atmospheric conditions.  相似文献   

Organic pollutants associated with macromolecular soil organic matter: Mode of binding   总被引：2，自引：0，他引：2  

H. H. Richnow  R. Seifert  J. Hefter  M. Link  W. Francke  G. Schaefer  W. Michaelis   《Organic Geochemistry》1997,26(11-12)

A study of ether-linked moieties in macromolecular bound residues of polycyclic aromatic hydrocarbons (PAH) generated in bioremediation experiments was performed using high temperature hydrolysis degradation with subsequent analysis of the products by GC-MS. This hydrolysis reaction was specifically designed to cleave ether bonds including relatively stable diarylether structures. Among the reaction products, aromatic alcohols representing typical microbiologically derived metabolites of PAH were found in addition to natural compounds. Thus, parts of the bound residues appeared to be linked within the macromolecular material by ether bonds. Model experiments with an oxidoreductase enzyme and aromatic alcohols indicate the formation of these ether bonds to be an enzyme-catalysed process.  相似文献   

关于侵入岩体中金矿床成因研究若干问题的讨论   总被引：9，自引：1，他引：9  

莫测辉  王秀璋 《地质论评》1997,43(2):139-147

各时代、不同类型侵入岩中的金矿床是金矿的主要类型。关于金矿床与岩体的成因关系目前尚存在不同的看法，但传统的岩浆热液成因观点仍居统治地位，其原因往往在于不少研究者把岩液热液成因当成了固定模式应用于具体矿床的研究，而不是建立在综合研究的基础之上。本文结合近年来金矿的研究进展，强调侵入岩中金矿床的研究的研究要综合考虑成岩成矿的时代与时差，成矿流体和成矿物质的来源等各方面因素。金矿床定年的进展研究表明，矿  相似文献   

药用滑石粉酸中可溶物测定方法考察   总被引：1，自引：0，他引：1  

农以宁  刘珊珊 《矿产与地质》2004,18(6):611-614

考察药用滑石粉酸中可溶物测定方法的重复性、耐用性 ,分析主要影响因素。比较酸溶物提取液滤过介质对测定结果差异的影响 ;采用重量法随机测定酸溶物含量和室间差异。两种滤过介质处理对测定结果没有显著差异 ;室间测定结果没有显著差异 ;30批样品平行测定结果的 RSD值范围为 0 %～ 18.2 %。酸中可溶物测定法存在重复性和耐用性不佳的问题 ,应相应调整酸中可溶物含量限度  相似文献   

Computational methods for fitting statistical distribution models of multi-site binding equilibria     

Rudolph S. Parrish  E. Michael Perdue 《Mathematical Geology》1989,21(2):199-219

Statistical distribution models of multi-site binding equilibria have potential applicability in the study of acid-base and metal complexation chemistry of humic substances in soils, sediments, and natural waters. A mathematical derivation is presented for the general continuous model for the case of proton binding; computational methods are described for fitting numerically the parameters in such models. Among models considered are those based on nontruncated, truncated, and bimodal (mixed) distributions. Specific emphasis is placed on Gaussian distribution models.  相似文献   

Patterns of dissolved organic matter in subarctic peatlands     

T. R. Moore 《地球表面变化过程与地形》1987,12(4):387-397

Samples of water from poor to very rich fens in the Schefferville region of subarctic Quebec revealed strong spatial and temporal variations in dissolved organic carbon (DOC), ranging from 2 to 40 mg 1^?1. Concentrations of DOC tend to increase during the summer and decrease in the autumn, at most sites, which probably reflects increased plant tissue decomposition and higher rates of evapotranspiration. Principal components analysis revealed that DOC is strongly associated with Fe, NO^?₃-N and NO^?₂-N, but essentially independent of other chemical properties of the peat water, such as pH, Ca, Mg, K, P, and NH⁺₄-N. Based on observed concentrations of DOC and estimates of summer runoff (June to September), export of DOC from four peatlands ranges from 1·1 to 4·9 gCm^?2, with the lowest values for peatlands underlain by dolomite. Molecular weight fractionation of four samples revealed significant differences in the dissolved organic matter (DOM), with the largest fractions (GF/C to 10 000 nmw) being dominant in the more acid samples. The ratio of absorbance at 400 and 600 nm wavelengths (E₄:E₆) has been used as a simple indicator of differences in DOM type, ranging from 3 to 15. There is a strong seasonal pattern of increasing E₄:E₆ ratio during the summer at many sites, though this ratio is essentially independent of other chemical properties of peat waters.  相似文献   

Seasonality in UV transparency of an alpine lake is associated to changes in phytoplankton biomass   总被引：1，自引：0，他引：1  

Ruben Sommaruga  Günther Augustin 《Aquatic Sciences - Research Across Boundaries》2006,68(2):129-141

  相似文献   

矿物材料应用于香烟过滤嘴降害的研究现状与展望     

吴敏  李胜荣 《岩石矿物学杂志》2007,26(2):171-176

总结了近几十年来包括活性炭、沸石、蒙脱石、海泡石、麦饭石、凹凸棒石、氧化铝、氢氧化钠、明矾、纳米材料等矿物材料作为卷烟滤嘴添加剂以去除烟气中有毒有害物质的研究和实验应用及效果。实验结果和市场调查表明,活性炭是减少卷烟危害最快、香烟市场应用增长最快的过滤嘴添加剂。从降低卷烟有害成分的比例和成本等综合因素来看,铝硅酸盐类滤嘴和多材料复合滤嘴亦有很好的应用前景和市场需求,应积极进行研制。  相似文献