Defect properties of albite     

Stephan Lowitzer  Dan J. Wilson  Björn Winkler  Victor Milman  Julian D. Gale 《Physics and Chemistry of Minerals》2008,35(3):129-135

Knowledge of the defect properties of Lunar and Mercurian minerals has recently become important, with the advent of models which attempt to explain the formation of the thin exosphere of these celestial bodies. Here, we have calculated the formation energies of sodium and oxygen vacancies in the mineral albite (NaAlSi₃O₈), as well as the Schottky defect energy for the removal of a Na₂O unit. We have employed both the supercell and Mott–Littleton approaches, using Kohn–Sham density functional theory and classical interatomic potential methods. As well as reporting the defect energies and structures, we comment upon the relative merits of the methods used.  相似文献   

Practical implementation of Hilbert-Huang Transform algorithm   总被引：12，自引：0，他引：12  

Huang Daji  Zhao Jinping  Su Jilan 《海洋学报(英文版)》2003,22(1):1-14

Hilbert-Huang Transform (HHT) is a newly developed powerful method for nonlinear and non-stationary time series analysis. The empirical mode decomposition is the key part of HHT, while its algorithm was protected by NASA as a US patent, which limits the wide application among the scientific community. Two approaches, mirror periodic and extrema extending methods, have been developed for handling the end effects of empirical mode decomposition. The implementation of the HHT is realized in detail to widen the application. The detailed comparison of the results from two methods with that from Huang et al. (1998, 1999), and the comparison between two methods are presented. Generally, both methods reproduce faithful results as those of Huang et al. For mirror periodic method (MPM), the data are extended once forever. Ideally, it is a way for handling the end effects of the HHT, especially for the signal that has symmetric waveform. The extrema extending method (EEM) behaves as good as MPM, and it is better t  相似文献   

Red Tide Frequency Analysis Using the Extreme Value Theory     

谢中华王洪礼  史道基孙景 《海洋通报(英文版)》2005,7(2):80-85

In recent years, the red tide erupted frequently, and caused a great economic loss. At present, most literatures emphasize the academic research on the growth mechanism of red tide alga. In order to find out the characters of red tide in detail and improve the precision of forecast, this paper gives some new approaches to dealing with the red tide. By the extreme values, we deal with the red tide frequency analysis and get the estimation of T-times red tide level U （T） , which is the level once the consistence of red tide alga exceeds on the average in a period of T times.  相似文献   

Shoreline variability via empirical orthogonal function analysis: Part I temporal and spatial characteristics     

Jon K. Miller  Robert G. Dean 《Coastal Engineering》2007

Empirical orthogonal functions (EOFs) or principal components were used to extract the significant modes of shoreline variability from several data sets collected at three very different locations. Although EOFs have proven to be a valuable tool in the analysis of nearshore data, most applications have focused on the ability of the technique to describe cross-shore or profile variability. Here however, EOFs were used to help identify the dominant modes of longshore shoreline variability at Duck, North Carolina, the Gold Coast, Australia, and at several locations within the Columbia River Littoral Cell in the U.S. Pacific Northwest. In part one of this analysis, characteristic patterns of shoreline variability identified by the EOF analysis are described in detail. At each site, the dominant modes consisting of the first four eigenfunctions were found to describe nearly 95% of the total shoreline variability. At both Duck and the Gold Coast, several interesting longshore periodic features suggestive of sand waves were identified, while boundary effects related to natural headlands and navigational structures/entrances dominated the Pacific Northwest data sets.  相似文献   

希尔伯特-黄变换的端点延拓   总被引：86，自引：0，他引：86       下载免费PDF全文

黄大吉  赵进平  苏纪兰 《海洋学报》2003,25(1):1-11

希尔伯特-黄变换(HHT)是近年来发展起来的一种新的时间序列信号分析方法.该文在对HHT深入研究与充分肯定的基础上,发展了信号的镜像闭合延拓和包络的极值延拓两种方法.通过几个典型的例子检验了两种方法,并与Huang等(1998,1999)进行了比较,得到了令人满意的结果.镜像闭合延拓法根据信号端点的分布特性,把镜子放在具有对称性的极值位置,通过镜像法把镜内信号映射成一个周期性的信号,不存在端点,从根本上避免了经验模态分解和希尔伯特变换的端点问题.极值延拓法简单易行,具有与镜像闭合法相当的效果,在处理非对称波形信号时更显其优越性.  相似文献   

On the multivariate total least-squares approach to empirical coordinate transformations. Three algorithms   总被引：2，自引：1，他引：1  

Burkhard Schaffrin  Yaron A. Felus 《Journal of Geodesy》2008,82(6):373-383

The multivariate total least-squares (MTLS) approach aims at estimating a matrix of parameters, Ξ, from a linear model (Y−E _Y = (X−E _X ) · Ξ) that includes an observation matrix, Y, another observation matrix, X, and matrices of randomly distributed errors, E _Y and E _X . Two special cases of the MTLS approach include the standard multivariate least-squares approach where only the observation matrix, Y, is perturbed by random errors and, on the other hand, the data least-squares approach where only the coefficient matrix X is affected by random errors. In a previous contribution, the authors derived an iterative algorithm to solve the MTLS problem by using the nonlinear Euler–Lagrange conditions. In this contribution, new lemmas are developed to analyze the iterative algorithm, modify it, and compare it with a new ‘closed form’ solution that is based on the singular-value decomposition. For an application, the total least-squares approach is used to estimate the affine transformation parameters that convert cadastral data from the old to the new Israeli datum. Technical aspects of this approach, such as scaling the data and fixing the columns in the coefficient matrix are investigated. This case study illuminates the issue of “symmetry” in the treatment of two sets of coordinates for identical point fields, a topic that had already been emphasized by Teunissen (1989, Festschrift to Torben Krarup, Geodetic Institute Bull no. 58, Copenhagen, Denmark, pp 335–342). The differences between the standard least-squares and the TLS approach are analyzed in terms of the estimated variance component and a first-order approximation of the dispersion matrix of the estimated parameters.  相似文献   

Modelling net erosion responses to enviroclimatic changes recorded upon multisecular timescales     

Nazzareno Diodato   《Geomorphology》2006,80(3-4):164-177

Land use change has been recognized throughout the Earth as one of the most important factors influencing the occurrence of rainfall-driven geomorphological processes. However, relating the occurrence of historical soil erosion rates is difficult because of the lack of long-term research projects in river basins. Also, complex models are not adequate to reconstruct erosion rate changes because they require significant input data not always available on long timescales. Given the problems with assessing sediment yield using complex erosion models, the objective of this study is to explore a parsimonious scale-adapted erosion model (ADT) from the original Thornes and Douglas algorithms, which aims at reconstruction of annual net erosion (ANE) upon multisecular timescales. As a test site, the Calore River basin (3015 km² in southern Italy) provides a peculiar and unique opportunity for modelling erosion responses to climate and land cover changes, where input-data generation and interpretation results were also supported by documented hydrogeomorphological events that occurred before and after land deforestation. In this way, ANE_ADT-values were reconstructed for the period 1675–2004 by using precipitation indexes, complemented by recent instrumental records, and by using land cover statistics from documented agrarian sources. Pulses of natural sedimentation in the predeforestation period have been related to Vesuvius volcanic activity and changes in rainstorm frequency. After deforestation, the basin system became unstable with sudden fluctuations in the hydrogeomorphological regime contributing significantly to increased erosion and, in turn, sediment transport sequences via river drainage towards the Tyrrhenian coast.  相似文献   

近45 a东北地区春季降水异常的气候特征   总被引：8，自引：0，他引：8  

杨素英  孙凤华  陈岩 《南京气象学院学报》2005,28(2):197-204

利用1959-2003年我国东北地区93站春季降水资料，将降水场分成5个区域，并在此基础之上分析了春季降水的时空变化特征，发现：降水量年际变化及长期趋势有明显的区域差异，呈东多西少的分布特征；西部是旱涝易发生区，近45a来降水量略有增多；降水量的周期振荡存在明显的区域差异。  相似文献   

多矿物岩石流变规律的研究进展及存在问题   总被引：4，自引：2，他引：4  

江燕  臧绍先 《地球物理学进展》2002,17(3):456-463

总结了近年来由多种矿物组成的岩石的流变规律的研究，阐述了多矿物岩石流变性质研究的意义和进展，再从实验和理论两个方面，详细论述了目前最具代表性的三种理论模型，算术平均方法、几何平均方法和能量极小方法，最后，指出这方面研究仍然存在的问题和进一步研究的方向。  相似文献   

Simulation of normal distributed smooth fields by Karhunen-Loéve expansion in combination with kriging     

Nils-Otto Kitterrød  Lars Gottschalk 《Stochastic Environmental Research and Risk Assessment (SERRA)》1997,11(6):459-482

Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function. This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the 2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the predefined covariance functions are evaluated.  相似文献