全文获取类型
收费全文 | 161篇 |
免费 | 46篇 |
国内免费 | 26篇 |
专业分类
测绘学 | 6篇 |
大气科学 | 11篇 |
地球物理 | 58篇 |
地质学 | 81篇 |
海洋学 | 14篇 |
天文学 | 22篇 |
综合类 | 10篇 |
自然地理 | 31篇 |
出版年
2023年 | 1篇 |
2022年 | 5篇 |
2021年 | 1篇 |
2020年 | 3篇 |
2019年 | 3篇 |
2018年 | 6篇 |
2017年 | 8篇 |
2016年 | 10篇 |
2015年 | 7篇 |
2014年 | 8篇 |
2013年 | 8篇 |
2012年 | 10篇 |
2011年 | 11篇 |
2010年 | 10篇 |
2009年 | 10篇 |
2008年 | 23篇 |
2007年 | 5篇 |
2006年 | 10篇 |
2005年 | 8篇 |
2004年 | 5篇 |
2003年 | 9篇 |
2002年 | 8篇 |
2001年 | 10篇 |
2000年 | 6篇 |
1999年 | 7篇 |
1998年 | 8篇 |
1997年 | 5篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1994年 | 7篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
排序方式: 共有233条查询结果,搜索用时 15 毫秒
1.
Ian C. Grieve 《水文研究》1989,3(4):339-346
Parameters for ion exchange selectivity and aluminium hydroxide dissolution in the soil chemical submodels used in applications of the Birkenes model and of MAGIC are compared and several discrepancies identified for organic soils. A laboratory column simulation of the soil chemical submodels is proposed and applied to soils from the Loch Dee area in Galloway. Experimental results were well predicted by a simplified version of MAGIC, with ion exchange selectivity parameters similar to those used in a previous simulation of one subcatchment of Loch Dee. The aluminium hydroxide dissolution parameter used previously was found to be too low for the organic soil materials, where a value of 106 predicted the experimental results more closely. The model developed also included a simple silicate weathering reaction to release base cations into the system. It is concluded that such simple laboratory simulations are useful for independent calibration of the soil chemical submodel of catchment models. 相似文献
2.
The spatial extent of ion cyclotron waves at Io has been interpreted as requiring a multistep acceleration and transport process: exospheric ions are accelerated outward (relative to Jupiter) due to the corotation electric field, neutralized due to charge exchange in the surrounding exosphere, and then reionized after traveling far across magnetic field lines, at which point they generate the waves. The trajectories of the particles away from Io are sensitive to the location of their initial ionization. This paper examines the spatial distributions of fast neutrals produced under varying conditions in order to provide constraints on the possible structure and nature of the Io exosphere. While a rapid onset of cyclotron waves at a specific location around Io can be modeled with a single, point-source region of ions, such as might occur over a volcano, the regional extent of the waves suggests multiple or distributed sources. 相似文献
3.
The kinetics of the aqueous phase reactions of NO3 radicals with HCOOH/HCOO– and CH3COOH/CH3COO– have been investigated using a laser photolysis/long-path laser absorption technique. NO3 was produced via excimer laser photolysis of peroxodisulfate anions (S2O
8
2–
) at 351 nm followed by the reactions of sulfate radicals (SO
4
–
) with excess nitrate. The time-resolved detection of NO3 was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO3 with formic acid (1) and formate (2) rate coefficients ofk
1=(3.3±1.0)×105 l mol–1 s–1 andk
2=(5.0±0.4)×107 l mol–1 s–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k
1(T)=(3.4±0.3)×1010 exp[–(3400±600)/T] l mol–1 s–1 andk
2(T)=(8.2±0.8)×1010 exp[–(2200±700)/T] l mol–1 s–1. The rate coefficients for the reactions of NO3 with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k
3=(1.3±0.3)×104 l mol–1 s–1 andk
4=(2.3±0.4)×106 l mol–1 s–1. The temperature dependences for these reactions are described by:k
3(T)=(4.9±0.5)×109 exp[–(3800±700)/T] l mol–1 s–1 andk
4(T)=(1.0±0.2)×1012 exp[–(3800±1200)/T] l mol–1 s–1. The differences in reactivity of the anions HCOO– and CH3COO– compared to their corresponding acids HCOOH and CH3COOH are explained by the higher reactivity of NO3 in charge transfer processes compared to H atom abstraction. From a comparison of NO3 reactions with various droplets constituents it is concluded that the reaction of NO3 with HCOO– may present a dominant loss reaction of NO3 in atmospheric droplets. 相似文献
4.
Sadrack Flix Toteu Joseph Penaye Etienne Deloule William Randall Van Schmus Rigobert Tchameni 《Journal of African Earth Sciences》2006,44(4-5):428
Ion microprobe U–Pb dating of zircons from Neoproterozoic volcano-sedimentary sequences in Cameroon north of the Congo craton is presented. For the Poli basin, the depositional age is constrained between 700–665 Ma; detrital sources comprise ca. 920, 830, 780 and 736 Ma magmatic zircons. In the Lom basin, the depositional age is constrained between 613 and 600 Ma, and detrital sources include Archaean to Palaeoproterozoic, late Mesoproterozoic to early Neoproterozoic (1100–950 Ma), and Neoproterozoic (735, 644 and 613 Ma) zircons. The Yaoundé Group is probably younger than 625 Ma, and detrital sources include Palaeoproterozoic and Neoproterozoic zircons. The depositional age of the Mahan metavolcano-sedimentary sequence is post-820 Ma, and detrital sources include late Mesoproterozoic (1070 Ma) and early Neoproterozoic volcanic rocks (824 Ma). The following conclusions can be made from these data. (1) The three basins evolved during the Pan-African event but are significantly different in age and tectonic setting; the Poli is a pre- to syn-collisional basin developed upon, or in the vicinity of young magmatic arcs; the Lom basin is post-collisional and intracontinental and developed on old crust; the tectono-metamorphic evolution of the Yaoundé Group resulted from rapid tectonic burial and subsequent collision between the Congo craton and the Adamawa–Yade block. (2) Late Mesoproterozoic to early Neoproterozoic inheritance reflects the presence of magmatic event(s) of this age in west–central Africa. 相似文献
5.
不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。 相似文献
6.
本文介绍了用离子色谱法同时测定矿物包裹体中F~-、Cl~-、PO_4~(3-)、Br~-、NO_3~-、SO_4~(2-)6种阴离子的新方法。研究了流动相浓度对保留时间的影响以及消除负峰干扰的方法。 相似文献
7.
离子色谱法测定岩石,土壤,水系沉积物等样品中的氯,溴,碘 总被引:1,自引:0,他引:1
本文采用碳酸钠一氧化锌烧结法分解样品,利用DIONEX2020i离子色谱仪,电导、电化学检测器,建立了一测定岩石等样品中氯、溴、碘的分析流程。实验表明,本方法选择性好,灵敏度高,检出限分别为:氯1.03×10~(-6)、溴0.012×10~(-6)、碘0.014×10~(-6)。 相似文献
8.
9.
The Conductivity Test — Determining the Membrane-toxic Properties of Substances A new biotest system is introduced which is specific in terms of the measured effect but not in terms of the applied organisms. The system is able to detect the effect of membrane-toxic compounds e.g. detergents, organic solvents, and radical formers. Released into the environment, these substances damage biological membranes and therefore cause ion leakage into a surrounding medium. Ion leakage is taken as a measure for membrane damage and is determined as an increase of the electrical conductivity in the medium (conductivity test). The results presented for the tensides benzalkonium chloride, LAS (linear alkylbenzenesulfonate), and APG (alkylpolyglycoside) demonstrate the capability of the conductivity test to distinguish between the differing toxicological potential of these membrane-toxic substances. In contrast to most of the conventional biotests, the endpoint of the conductivity test is independent of a specific organism. This independence is demonstrated by the results obtained with benzalkonium chloride treatment of Elodea canadensis, Lemna minor, and Salvinia natans. The conductivity test represents a versatile, easy to handle biotest system for the assessment of ecotoxicological effects caused by membrane-toxic substances. 相似文献
10.
内蒙古东五分子地区韧性剪切变质作用的特征 总被引:6,自引:0,他引:6
东五分子地区花岗-绿岩地体经受了三种类型变质作用的改造。韧性剪切带不仅控制了区域变质岩组合的分布,而且也导致其变质作用的强度出现了逆转序列。根据岩石的结构、碎斑含量及矿物成分,韧性剪切变质岩划分为三类,其共同特点是具有碎斑结构。其变形结构分为单矿物型及组合型。同一块韧性剪切变质岩由处在单变平衡的一组矿物组成。根据岩石变形及重结晶的特点,结合其产状,确定出两种不同类型韧性剪切变质带。共生矿物对的研究证明它们形成于地壳不同深度及温度、压力条件。本区的金矿化、运移、沉淀与韧性剪切变质带紧密相关。 相似文献