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1.
Mark B. Boslough Thomas J. Ahrens Arthur C. Mitchell 《Geophysical Journal International》1986,84(3):475-489
Summary. Temperatures of CaAl2 Si2 O8 (anorthite glass) shocked to pressures between 48 and 117 GPa have been measured in the range from 2500 to 5600 K, using optical pyrometry techniques. The pressure dependence of the shock temperatures deviates significantly from predictions based on a single high-pressure phase. Either a variable specific heat, or the existence of three phase transitions, at pressures of about 55, 85 and 100 GPa and with transition energies of about 0.5 MJ kg−1 each (∼ 1.5 MJ kg−1 total) can explain the shock-temperature data. The proposed phase transition at 100 GPa can possibly be identified with the stishovite melting transition. Theoretical models of the time dependence of the thermal radiation from the shocked anorthite based on the geometry of the experiment and the absorptive properties of the shocked material yield good agreement with observations, indicating that it is not necessary to invoke intrinsic time dependences to explain the data in many cases. Observed time dependences were used to calculate absorption coefficients of the shocked material of from about 2 mm−1 to greater than 24 mm−1 – an increasing function of shock pressure. The assumption that the shocked material radiates as a black body is supported by the theoretical model, and by the close agreement between measured and calculated black body spectral radiance as a function of wavelength. 相似文献
2.
材料研究与制备过程中的几个矿物学岩石学问题 总被引：4，自引：0，他引：4
在材料的研究与制备过程中往往会遇到很多有趣的矿物学、岩石学问题。这些问题有些是矿物学工作者和材料研究者所熟悉的,是材料研究者直接利用了矿物学工作者的研究成果。而有些问题是材料研究者首先发现,并将其中的某些条件加以利用,但缺少深入的矿物学理论研究;还有些工作是矿物学工作者得到的矿物学纯理论研究成果,但却不知如何应用到材料的开发与研究中。这就造成了介于矿物学与材料学之间的一个薄弱环节。这个薄弱环节为矿物、岩石工作者提供了一个广阔的研究领域和很多富有诱惑力的崭新的研究课题。于是一个新的分支学科———矿… 相似文献
3.
Alfons M. van den Kerkhof Geoffrey H. Grantham 《Contributions to Mineralogy and Petrology》1999,137(1-2):115-132
In the Port Edward area of southern Kwa-Zulu Natal, South Africa, charnockitic aureoles up to 10 m in width in the normally
garnetiferous Nicholson's Point Granite, are developed adjacent to intrusive contacts with the Port Edward Enderbite and anhydrous
pegmatitic veins. Mineralogical differences between the country rock and charnockitic aureole suggest that the dehydration
reaction Bt + Qtz → Opx + Kfs + H2O and the reaction of Grt + Qtz → Opx + Pl were responsible for the charnockitization. The compositions of fluid inclusions
show systematic variation with: (1) the Port Edward Enderbite being dominated by CO2 and N2 fluid inclusions; (2) the non-charnockitized granite by saline aqueous inclusions with 18–23 EqWt% NaCl; (3) the charnockitic
aureoles by low-salinity and pure water inclusions (<7 EqWt% NaCl); (4) the pegmatites by aqueous inclusions of various salinity
with minor CO2. As a result of the thermal event the homogenization temperatures of the inclusions in charnockite show a much larger range
(up to 390 °C) compared to the fluid inclusions in granite (mostly <250 °C). Contrary to fluid-controlled charnockitization
(brines, CO2) which may have taken place along shear zones away from the intrusive body, the present “proximal” charnockitized granite
formed directly at the contact with enderbite. The inclusions indicate contact metamorphism induced by the intrusion of “dry”
enderbitic magma into “wet” granite resulting in local dehydration. This was confirmed by cathodoluminescence microscopy showing
textures indicative for the local reduction of structural water in the charnockite quartz. Two-pyroxene thermometry on the
Port Edward Enderbite suggests intrusion at temperatures of ∼1000–1050 °C into country rock with temperature of <700 °C. The
temperature of aureole formation must have been between ∼700 °C (breakdown of pyrite to form pyrrhotite) and ∼1000 °C. Charnockitization
was probably controlled largely by heat related to anhydrous intrusions causing dehydration reactions and resulting in the
release and subsequent trapping of dehydration fluids. The salinity of the metamorphic fluid in the contact zones is supposed
to have been higher at an early stage of contact metamorphism, but it has lost its salt content by K-metasomatic reactions
and/or the preferential migration of the saline fluids out of the contact zones towards the enderbite. The low water activity
inhibited the localized melting of the granite. Mineral thermobarometry suggests that after charnockite aureole genesis, an
isobaric cooling path was followed during which reequilibration of most of the aqueous inclusions occurred.
Received: 8 November 1998 / Accepted: 21 June 1999 相似文献
4.
广西大厂锡多金属矿区钙长石产出的地质环境及成因机制 总被引：3，自引：0，他引：3
本文对广西大厂锡多金属矿区容矿岩石内含有钙长石大晶体岩石的岩石学，钙长石的产状，钙长石及有关矿物的成分特征等作了较为细致的研究，对其自生成因的机理进行了探讨，阐明了成岩作用对矿床的形成有关重要的地质意义。 相似文献
5.
Strain softening and microstructural evolution of anorthite aggregates and quartz-anorthite layered composites deformed in torsion 总被引：1，自引：0，他引：1
Shaocheng Ji Zhenting Jiang Richard Wirth Bin Xia 《Earth and Planetary Science Letters》2004,222(2):377-390
Torsion experiments of anorthite (An) aggregates and layered composites with equal volume fractions of quartz (Qtz) and An were performed in a gas-medium apparatus at a confining pressure of 400 MPa, temperatures from 1373 to 1473 K, and twist rates from 1.0×10−4 to 3.0×10−4 rad/s. Dense specimens were fabricated from An glass and Qtz crystalline powder using hot isostatic pressing (HIP) techniques. Both An aggregates and Qtz-An layered composites show a continuous strain weakening from a peak stress at γ=0.2-0.3 to γ=3.2, and steady-state flow has not reached under the experimental conditions. The weakening is even more pronounced in the layered composites than the monolithic aggregates, suggesting channeling or localization of flow into the weak material between strong layers. The sheared An specimens developed pervasively C-S-C′ structures which are similar to those observed in natural ductile shear zones. TEM and electron backscattering diffraction (EBSD) fabric analyses suggest that grain boundary migration recrystallization-accommodated dislocation creep with (010)[100] as the dominant slip system was operating in the An. The strain softening may be due to the development of crystallographic preferred orientation (CPO), the operation of dynamic recrystallization and the formation of extremely fine-grained recrystallized material in the narrow C′ shear bands. 相似文献
6.
RALPH KRETZ 《Journal of Metamorphic Geology》1990,8(5):493-506
Garnet-biotite gneisses, some of which contain sillimanite or hornblende, are widespread within the Otter Lake terrain, a portion of the Grenville Province of the Canadian Shield. The metamorphic grade is upper amphibolite to, locally, lower granulite facies. The atomic ratio Fe2+/(Fe2++ Fe3+) in biotite ranges from 0.79 to 0.89 (ferrous iron determinations in 10 highly pure separates), with a mean of 0.86. Mg and Fe2+ atoms occupy 67–78% of the octahedral sites, the remainder are occupied by Fe3+, Ti, and Al, and some are vacant. Mg/(Mg + Fe2+), denoted X, in the analysed samples ranges from 0.32 to 0.65. Garnet contains 1–24% grossular, 1–12% spessartine and X ranges from 0.07 to 0.34. Compositional variation in biotite and garnet is examined in relation to three mineral equilibria: (I) biotite + sillimanite + quartz = garnet + K-feldspar + H2O; (II) pyrope + annite = almandine + phlogopite; (III) anorthite = grossular + sillimanite + quartz. Measurements of X (biotite) and X (garnet) are used to construct an illustrative model for equilibrium (I) which relates the observed variation in X to a temperature range of 70°C or a range in H2O activity of 0.6; the latter interpretation is preferred. In sillimanite-free gneisses, the distribution of Mg and Fe2+ between garnet (low in Ca and Mn) and biotite is adequately described by a distribution coefficient (KD) of 4.1 (equilibrium II). The observed increase in the distribution coefficient with increasing Ca in garnet is ln KD= 1.3 + 2.5 × 10?2 [Ca] where [Ca] = 100 Ca/(Mg + Fe2++ Mn + Ca). The distribution coefficient is apparently unaffected by the presence of up to 12% spessartine in garnet. In several specimens of garnet-sillimanite-plagioclase gneiss, the Ca contents of garnet and of plagioclase increase in unison, as required by equilibrium (III). The mean pressure calculated from these data (n= 17) is 5.9 kbar, and the 95% confidence limits are ±0.5 kbar. 相似文献
7.
Molecular dynamics (MD) simulations of the influence of the Al-O-Al linkage on the P&1macr;-I&1macr; phase transition of
pure anorthite (An) were carried out using two different types of structures with fully ordered (FO) and partially disordered
(PD) arrangements of Al/Si in tetrahedral sites. Discontinuous changes in unit cell volumes and structure factors at the transition
temperature were observed in FO-An but not in PD-An. These results show that the orders of the transitions of FO-An and PD-An
are first and non-first, respectively. In both structures, the motions of the Ca atoms and the framework are strongly correlated
with each other during the transition and Ca atoms dominate the system. Since high-temperature X-ray studies have shown that
the transition of natural anorthite is non-first order, it is suggested that the natural anorthite has a partially disordered
arrangement of Al and Si atoms.
Received: 22 October 1998 / Revised, accepted: 12 March 1999 相似文献
8.
B. Reynard M. Okuno Y. Shimada Y. Syono C. Willaime 《Physics and Chemistry of Minerals》1999,26(6):432-436
Structural modifications induced by shock-wave compression up to 40 GPa in anorthite glass are investigated by Raman spectroscopy.
In the first investigation, densification increases with increasing shock pressure. A maximum densification of 2.2% is obtained
for a shock pressure of 24 GPa. This densification is attributed to a decrease of the average ring size, favoring three-membered
rings. The densification is much lower than in silica glass subject to shock at similar pressures (11%), because the T-O-T
bond angle decrease is impeded in anorthite glass. For higher shock pressures, the decrease of the recovered densification
is attributed to partial annealing of the samples due to high after-shock residual temperatures. The study of the annealing
process of the most densified glass by in-situ high temperature Raman spectroscopy confirms that relaxation of the three-membered
rings occurs above about 900 K.
Received: 21 July 1998 / Revised and accepted: 27 January 1999 相似文献
9.
Several intrusions of ultrabasic to basic composition occur in the Roslagen area of east‐central Sweden in close spatial and temporal association with the surrounding 1.90–1.87 Ga old early orogenic Svecofennian granitoids. An imprecise Sm‐Nd WR errorchron yields an age of 1895 ± 71 Ma. In spite of the penetrative deformation in the granitoids, the basic–ultrabasic rocks mostly appear undeformed and largely preserve magmatic textures with plagioclase, olivine (in some rock types), orthopyroxene and clinopyroxene, and amphibole as major constituents. The plagioclase is typically very anorthitic (ca. An90). The Roslagen intrusions range in composition from primitive to evolved (Mg# 80 to 49) but contain only 40–50 wt% SiO2. Many samples are highly elevated in Al2O3 (up to 30 wt%), CaO (up to 16 wt%) and Sr (up to 800 ppm), with strongly positive Eu and Sr anomalies, in line with being plagioclase cumulates. Although masked by cumulus effects, the relative trace element contents indicate a volcanic arc signature. The initial Nd isotope composition is homogeneously ‘mildly depleted’, with εNd of +0.3 to +1.1, and the initial Sr isotope composition ‘mildly enriched’, with εSr of +8 to +15. Non‐cumulus rocks with small Eu and Sr anomalies can be used to deduce the composition of the parental magma. This LILE‐ and LREE‐enriched and HFSE‐depleted high‐alumina basalt magma, with Mg# of ca. 50–60 and Ca# of ca. 80, most likely formed by partial melting of mantle material, enriched by fluids in a subduction environment, at 1.9 Ga. The cumulate rocks apparently crystallized from a somewhat more evolved water‐rich magma with Mg# of ca. 40. Crystallization was followed by the development of late‐magmatic to post‐magmatic coronas between olivine and plagioclase in the presence of H2O‐rich fluids. The subduction‐related setting would make these intrusions Palaeoproterozoic counterparts of Alaskan‐type ultramafic intrusions, but they differ from those in being plagioclase enriched, possibly reflecting different levels of exposure. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
10.