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1.
This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies. 相似文献
2.
Silicon limitation on primary production and its destiny in Jiaozhou Bay, China——Ⅳ:Study on cross-bay transect from estuary to ocean 总被引:1,自引:0,他引:1
The authors analyzed the data collected in the Ecological Station Jiaozhou Bay from May 1991 to November 1994, including 12
seasonal investigations, to determine the characteristics, dynamic cycles and variation trends of the silicate in the bay.
The results indicated that the rivers around Jiaozhou Bay provided abundant supply of silicate to the bay. The silicate concentration
there depended on river flow variation. The horizontal variation of silicate concentration on the transect showed that the
silicate concentration decreased with distance from shorelines. The vertical variation of it showed that silicate sank and
deposited on the sea bottom by phytoplankton uptake and death, and zooplankton excretion. In this way, silicon would endlessly
be transferred from terrestrial sources to the sea bottom. The silicon took up by phytoplankton and by other biogeochemical
processes led to insufficient silicon supply for phytoplankton growth. In this paper, a 2D dynamic model of river flow versus
silicate concentration was established by which silicate concentrations of 0.028–0.062 μmol/L in seawater was yielded by inputting
certain seasonal unit river flows (m3/s), or in other words, the silicate supply rate; and when the unit river flow was set to zero, meaning no river input, the
silicate concentrations were between 0.05–0.69 μmol/L in the bay. In terms of the silicate supply rate, Jiaozhou Bay was divided
into three parts. The division shows a given river flow could generate several different silicon levels in corresponding regions,
so as to the silicon-limitation levels to the phytoplankton in these regions. Another dynamic model of river flow versus primary
production was set up by which the phytoplankton primary production of 5.21–15.55 (mgC/m2·d)/(m3/s) were obtained in our case at unit river flow values via silicate concentration or primary production conversion rate.
Similarly, the values of primary production of 121.98–195.33 (mgC/m2·d) were achieved at zero unit river flow condition. A primary production conversion rate reflects the sensitivity to silicon
depletion so as to different phytoplankton primary production and silicon requirements by different phytoplankton assemblages
in different marine areas. In addition, the authors differentiated two equations (Eqs. 1 and 2) in the models to obtain the
river flow variation that determines the silicate concentration variation, and in turn, the variation of primary production.
These results proved further that nutrient silicon is a limiting factor for phytoplankton growth.
This study was funded by NSFC (No. 40036010), and the Director's Fund of the Beihai Sea Monitoring Center, the State Oceanic
Administration. 相似文献
3.
对广西岩溶区三个铅锌硫化物矿床风化带观测结果表明,中低山岩溶区硫化物矿床具有更强烈的风化淋滤作用,但次生晕面积较小;岩溶平原区硫化物矿床风化与元素表生迁移特征较相似于非岩溶区的情况,表现在可产生较宽的pH偏低带和较大面积的次生晕 相似文献
4.
A strain of thermophilic fungus Aspergillus fumigatus was cultured with K-bearing minerals to determine if microbe-mineral interactions enhance the release of mineralic potassium. Experiments were carried out in two settings, one with the mineral grains and the fungal cells in direct contact, and the other employing a membrane (pore size 0.22 μm) to separate the two. Measurements over a period of 30 days showed that, irrespective of the experimental setup, the concentration of free K in the culture was drastically higher than those in any of the control experiments where no living organism was present. Moreover, the occurrence of mineral-cell physical contact enhanced potassium release by an additional factor of 3 to 4 in comparison to the separation experiments. For contact experiments, Electron Probe Microanalysis revealed the formation of mycelium-mineral aggregates, and Atomic Force Microscopy imaging further indicated the possible ingestion of mineral particles by the fungus cells. Contrasting to what was observed and expected in control experiments, the potassium solubilization rate showed a positive dependence upon pH when fungi and minerals were mixed directly, and exhibited no correlations with solution acidity if cell-rock contact was restrained. These results appear to suggest that A. fumigatus promoted potassium release by means of at least three likely routes, one through the complexation of soluble organic ligands, another appealing to the immobile biopolymers such as the insoluble components of secretion, and the third related to the mechanical forces in association with the direct physical contact between cells and mineral particles. 相似文献
5.
Summary Left in place pillars of abandoned mines are subject to weathering (e.g action of water, bacteria) that degrades their mechanical
strength and eventually leads to collapse. A simple weathering model is proposed, that is governed by two parameters: the
rate of progression of weathered front and the rate of degradation of the compressive strength with time. Both plane strain
and axisymmetric analyses are performed and closed form solutions of the variation with time of the bearing capacity of the
pillar are given. Experimental data of the tests conducted on gypsum and anhydrite specimens attacked by water are presented.
It is shown that in order to fit the experimental data a third parameter must be introduced. New closed form solutions are
given and the data are used for estimating the time to failure of abandoned gypsum mines in Northern Italy.
Authors’ address: Dr. Riccardo Castellanza, Research Assistant, Department of Structural Engineering, Milan University of
Technology (Politecnico), Piazza Leonardo da Vinci 32, 20133 Milan, Italy 相似文献
6.
一株胶质芽胞杆菌对磷矿石风化作用的实验研究 总被引:1,自引:0,他引:1
以一株质芽孢杆菌为例研究实验条件下微生物对磷矿石的风化作用.以直接作用和间接作用的方式研究培养基中胶质芽孢杆菌对磷矿粉的风化作用,即在装有100目磷矿石粉的液体培养基中接种,研究该菌对磷矿石粉的直接风化作用;同时,将装有100目磷矿石粉的透析袋放入液体培养基中再接入该菌,研究其对磷矿石粉的间接风化作用.按不同时间取培养液上清液,过滤,用电感耦合等离子体发射光谱(ICP-OES)测定滤液中Ca2 、Mg2 、Na 、Mn2 、Al3 、Fe3 和K 等浓度,比色法测定水溶性P(Pws)和水溶性Si (Siws) 的含量;滤膜上的固体物称重并消解后,同上方法测定Ca2 、Mg2 、Na 、Mn2 、Al3 、Fe3 和K 等浓度以及Pws和Siws含量.此外,细菌风化作用后的矿物残渣用电子探针作表面微观形态分析和XRD矿物物相分析.结果表明:胶质芽孢杆菌对磷矿石粉风化的直接作用强度大于间接作用;对不同矿物的风化强度不同,对粘土矿物的风化作用较明显.提出细菌对磷矿石的风化作用源自细菌生长导致的机械破坏作用、胞外分泌物的生化降解作用以及多种因素之间的协同作用. 相似文献
7.
Relationship between biogeochemical features of biogenic elements and flocculation in the Changjiang Estuary 总被引:1,自引:3,他引:1
RelationshipbetweenbiogeochemicalfeaturesofbiogenicelementsandflocculationintheChangjiangEstuary¥LinYi'an;TangRenyou;LiYan;Do... 相似文献
8.
Toshiro Saino Alexander Bychkov Chen-Tung Arthur Chen Paul J. Harrison 《Journal of Oceanography》2004,60(1):1-4
This special issue is comprised of 13 papers, including this overview, and focuses on the synthesis of the Joint Global Ocean
Flux Study (JGOFS) in the North Pacific which took place from 1997 through 2003. The effort was led by the JGOFS North Pacific
Synthesis Group, with the aim of quantifying CO2 drawdown by physical and biological pumps in the North Pacific by identifying and studying the regional, seasonal to inter-annual
variations in the key processes, and understanding their regulating mechanisms. Emphasis was placed on the similarities and
differences of the biogeochemical regimes in the eastern and western subarctic Pacific. Effort was also made to address the
future research directions which arose from the scientific findings during the North Pacific JGOFS process study. A brief
overview of the papers from view points of CO2 drawdown by physical and biological pumps, spatial variability, and temporal variability from seasonal to decadal scales
is made, followed by suggestions for the directions of future research.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
9.
A preliminary study of carbon system in the East China Sea 总被引:1,自引:0,他引:1
Shizuo Tsunogai Shuichi Watanabe Junya Nakamura Tsuneo Ono Tetsuro Sato 《Journal of Oceanography》1997,53(1):9-17
In the central part of the East China Sea, the activity of CO2 in the surface water and total carbonate, pH and alkalinity in the water column were determined in winter and autumn of 1993.
The activity of CO2 in the continental shelf water was about 50 ppm lower than that of surface air. This decrease corresponds to the absorption
of about 40 gC/m2/yr of atmospheric CO2 in the coastal zone or 1 GtC/yr in the global continental shelf, if this rate is applicable to entire coastal seas. The normalized
total carbonate contents were higher in the water near the coast and near the bottom. This increase toward the bottom may
be due to the organic matter deposited on the bottom. This conclusion is supported by the distribution of pH. The normalized
alkalinity distribution also showed higher values in the near-coast water, but in the surface water, indicating the supply
of bicarbonate from river water. The residence time of the East China Sea water, including the Yellow Sea water, has been
calculated to be about 0.8 yr from the excess alkalinity and the alkalinity input. Using this residence time and the excess
carbonate, we can estimate that the amount of dissolved carbonate transported from the coastal zone to the oceanic basin is
about 70 gC/m2/yr or 2 GtC/yr/area-of-global-continental-shelf. This also means that the rivers transport carbon to the oceans at a rate
of 30 gC/m2/yr of the coastal sea or 0.8 GtC/yr/ area-of-global shelf, the carbon consisting of dissolved inorganic carbonate and terrestrial
organic carbon decomposed on the continental shelf. 相似文献
10.
Song Jinming 《海洋学报(英文版)》1997,16(4):557-562
Binogeochemical process of major elements in sining particulate of Nansha coral reef lagoons,South TXBinogeochemicalprocessofm... 相似文献