南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

珠江口沉积物酸挥发性硫化物与重金属生物毒性的研究     

杨永强  陈繁荣  张德荣  张凌  吕莹 《热带海洋学报》2006,25(3):72-78

研究了2003年10月采于珠江口5个站位的沉积物剖面酸挥发性硫化物(AVS)和同时提取的重金属(SEM:Pb,Zn,Cu,Cd,Ni)。其中,站位1、2位于中滩,其沉积物的AVS含量变化范围较小,为0.25—4.06μmol.g-1;站位3、4位于西滩,其沉积物的AVS含量变化范围较大,为0—26.09μmol.g-1。中滩和西滩沉积物的AVS含量均随深度增加。西滩表层沉积物的AVS含量接近于零,这可能与该水域较强的底层流和沉积物的再悬浮作用有关。站位5位于珠江口外侧,其表层沉积物的AVS含量相对较高,且垂向变化较小,可能是还原性沉积物间歇性再悬浮后重新沉积的结果。站位1、2和5沉积物中同时提取的重金属含量大体在0.95±0.2μmol.g-1范围内,随深度增加略呈下降趋势;而西滩沉积物重金属含量相对较高,为1.43—2.42μmol.g-1,且在一定深度范围内随深度增加呈明显下降的趋势,表明珠江口西滩沉积物中的重金属污染有加重的趋势。对AVS/SEM摩尔比值和单个金属的毒性效应研究显示,珠江口内尤其是西滩的表层沉积物存在重金属污染,对其中生活的底栖生物具有潜在的毒性效应。  相似文献   

Seasonal dynamics of elemental sulfur in two coastal sediments   总被引：1，自引：0，他引：1  

Henning Troelsen  Bo Barker Jørgensen 《Estuarine, Coastal and Shelf Science》1982,15(3):255-266

A spectrophotometric method for elemental sulfur (S⁰) analysis without interference from other reduced sulfur compounds was adapted for the use in reducing sediments. The S⁰ distribution in two coastal sediments was studied regularly from summer to winter and compared to factors regulating the S⁰ accumulation, such as redox potentials, the rate of bacterial sulfide production and the general sulfur chemistry. Dense coatings of sulfur bacteria developed on the sediment surface of a sulfuretum which had an S⁰ concentration of up to 41 μmol S cm^?3. The 2·5-mm thick bacterial coating contained 40% of all S⁰ in the sediment. A more typical marine sediment with a few cm thick oxidized surface layer had an S⁰ maximum of 1–3 μmol S cm^?3 at 2–4 cm depth. The S⁰ maximum in both sediments increased from summer to winter as the sediments gradually became more oxidized. The deeper layers maintained a low S⁰ concentration. Most of the S⁰ in the upper few mm of a laboratory sulfuretum was present inside sulfur bacteria and actively migrated up and down with the bacteria depending upon the changing light and oxygen conditions.  相似文献   

河南桐柏县破山银矿和银洞坡金矿的硫同位素研究   总被引：1，自引：0，他引：1  

李红梅  魏俊浩  黄祥芝 《现代地质》2008,22(1):18-23

河南桐柏县围山城金银成矿带的破山银矿和银洞坡金矿位于河前庄背斜的轴部和两翼,围岩为歪头山岩组,矿体受地层和构造的双重控制。两个矿床的矿石硫同位素δ34S值变化范围很窄,位于-1.8‰～5.3‰之间,具塔式效应,与围岩的硫同位素组成类似,具有深源硫的特征,由混合总体筛分可推测围岩提供了大部分硫源,破山银矿δ34S∑S为2.8‰左右。同时赋矿围岩的Au、Ag含量远远高于地壳丰度,因此可推断成矿物质主要来源于围岩歪头山岩组。  相似文献   

Interaction of copper with fatty acids in Soxhlet extraction and its influence     

Ming Jin  Yanqing Xia  Tianzhu Lei  Junli Qiu  Rui Zhang 《中国地球化学学报》2008,27(2):157-160

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.  相似文献   

Isotopes and Geochronology of the Meixian-type Pb-Zn-(Ag)Deposits,Central Fujian Rift,South China:Implications for Geological Events     

FENG Chengyou  ZHANG Dequan  LI Daxin  SHE Hongquan  DONG Yingjun 《《地质学报》英文版》2008,82(4):826-837

Central Fujian Rift is another new and important volcanogenic massive sulfide Pb-Zn polymetallic metallogenetic belt. In order to find out the material genesis and mineralization period of Meixian-type Pb-Zn-Ag deposits, S and Pb isotope analysis and isotope geochronology of ores and wall rocks for five major deposits are discussed. It is concluded that the composition of sulfur isotope from sulfide ore vary slightly in different deposits and the mean value is close to zero with the 834S ranging from -3.5‰ to ＋5.6‰ averaging at ＋2.0‰, which indicates that the sulfur might originate from magma or possibly erupted directly from volcano or was leached from ore-hosted volcanic rock. The lead from ores in most deposits displays radioactive genesis character （206pb/204pb〉18.140, 207Pb/204pb〉15.584, 208pb/204pb〉38.569） and lead isotope values of ores are higher than those of wall rocks, which indicates that the lead was likely leached from the ore-hosted volcanic rocks. Based on isotope data, two significant Pb-Zn metallogenesis are delineated, which are Mid- and Late-Proterozoic sedimentary exhalative metailogenesis （The single zircon U-Pb, Sm-Nd isochronal and Ar-Ar dating ages of ore- hosted wall rocks are calculated to be among 933-1788 Ma.） and Yanshanian magmatic hydrothermal superimposed and alternated metallogenesis （intrusive SHRIMP zircon U-Pb and Rb-Sr isochronal ages between 127-154 Ma）.  相似文献   

Distribution Characteristics of Sulfur and the Main Harmful Trace Elements in China’s Coal     

TANG Shuheng  SUN Shenglin  QIN Yong  JIANG Yaof  WANG Wenfeng 《《地质学报》英文版》2008,82(3):722-730

To promote the rational development and use of clean coal resources in China, data on the regional and age distribution of sulfur, arsenic and other harmful elements in Chinese coal was broadly collected, tested for content, and analyzed. Coal in northwestern China is characterized by low to extremely low levels of sulfur; the coal of the Taiyuan Formation in northern China mainly has high-sulfur content; that of the Shanxi Formation is mainly characterized by low sulfur coal; and the Late Permian coal in southern China has overall higher sulfur content; other regions have low sulfur coal. The average content of harmful trace elements in the bulk of China＇s coal is similar to the corresponding content in the coal of the North America and the rest of the world, whereas the content of various elements （Hg, Sb and Se） is different in magnitude to the corresponding percentage in the crust. The average content of the elements Cr, Se, Co, Be, U, Br in Late Permian coal in S China ranks first in the country whereas the average content of Hg and CI in the coals of Late Carboniferous to Early Permian age in N China are the highest. The average content of Mn in Early and Middle Jurassic coal is higher in NW China. The high content of harmful elements in some coal should cause particular concern both in the development and utilization of coal.  相似文献   

On the pH-dependent formation constants of iron(III)-sulfur(IV) transient complexes     

Eric A. Betterton 《Journal of Atmospheric Chemistry》1993,17(4):307-324

An experimental study is described of Fe(III)-S(IV) formation constants measured as a function of pH (1–3), ionic strength (0.2–0.5 M) and [Fe(III)] _T (2.5–5.0×10^–4 M) using a continuous-flow spectrophotometric technique to make observations 160 ms after mixing. Preliminary experiments using pulse-accelerated-flow (PAF) spectrophotometry to measure rate constants on a microsecond timescale are also described. The conditional formation constant at 25 °C can be modeled with the following equation: {ie307-1} where {ie307-2}K ₇ andK ₈ can be interpreted as intrinsic constants for the coordination of HSO ₃ ^– by FeOH²⁺ and Fe³⁺, respectively, but until further evidence is obtained they should be regarded as fitting constants. PAF spectrophotometry showed that the initial reaction of Fe(III) with S(IV) (pH 2.0) is characterized by a second-order rate constant of 4×10⁶ M^–1 s^–1 which is comparable to rate of reaction of FeOH²⁺ with SO ₄ ^2– . However, the PAF results should be regarded as preliminary since unexpected features in the initial data indicate that the reaction may be more complex than expected.  相似文献   

甘肃代家庄铅锌矿的地质特征与找矿意义   总被引：4，自引：1，他引：4  

祝新友  汪东波  卫冶国  邱小平  王瑞廷 《地球学报》2006,27(6):595-602

位于甘肃宕昌县的代家庄矿床曾被认为是西成矿田铅锌找矿的重大进展,矿床产于秦岭西成盆地西北端泥盆系浅海相的富含生物化石的细碎屑岩—灰岩中。矿体不规则受NW向断裂的控制,呈角砾状分布于下部碎屑岩与上部厚层灰岩界面附近灰岩一侧。矿石的矿物共生组合为闪锌矿 方铅矿 少量黄铁矿 少量白铁矿 方解石,不含石英。硫化物发育大量的胶状、球粒状、草霉状微晶结构,部分显现出微生物化石结构特点。对代家庄与西成主要类型铅锌矿床地质地球化学特征的对比发现,二者在容矿围岩沉积环境、矿石形态、结构构造以及同位素地球化学等多方面存在明显的差异,代家庄矿床成因属于碳酸盐岩容矿的低温热液矿床,不同于西成矿田的主要SEDEX类型。主要控矿因素为灰岩—碎屑界面附近、NW向断裂等。  相似文献   

Variability of sulfur along the coastal salt marshes, Quanzhou Bay, China     

《中国地球化学学报》2006,25(B08):11-11

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