阿拉尔河悬浮物对铀的吸附影响研究          下载免费PDF全文

钟翼  许建新  韩积斌  徐凯 《盐湖研究》2020,28(1):112-122

为了解阿拉尔河悬浮物对铀的吸附特性,通过静态吸附实验,研究了吸附时间、pH值、温度和铀初始浓度等因素对模拟含铀水中U(VI)去除率的影响,并从热力学和动力学方面对吸附过程进行了分析。结果表明,在T=25℃,溶液初始pH=7,接触时间为16 h时,悬浮物对铀的平衡吸附率最佳,为95.48%。随着铀初始浓度的增加,吸附量增加,但吸附率随之下降,升高温度有利于铀的吸附。铀在悬浮物上的吸附过程符合Langmuir等温吸附方程,说明悬浮物对铀为单分子层吸附,且化学吸附占主导地位。吸附动力学过程可用准二级吸附动力学模型描述,表明吸附主要受动力学控制,由两个以上步骤共同控制。FTIR和EDS分析结果表明,吸附过程中铀主要与悬浮物表面活性基团螯合并以表面络合吸附为主。吸附前后的能谱对比分析表明,吸附过程中存在离子交换行为。因此,悬浮物对铀的吸附机理是以表面络合吸附和离子交换为主、物理吸附为辅的混合吸附过程。  相似文献   

A fully coupled THM model based on a non‐equilibrium thermodynamic approach and its application          下载免费PDF全文

Z. Zhang  X. Cheng 《国际地质力学数值与分析法杂志》2017,41(4):527-554

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The influence of coupled physical swelling and chemical reactions on deformable geomaterials     

Yue Ma  Xiao‐Hui Chen  Lee J. Hosking  Hai‐Sui Yu  Hywel R. Thomas  Simon Norris 《国际地质力学数值与分析法杂志》2021,45(1):64-82

Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials.  相似文献   

Grain‐scale pressure variations and chemical equilibrium in high‐grade metamorphic rocks     

L. Tajčmanová  Y. Podladchikov  R. Powell  E. Moulas  J.C. Vrijmoed  J.A.D. Connolly 《Journal of Metamorphic Geology》2014,32(2):195-207

In the classical view of metamorphic microstructures, fast viscous relaxation (and so constant pressure) is assumed, with diffusion being the limiting factor in equilibration. This contribution is focused on the only other possible scenario – fast diffusion and slow viscous relaxation – and brings an alternative interpretation of microstructures typical of high‐grade metamorphic rocks. In contrast to the pressure vessel mechanical model applied to pressure variation associated with coesite inclusions in various host minerals, a multi‐anvil mechanical model is proposed in which strong single crystals and weak grain boundaries can maintain pressure variation at geological time‐scales in a polycrystalline material. In such a mechanical context, exsolution lamellae in feldspar are used to show that feldspar can sustain large differential stresses (>10 kbar) at geological time‐scales. Furthermore, it is argued that the existence of grain‐scale pressure gradients combined with diffusional equilibrium may explain chemical zoning preserved in reaction rims. Assuming zero net flux across the microstructure, an equilibrium thermodynamic method is introduced for inferring pressure variation corresponding to the chemical zoning. This new barometric method is applied to plagioclase rims around kyanite in felsic granulite (Bohemian Massif, Czech Republic), yielding a grain‐scale pressure variation of 8 kbar. In this approach, kinetic factors are not invoked to account for mineral composition zoning preserved in rocks metamorphosed at high grade.  相似文献   

A bounding surface model for anisotropically overconsolidated clay incorporating thermodynamics admissible rotational hardening rule     

Yanni Chen  Zhongxuan Yang 《国际地质力学数值与分析法杂志》2020,44(5):668-690

A bounding surface model is formulated to simulate the behavior of clays that are subject to an anisotropic consolidation stress history. Conventional rotational hardening is revisited from the perspective of thermodynamics. As the free energy cannot be accumulated infinitely upon critical state failure, the deviatoric back stress must vanish. This requires the rotated yield surface to be turned back to eventually align on the hydrostatic axis in the stress plane. Noting that most of the previous propositions violate this restriction, an innovative rotational hardening rule is formulated that is thermodynamically admissible. The bounding surface framework that employs the modified yield surface is applied to simulate elastoplastic deformations for overconsolidated clays, with which the overprediction of strength on the “dry” side can be greatly improved with reasonable results. Other important features, including contractive or dilative response and hardening or softening behavior, can also be well-captured. It has been shown that the model can simulate three types of reconstituted clays that are sheared with initial conditions over a wide range of anisotropic consolidation stress ratios and overconsolidation ratios under both triaxial undrained and drained conditions. Limitations and potential improvement of the model regarding the fabric anisotropy at critical state have been discussed.  相似文献   

Effect of grain‐scale pressure variations on garnet growth: a numerical approach          下载免费PDF全文

X. Zhong  J.C. Vrijmoed  L. Tajčmanová 《Journal of Metamorphic Geology》2017,35(1):19-33

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Thermodynamic processes of lake ice and landfast ice around Zhongshan Station, Antarctica     

LEI RuiBo  LI ZhiJun  ZHANG ZhanHai  CHENG YanFeng 《极地研究(英文版)》2011,(3):143-152

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Energy and first law of thermodynamics for Born—Infeld—anti-de-Sitter black hole     

魏益焕 《海洋学报(英文版)》2010,29(9)

We calculate the local energy and the energy density of the Reisner--Norstrõm--anti-de-Sitter black hole, study the first law of thermodynamics and show the Smarr formula for the Born--Infeld--anti-de-Sitter black hole. Applying the first law of thermodynamics to the black hole region, we analyse the three energy exchange processes between the black hole region and the outer and the inner regions.  相似文献   

Are peatlands in different states with respect to their thermodynamic behaviour? A simple test of peatland energy and entropy budgets     

Fred Worrall  Ross Morrison  Chris Evans  Joerg Kaduk  Susan Page  Alex Cumming  Mark Rayment  Nicholas Kettridge 《水文研究》2021,35(12):e14431

Whilst all ecosystems must obey the second law of thermodynamics, these physical bounds and controls on ecosystem evolution and development are largely ignored across the ecohydrological literature. To unravel the importance of these underlying restraints on ecosystem form and function, and their power to inform our scientific understanding, we have calculated the entropy budget of a range of peat ecosystems. We hypothesize that less disturbed peatlands are ‘near equilibrium’ with respect to the second law of thermodynamics and thus respond to change by minimizing entropy production. This ‘near equilibrium’ state is best achieved by limiting evaporative losses. Alternatively, peatlands ‘far-from-equilibrium’ respond to a change in energy inputs by maximizing entropy production which is best achieved by increasing evapotranspiration. To test these alternatives this study examined the energy balance time series from seven peatlands across a disturbance gradient. We estimate the entropy budgets for each and determine how a change in net radiation (ΔR_n) was transferred to a change in latent heat flux (ΔλE). The study showed that: (i) The transfer of net radiation to latent heat differed significantly between peatlands. One group transferred up to 64% of the change in net radiation to a change in latent heat flux, while the second transferred as little as 27%. (ii) Sites that transferred the most energy to latent heat flux were those that produced the greatest entropy. The study shows that an ecosystem could be ‘near equilibrium’ rather than ‘far from equilibrium’.  相似文献   

变质作用p-T-t轨迹的研究方法与进展          下载免费PDF全文

魏春景 《地学前缘》2011,18(2):1-16

变质作用p T t轨迹理论的提出完全改变了人们对变质作用过程的认识。地壳加厚区(造山带)内区域变质作用发生于地壳从热扰动到热松弛的动态演化过程中,岩石的p T t轨迹是地壳加厚的方式及机制、热松弛速率和岩石折返速率的综合函数。一维热模拟假设引起热扰动的构造作用在瞬间完成,岩石在折返过程中开始变质作用演化。二维热模拟结果表明在地壳加厚过程中(岩石埋藏阶段)伴随明显热效应,岩石在折返过程中有少量加热,达到温度峰值。反演变质作用的p T t轨迹包括3种方法：传统地质温压计方法,吉布斯/微分热力学方法和变质相图方法。无论哪种方法,都必须以详细岩相学研究为基础,在岩石中划分出两期以上矿物组合。传统地质温压计方法被广泛使用,但在确定不同期次矿物组合的平衡和p T条件上有若干不确定性。吉布斯/微分热力学方法理论上非常完善,依据矿物(石榴石)的生长环带计算岩石的p T t轨迹,但是由于难以确定矿物生长阶段的矿物组合变化,以及缺少复杂固溶体的活度模型等,致使该方法实用性较差。目前反演岩石p T t轨迹的最好方法是变质相图方法,该方法依据p T视剖面图上矿物等值线温压计,模拟由矿物的世代关系和生长环带所记录的p T条件变化,并可以定量模拟变质过程中的矿物组合演化、变质反应和流体行为。对不同中压型变质带和超高压型地体中岩石p T t轨迹的反演模拟表明,岩石在构造埋藏阶段应伴随明显热效应,发生一系列递增变质作用,几乎同时达到压力与温度峰值,岩石折返过程以等温降压型(ITD)为主。这与一维热模拟结果很不相同,而与二维热模拟结果大体相似,但一般折返速率更快。  相似文献