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1.
Tephra dispersed during the Millennium eruption (ME), Changbaishan Volcano, NE China provides one of the key stratigraphic links between Asia and Greenland for the synchronization of palaeoenvironmental records. However, controversy surrounds proximal-distal tephra correlations because (a) the proposed proximal correlatives of the distal ME tephra (i.e. B–Tm) lack an unequivocal chronostratigraphic context, and (b) the ME tephra deposits have not been chemically characterized for a full spectrum of element using grain-specific techniques. Here we present grain-specific glass chemistry, including for the first time, single grain trace element data, for a composite proximal sequence and a distal tephra from Lake Kushu, northern Japan (ca. 1100 km away from Changbaishan). We demonstrate a robust proximal-distal correlation and that the Kushu tephra is chemically associated with the ME/B–Tm. We propose that three of the proximal pyroclastic fall units were erupted as part of the ME. The radiocarbon chronology of the Kushu sedimentary record has been utilised to generate a Bayesian age-depth model, providing an age for the Kushu tephra which is consistent with high resolution ages determined for the eruption and therefore supports our geochemical correlation. Two further Bayesian age-depth models were independently constructed each incorporating one of two ice-core derived ages for the B–Tm tephra, providing Bayesian modelled ages of 933–949 and 944–947 cal AD (95.4%) for the Kushu tephra. The high resolution ice-core tephra ages imported into the deposition models help test and ultimately constrain the radiocarbon chronology in this interval of the Lake Kushu sedimentary record. The observed geochemical diversity between proximal and distal ME tephra deposits clearly evidences the interaction of two compositionally distinct magma batches during this caldera forming eruption. 相似文献
2.
Geochemical analysis of fine grained (<20 μm) tephra found in ice cores is inherently difficult, due to the typically low number and small size of available particles. Ice core tephra samples require specialized sample preparation techniques to maximize the amount of information that can be gained from these logistically limited samples that may provide important chronology to an ice record, as well as linking glacial, marine and terrestrial sediments. We have developed a flexible workflow for preparation of tephra and cryptotephra samples to allow accurate and robust geochemical fingerprinting, which is fundamental to tephrochronology. The samples can be prepared so that secondary electron imagery can be obtained for morphological characterization of the samples to ensure that the sample is tephra-bearing and then the sample can be further prepared for quantitative electron microprobe analysis using wavelength dispersive techniques (EMP-WDS), scanning electron microscopy with energy dispersive spectrometry (SEM-EDS), laser ablation inductively coupled mass spectrometry (LA-ICP-MS) or secondary ion mass spectrometry (SIMS). Some samples may be too small for typical instrumentation conditions to be used (i.e. 20 μm beam on the EMP) to analyze for geochemistry and we present other techniques that can be employed to obtain accurate, although less precise, geochemistry. Methods include analyzing unpolished tephra shards less than 5 μm in diameter with a 1 μm beam on an SEM; using the “broad beam overlap” EMP method on irregular particles less than 20 μm in diameter, and analyzing microlitic shards as well as aphyric shards using EMP to increase the number of analyzed shards in low abundance tephra layers. The methods presented are flexible enough to be employed in other geological environments (terrestrial, marine and glacial) which will help maximize and integrate multiple environments into the overall tephra framework. 相似文献
3.
Cryptotephrochronology, the use of hidden, diminutive volcanic ash layers to date sediments, has rarely been applied outside western Europe but has the potential to improve the tephrochronology of other regions of the world. Here we present the first comprehensive cryptotephra study in Alaska. Cores were extracted from five peatland sites, with cryptotephras located by ashing and microscopy and their glass geochemistry examined using electron probe microanalysis. Glass geochemical data from nine tephras were compared between sites and with data from previous Alaskan tephra studies. One tephra present in all the cores is believed to represent a previously unidentified eruption of Mt. Churchill and is named here as the ‘Lena tephra’. A mid-Holocene tephra in one site is very similar to Aniakchak tephra and most likely represents a previously unidentified Aniakchak eruption, ca. 5300-5030 cal yr BP. Other tephras are from the late Holocene White River eruption, a mid-Holocene Mt. Churchill eruption, and possibly eruptions of Redoubt and Augustine volcanoes. These results show the potential of cryptotephras to expand the geographic limits of tephrochronology and demonstrate that Mt. Churchill has been more active in the Holocene than previously appreciated. This finding may necessitate reassessment of volcanic hazards in the region. 相似文献
4.
Macro- and crypto-tephra layers deposited in European climate archives during the Last Glacial-Interglacial Transition (LGIT ca. 16–8 ka) have become increasingly important as a means to robustly correlate palaeoclimate records, and to test the spatial and temporal synchronicity of climatic transitions. However, correlations between climate archives are currently limited by the number of tephra-linkages that can be made. This disparity in the observed distributions of tephras may lie with methodological limitations relating to the resolution of cryptotephra refinement within palaeoclimate records. Here we present new data from Quoyloo Meadow, Orkney Mainland, Scotland, where nine tephra horizons and ten chemically distinct tephra populations have been identified and correlated to known eruptions during the LGIT. Three of the tephras; the Hässeldalen, Hovsdalur and the Fosen are characterised and placed into a reliable tephrostratigraphy for the first time in the British Isles. The detection of new tephra layers in this case is thought to reflect modifications to the sampling approach applied here. The resulting tephrostratigraphy is used to produce an age model with centennial-scale precision, providing new age estimates for three poorly dated tephras. The chronology rivals the output of more traditionally dated radiocarbon chronologies, and illustrates the potential for tephra to develop robust age-depth models for carbonate sequences. 相似文献
5.
We detected late Pleistocene cummingtonite-bearing cryptotephras in loess deposits in NE Japan and correlated them with known tephras elsewhere by using major-element compositions of the cummingtonite. This is the first time cryptotephras have been identified by analysis of a crystal phase rather than glass shards. In central NE Japan, four cummingtonite-bearing tephras, the Ichihasama pumice, the Dokusawa tephra, the Naruko–Nisaka tephra, and the Adachi–Medeshima tephra, are present in late Pleistocene loess deposits. Because the cummingtonite chemistry of each tephra is different and characteristic, it is potentially a powerful tool for detecting and identifying cryptotephras. An unidentified cummingtonite-bearing cryptotephra previously reported to be present in the late Pleistocene loess deposits at Kesennuma (Pacific coast) did not correlate with any of the known cummingtonite-bearing tephras in central NE Japan, but instead with the Numazawa–Kanayama tephra (erupted from the Numazawa caldera, southern NE Japan), although Kesennuma is well beyond the previously reported area of the distribution of the Numazawa–Kanayama tephra. Three new cummingtonite-bearing cryptotephras in the mid and late Pleistocene loess deposits (estimated to be less than 82 ka, 100–200 ka, and ca. 250 ka) on the Isawa upland were also detected. 相似文献
6.
Chunqing Sun Gill Plunkett Zeyang Zhu Lei Zhang Bin Zhang Di Zhang Qian Mao Haitao You Luo Wang Guoqiang Chu Jiaqi Liu 《第四纪科学杂志》2021,36(7):1143-1148
Far-travelled ash layers from explosive volcanic eruptions can provide invaluable marker horizons for dating and correlating regional to global sedimentary archives. Here, we present a new cryptotephra associated with the ~5.9 cal ka bp Towada-Chuseri eruption (To-Cu) in a peat sediment record from northeast China. This tephra exhibits a rhyolitic glass composition that can be distinguished from other widespread tephra layers around the region of Japan and northeast China. Our findings extend the known range of this ash significantly, making it now traceable about 1200 km from its source, Towada volcano, Japan. Notably, this tephra provides an important isochron for synchronising palaeoenvironmental studies during the mid-Holocene period from the western Pacific, central Japan, Japan Sea and northeast China. 相似文献
7.
The Mt. Edgecumbe Volcanic Field (MEVF), located on Kruzof Island near Sitka Sound in southeast Alaska, experienced a large multiple-stage eruption during the last glacial maximum (LGM)-Holocene transition that generated a regionally extensive series of compositionally similar rhyolite tephra horizons and a single well-dated dacite (MEd) tephra. Marine sediment cores collected from adjacent basins to the MEVF contain both tephra-fall and pyroclastic flow deposits that consist primarily of rhyolitic tephra and a minor dacitic tephra unit. The recovered dacite tephra correlates with the MEd tephra, whereas many of the rhyolitic tephras correlate with published MEVF rhyolites. Correlations were based on age constraints and major oxide compositions of glass shards. In addition to LGM-Holocene macroscopic tephra units, four marine cryptotephras were also identified. Three of these units appear to be derived from mid-Holocene MEVF activity, while the youngest cryptotephra corresponds well with the White River Ash eruption at ∼ 1147 cal yr BP. Furthermore, the sedimentology of the Sitka Sound marine core EW0408-40JC and high-resolution SWATH bathymetry both suggest that extensive pyroclastic flow deposits associated with the activity that generated the MEd tephra underlie Sitka Sound, and that any future MEVF activity may pose significant risk to local population centers. 相似文献
8.
火山灰年代学:原理与应用 总被引：1，自引：0，他引：1
火山灰(2mm)等时标志层是火山灰年代学研究的基础。火山灰地层的直接或间接测年依赖于火山灰中存在合适的原生矿物(如:透长石、锆石、磷灰石)或外来物质(如:炭化木)。然而大多数火山灰沉积层,尤其是远源火山灰,其主要由岩浆源碎屑构成,开展测年显得十分困难。利用火山玻璃(岩浆)的地球化学,是一种被广泛应用的替代性方法。火山玻璃作为岩浆源物质普遍出现在各类近源、远源可见火山灰层和显微火山灰中,其主量、微量元素含量和特定的同位素组成能被电子、激光和离子探针技术准确测定。近源-远源玻璃化学成分的相互匹配,使得火山灰等时标志层得以在时间和空间上相互关联,构成有力的地层学工具,用以同步各类环境、考古和火山活动记录。近源火山沉积和远源火山灰层中的年龄信息得以实现交叉验证和整合。远源海洋、湖泊沉积中的相对年龄信息(氧同位素地层学,年纹层年代学)也为揭示火山活动、古环境变化和考古学事件的时间顺序提供了可能。火山灰年代学在地球科学中应用广泛,尤其是对于第四纪研究,其在同步各类记录从而评估火山活动、气候/环境变化和人类演化/迁移的因果关系中具有至关重要的作用。 相似文献
9.
《Proceedings of the Geologists' Association. Geologists' Association》2017,128(4):523-530
Tephrochronology and especially crypto-tephrochronology is an established chronological technique employed in a range of depositional environments in Europe and beyond. During the late Quaternary, Icelandic cryptotephra deposits are widely found in palaeorecords across northern latitudes of Europe e.g. Scotland, Ireland, Norway, Sweden and the Faroe Islands but are sporadic in southerly latitudes as distance from Iceland increases. As yet, very few Icelandic cryptotephras have been identified in Wales or southern England which may well reflect the geographical limit of Icelandic tephra distribution. Here, however, we report the discovery of an Icelandic cryptotephra deposit within a sediment sequence retrieved from the Pant-y-Llyn turlough (Carmarthenshire, south Wales), the only known turlough in Britain. Turloughs are groundwater-fed ephemeral lakes associated with limestone bedrock and can accumulate sediments that may yield records suitable for palaeoreconstructions. A discrete peak of glass shards originating from the Askja-S eruption is identified in the sediment record. This discovery extends the distribution of this early Holocene eruption giving new insight into its dispersal patterns and also indicates that sedimentary sequences from sites in these more southerly latitudes are valuable repositories for ash preservation. Furthermore, its discovery within a carbonate-rich sequence provides a minimum age constraint on the timing of sediment accumulation and provides an alternative tool for what is typically a problematic dating environment. 相似文献
10.
We present results from a cryptotephra investigation performed at a high resolution (0.5 cm) on sediments from Körslättamossen in southernmost Sweden. Six peak concentration levels were detected and extracted for geochemical analysis by electron probe microanalyser. Five of these levels were successfully analysed and we propose correlations to the Hässeldalen Tephra, the Vedde Ash, and the Laacher See Tephra (adding new analysis results for the first geochemically confirmed finding of the latter in Sweden), as well as an undetermined Borrobol-type tephra. The tephra identifications were combined with radiocarbon dated macrofossils in order to create an age model for the sampled sediments based on Bayesian methods. Stratigraphical and chronological results were found to concur with a previous study of the site and our results form the basis for discussion concerning the issues surrounding Lateglacial Borrobol-type tephras, of which we suggest further review in order to unlock these tephras’ full potential for Quaternary studies. 相似文献