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1.
作为战略性矿产资源之一,高纯石英已广泛应用于集成电路、半导体芯片、太阳能等高新技术产业中,但是能够生产高纯石英的原料矿床极为稀缺,我国尤为紧缺高纯石英原料矿。鄂东南地区是湖北省脉石英矿床的主要分布区。本文针对鄂东南付家山脉石英矿床,通过光学显微镜、扫描电子显微镜观察了脉石英的脉石矿物类型和包裹体特征,采用电感耦合等离子发射光谱法(ICP-OES)对原矿进行了微量元素分析,旨在获得付家山脉石英矿床的杂质元素特征,进而评价矿床用作高纯石英原料的潜力。结果表明,付家山脉石英矿石SiO2含量大于99.95%,杂质元素主要为Al、K、Fe、Ti、Ca等,脉石矿物主要有白云母、钾长石、铁氧化物等,流体包裹体较为发育。杂质元素分析结果表明,付家山脉石英原矿质量达到低端高纯石英标准,经传统工艺提纯后,可能具有生产中高端高纯石英的潜力。 相似文献
2.
Characteristics of mineral element content of alpine vegetation
in permafrost region on Qinghai-Tibetan Plateau 总被引：1，自引：0，他引：1
The content characteristics of 16 elements (Al, Ca, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Sr, and Zn) in 23 plant species
collected from the Qinghai-Tibetan Plateau permafrost region were investigated using ICP-OES. Results show that the average
contents of Ca, K, Mg, Fe and P were higher than 1,000 mg/kg, those of Al, Na, Zn and Cr ranged between 10–1,000 mg/kg and
those of Cu, Li, Pb and Mo were less than 10 mg/kg. The levels of Al, Ca, K, Mg and Na were within the scope of the reported
terrestrial plant element content, those of Sr, Fe and Cr were higher than the average of the terrestrial plants and the maximum
content of Mn was higher than the upper limit of the reported Mn content. The main character of the element content was of the
Ca>K type, however, in terms of Cyperaceae species the element content character was K>Ca type. The contents of Ca, Li, Mg
and Sr in Gramineae and Cyperaceae species were higher than those in other species and the contents of Ca, K, Mg, Fe, P, Al and
Na in all collected plants were higher than those of other elements. Zn had weak variability with the lowest coefficient (i.e.,
7.81%), while other elements had strong variability. The ratio of maximum content to minimum content indicated Ca and K had
less change than other elements in the Qinghai-Tibetan Plateau permafrost region. Element content of alpine vegetation in the
Qinghai-Tibetan Plateau permafrost region mainly shows a positive correlation, among which the correlation coefficient between
Al and Pb, Al and Fe, Mo and Cr, Pb and Fe, Sr and Li were higher than 0.9, and negative correlation had no statistical significance.
The correlation between Al and Fe, Mg, Mn in the Qinghai-Tibetan Plateau permafrost region were consistent with that reported
in Kunlun Mountains. 相似文献
3.
A modified method for biogenic silica determination 总被引：1，自引：0，他引：1
We describe a modified method for the determination of biogenic silica (BSi) in lacustrine sediment samples with BSi concentrations
>0.5% SiO2 (detection limit). To speed up the leaching procedure (48 samples per day), we suggest the use of Teflon autoclaves that
can be left unattended (no stirring of the solution) for 3 h at 100°C in an oven. We suggest a volume correction by Na measurement
to account for volume errors during pipetting off a hot solution. We also propose to carry out a correction for minerogenic
silica by the simultaneous determination of Al in the leachate. Analytical precision and accuracy of the proposed method are
2.4% (relative standard deviation) and 70–110% recovery (relative to the mean of four international reference sediment samples),
respectively. Additionally, we demonstrate that pre-treatment of the samples with H2O2 and/or HCl prior to alkaline leaching is not necessary for all samples. Due to the great diversity of lacustrine and marine
sediments, however, the pre-treatment procedure should be tailored for samples from different sites. 相似文献
4.
基体效应是化学分析中常见的干扰之一,但对其作用机理目前还不清楚.在碱溶酸处理直接用ICP-OES法测定钇和锆的分析中,大量基体进入测定溶液,致使测定结果偏低.本文采用多元统计的方法对测定结果和基体组分含量进行处理,求得了测定误差的一些模型,以评价这类基体效应,并校正测定结果. 相似文献
5.
电感耦合等离子体发射光谱法测定锑精矿中多种微量元素 总被引：3，自引：2，他引：1
建立了电感耦合等离子体发射光谱法(ICP-OES)测定锑精矿中10种微量元素Zn、Cd、Pb、Si、Mn、Fe、Mg、Ca、Cu、Ag的快速定量分析方法。探讨了锑精矿的溶样方法,发现采用氢溴酸挥锑后用浓酸溶解样品,稳定性较好。优化了仪器参数条件,对样品中各元素做加标回收试验。与原子吸收光谱法测定比较,方法检出限低,精密度(RSD,n=11)均小于6%,回收率为89.4%~108.0%,能满足进出口对锑精矿中杂质元素的检测要求。 相似文献
6.
采用电感耦合等离子体发射光谱法(ICP-OES)法测定氧化钕中杂质氧化镍的含量,得到氧化镍含量为0.002 7%,分析了检测过程中的各个影响因素,并对测量结果的可靠性以相对扩展不确定度表示(Urel=12%,k=2)。相对不确定度分量计算结果表明,标准曲线拟合时引入的相对不确定度分量最大,urel(c2)=5.639%,其次为标准溶液配制过程中引入的相对不确定度分量urel(c1)=0.879%。本文可为相关检测人员的结果不确定度分析提供参考。 相似文献
7.
8.
为优化电感耦合等离子体发射光谱仪(ICP-OES)测试微量生物碳酸盐中元素含量的工作条件, 在Thermo-Fisher 公司生产的iCAP 6300 Radial 型ICP-OES 上, 对1 050 组仪器条件、32 种不同组成的标准溶液、36 个谱线对和两种仪器校正工作曲线进行了测试; 借助开源科学计算软件Scilab 数据插值和可视化技术对测试数据进行了比较分析。结果表明, 该仪器测试微量生物碳酸盐中Mg/Ca 和Sr/Ca 比值的最佳条件为: 雾化器, 0.1 mL/min 同心雾化器; 冷却气流量, 缺省设置12 L/min; 辅助气流量, 0.5L/min; 雾化气压力, 0.24 MPa; 蠕动泵速, 16 r/min; RF 功率, 1 000 W; 观察高度, 15 mm; 谱线, Ca373.690 nm, Mg 279.553 nm {121}, Sr 407.771 nm; 仪器校准工作曲线为强度-浓度工作曲线。 相似文献
9.
用传统的滴定法与ICP-OES相结合的方法测定含铜高的铁矿石中的铁,采用过氧化钠融矿,使铁能得到完全熔融,全部转移到溶液中,然后分取上机测定。此法自动化程度高,精密度和准确度均符合要求。 相似文献
10.
硼作为海水中的重要组分,其准确测定对海洋环境生物地球化学过程研究具有重要意义。海水中硼的常用测定方法具有前处理步骤繁琐、耗时长、样品易被污染、灵敏度低等缺点,不适于大批量海水样品的准确测定。为剔除海水高盐基体效应及干扰,本文运用电感耦合等离子体发射光谱法(ICP-OES),将海水样品进行稀释,采用标准加入法建立工作曲线,对海水中硼含量进行准确测定。正交实验显示,ICP-OES最佳工作条件为射频功率1400 W,雾化气流量0.7 L/min,观测高度14 mm,进样泵速1.5 m L/min。标准加入法标准曲线相关系数大于0.999,相对标准偏差为0.76%~1.27%,加标回收率为94.6%~101.8%,方法检出限为1.073μg/L。实际的海水样品分析表明,该方法可消除海水基体干扰,减少测定误差,并且前处理操作简单快速,化学试剂用量少,回收率高,精密度好,灵敏度高,可用于海水及其它高盐样品中硼含量的准确测定。 相似文献