Pyrite formation driven by MSW landfill leachate in the Madrid Basin, Spain     

Ricardo Castelló  Clemente Recio  Pilar Morillas  Carmen Vizcayno 《Environmental Geology》2008,54(4):679-688

The role of municipal solid waste (MSW) landfill leachate on the genesis of minor amounts of pyrite associated with gypsum in an otherwise predominantly evaporitic sequence was studied in geological and geochemical terms. The potential association between landfill leachate and the conditions required for bacterial reduction of sulfate and fixation of H₂S as pyrite were examined. The lithological column was generally found to contain little or no Fe. The δ³⁴S values for sulfates were consistent with previously reported data; however, the measured δ¹⁸O values were slightly higher. Sulfides disseminated in the marl/lutite exhibited higher δ³⁴S values (≈−8‰) than gypsum-coating pyrite crystals (δ³⁴S < −30‰). Dissolution of gypsum to sulfate and the supply of metabolizable organic matter and Fe required for H₂S fixation as sulfides may have originated from landfill leachate. Intermittent availability of leachate, a result of the precipitation regime, can facilitate sulfur disproportionation and lead to fractionations as high as   相似文献   

Can stable isotopes be used to monitor landfill leachate impact on surface waters?     

Jessica C. North  Russell D. Frew  Robert Van Hale 《Journal of Geochemical Exploration》2006,88(1-3):49

Bacterially mediated methanogenesis in municipal solid waste landfills has been shown to cause an enrichment of carbon stable isotope ratios of dissolved inorganic carbon and hydrogen stable isotope ratios of water in landfill leachate. In the present study, we investigate the universality of this enrichment in leachate obtained from four diverse landfill sites in New Zealand. At each site, surface water samples upstream and downstream of landfills were analysed to examine the applicability of stable isotope ratios as a tool for monitoring leachate contamination in landfill-associated streams. The design of leachate collection systems, operational history, and landfill location appeared to strongly influence leachate isotopic values and the effectiveness of isotope ratios as an environmental monitoring tool for surface water.  相似文献   

Tracing leachates at waste sites using geophysical and geochemical modelling     

Bo Olofsson  Hillevie Jernberg  Andreas Rosenqvist 《Environmental Geology》2006,49(5):720-732

Tracing leachates at landfills is usually carried out using either geophysical methods or chemical analyses of groundwater. There are often problems with fingerprinting pollution sources or clarifying the spreading pattern due to a wide variety of possibilities giving similar anomalies. The aims of the project were to evaluate the advantages of combining results from multigeophysical modelling and statistical/chemical modelling in order to identify pollution sources and the spreading pattern and to test a new technique for chemical fingerprinting. The project was carried out at a landfill in central Sweden using geophysical measurements and modelling of CVES, GPR and VLF as well as chemical modelling using M3 (multivariate mixing and mass balance calculations). The results indicate that by combining geophysical modelling and chemical calculations, the possibilities of fingerprinting the origin of pollution as well as delineating the spreading pattern are significantly increased.  相似文献   

3D behaviour of contamination in landfill sites using 2D resistivity/IP imaging: case studies in Portugal   总被引：2，自引：0，他引：2  

E. Martinho  F. Almeida 《Environmental Geology》2006,49(7):1071-1078

Aiming at defining a valid spatial contamination model, resistivity and induced polarization (IP) measurements were used to investigate contamination plumes in the vicinity of two municipal landfills (Ovar and ílhavo). Previous geophysical surveys and underground water samples confirmed the contamination. However 2D resistivity/IP surveys enabled in obtaining a more accurate spatial model. The Ovar survey consisted of two profiles with nine Wenner soundings each; the ílhavo survey was carried out along two individual lines using a Wenner standard pseudo-section. In both situations, negative IP values were found associated with positive IP values, which can be explained mainly by 2D or 3D geometric effects caused by the presence of the conductive plumes. The data were modelled using a 2D inversion program (RES2DINV) and the resulting resistivity and chargeability distributions were displayed as pseudo-sections. The resistivity and chargeability pseudo-sections define the contamination plumes and the sedimentary structure. These case studies illustrate the advantages of 2D resistivity/IP surveys for the mapping of shape and dimension of contamination associated with landfills.  相似文献   

Electromagnetic methods to characterize the Savoia di Lucania waste dump (Southern Italy)     

M. Bavusi  E. Rizzo  V. Lapenna 《Environmental Geology》2006,51(2):301-308

The aim of this work is the joint application and integration of non-invasive geoelectrical methods for studying the landfill of Savoia di Lucania (Southern Italy). This landfill for its engineering features and small dimensions (70 m × 30 m × 6 m) represents an optimal test site to assess a geophysical survey protocol for municipal solid waste landfills investigation and monitoring. The landfill of Savoia di Lucania has been built with a reinforced concrete material and coated with a high-density polyethylene (HDPE) liner. Three electrical resistivity tomographies (ERT), two self-potential (SP) map surveys and one induced polarization (IP) section have been performed, both in the surrounding area and inside the waste landfill. The geophysical investigations have well defined some buried boundaries of the landfill basin and localized the leachate accumulation zones inside the dumpsite. Comparison of our results with other engineering and geological investigations could be the key for evaluating the integrity of the HDPE liner. Finally, the joint use of the ERT, IP and SP methods seems to be a promising tool for studying and designing new monitoring systems able to perform a time-lapse analysis of waste landfill geometry and integrity.  相似文献   

The use of GPR and VES in delineating a contamination plume in a landfill site: a case study in SE Brazil   总被引：3，自引：0，他引：3  

Jorge L. Porsani  Walter M. Filho  Vagner R. Elis  Fisseha Shimeles  Joo C. Dourado  Helyelson P. Moura 《Journal of Applied Geophysics》2004,55(3-4):199-209

This paper presents the results of the application of the Ground Penetrating Radar (GPR) method, or Georadar, in outlining a zone of contamination due to solid residues at the waste burial site of Rio Claro in the state of São Paulo, SE Brazil. A total of eight GPR profiles with 50- and 100-MHz antennae were surveyed. Six profiles were located within the landfill site and the remaining two were outside. The main objective of the GPR survey was to evaluate the side extension of contamination. A Vertical Electric Sounding (VES) survey was performed at four points within the site in order to investigate the vertical extent of the contamination plume and to define the bottom of the landfill. Two additional VESs were done outside the landfill with the purpose of determining the top of the ground water table and the geoelectric stratigraphy of the background. From the interpretation of the GPR profiles, it was possible to locate the top of the contamination plume and to infer that it was migrating laterally beyond the limits of the waste disposal site. This was observed along the profile situated close to the highway SP-127, which was about 20 m from the limit of the site. The signature of the contaminant appears as a discontinuous reflector that is believed to be a shallow ground water table. The discontinuity is marked by a shadow zone, which is characteristic of conductive contaminant residues. The contamination did not move far enough to reach a sugar cane plantation located at approximately 100 m from the border of the site. In the regions free from contamination, the ground water table was mapped at approximately 10 m of depth, and it was characterized by a strong and continuous reflector. The radar signal penetrated deep enough and enabled the identification of a second reflector at approximately 14 m deep, interpreted as the contact between the Rio Claro and the Corumbataí formations. The contact is marked by the presence of gravel characterized by ferruginous concretes, which cause the strong amplitude reflection in the GPR profile. Within the landfill site, the quantitative interpretation of the VES results showed the contamination zone. The base of the landfill varies between 11 and 15 m deep. Outside the landfill site, the VES results showed no indication of contamination and allowed the determination of the top of the ground water table and the contact between the Rio Claro and the Corumbataí formations. The results of GPR and VES showed a good agreement and the integrated interpretations were supported by local geology and information from several boreholes, about 17 m depth, on average. The bottom of the landfill reaches a maximum of 14.5 m depth.  相似文献   

Environmental impact of an urban landfill on a coastal aquifer (El Jadida, Morocco)     

Amina Chofqi  Abedelkader Younsi  El Kbir Lhadi  Jacky Mania  Jacques Mudry  Alain Veron 《Journal of African Earth Sciences》2004,39(3-5):509

The El Jadida landfill is one among many uncontrolled dumping sites in Morocco with no bottom liner. About 150 tons/day of solid wastes from mixed urban and industrial origins are placed directly on the ground. At the site of this landfill, the groundwaters circulate deeply (10–15 m) in the Cenomanian rock (calcareous–marl), which is characterised by an important permeability from cracks. The soil is sand–clay characterized by a weak coefficient of retention.The phreatic water ascends to the bottom of three quarries, which are located within the landfill. These circumstances, along with the lack of a leachate collection system, worsen the risks for a potential deterioration of the aquifer.To evaluate groundwater pollution due to this urban landfill, piezometric level and geochemical analyses have been monitored since 1999 on 60 wells. The landfill leachate has been collected from the three quarries that are located within the landfill. The average results of geochemical analyses show an important polluant charge vehiculed by landfill leachate (chloride = 5680 mg l⁻¹, chemical oxygen demand = 1000 mg l⁻¹, iron = 23 000 μg l⁻¹). They show also an important qualitative degradation of the groundwater, especially in the parts situated in the down gradient area and in direct proximity to the landfill. In these polluted zones, we have observed the following values: higher than 4.5 mS cm⁻¹ in electric conductivity, 1620 and 1000 mg l⁻¹ respectively in chlorides and sulfate (), 15–25 μg l⁻¹ in cadmium, and 60–100 μg l⁻¹ in chromium. These concentrations widely exceed the standard values for potable water.Several determining factors in the evolution of groundwater contamination have been highlighted, such as (1) depth of the water table, (2) permeability of soil and unsaturated zone, (3) effective infiltration, (4) humidity and (5) absence of a system for leachate drainage. So, to reduce the pollution risks of the groundwater, it is necessary to set a system of collection, drainage and treatment of landfill leachates and to emplace an impermeable surface at the site of landfill, in order to limit the infiltration of leachate.  相似文献   

Landfill site selection based on reliability concepts using the DRASTIC method and AHP integrated with GIS – a case study of Bengaluru city,India     

L. G. Santhosh  G. L. Sivakumar Babu 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2018,12(3):234-252

The selection of landfill sites for municipal solid waste (MSW) disposal involves consideration of geological, hydrological and environmental parameters which exhibit large spatial variability. Therefore, it is necessary to define, to what extent the chosen sites are reliable such that the probability of environmental pollution and health risks to population is minimal. In the present study, groundwater vulnerability to contamination has been assessed using the standard DRASTIC method. The results showed that the study region has 9.45% of very less, 32.94% of less, 25.47% of moderate, 22.79% of high and 9.35% of very high vulnerable zones. The study also revealed that none of the landfills are located in safe zones. This suggests that it requires proper remedial measures to avoid environmental pollution. A landfill site selection process has been carried out using the Analytical Hierarchy Process integrated with Geographical Information System tools. The obtained results showed that only 3.59?km² (0.08%) of the total area is suitable for landfills. The reliability analysis of the site suitability revealed that landfills are located at unreliable locations where the probability of risk to environmental pollution is high. The presented approach assists decision-makers in selecting reliable locations for the safe disposal of MSW.  相似文献   

How does landfill leachate affect the chemical processes in a lake system downgradient from a landfill site?     

Thomas Striebel  Wolfgang Schäfer  Stefan Peiffer 《Aquatic Sciences - Research Across Boundaries》1991,53(4):346-366

A field study on the geochemical properties of a chemically-stressed limnic environment was performed in Lake Silbersee, which receives leachate water of high inorganic loading from an upgradient landfill site. The highly concentrated sulfate ion in groundwater, when entering the pore water system of the lake, gives rise to an intensive microbial sulfate reduction. A diagenetic approach was used to explain the existence of a marine-like aqueous system within a geologically slightly acidic aquifer, consisting of a well-buffered lake water and an alkalinity producing, excess sulphide containing sediment pore water system.  相似文献   

Application of integrated methods in mapping waste disposal areas   总被引：2，自引：0，他引：2  

Pantelis Soupios  Nikos Papadopoulos  Ilias Papadopoulos  Maria Kouli  Filippos Vallianatos  Apostolos Sarris  Thrassyvoulos Manios 《Environmental Geology》2007,53(3):661-675

An integrated suite of environmental methods was used to characterize the hydrogeological, geological and tectonic regime of the largest waste disposal landfill of Crete Island, the Fodele municipal solid waste site (MSW), to determine the geometry of the landfill (depth and spatial extent of electrically conductive anomalies), to define the anisotropy caused by bedrock fabric fractures and to locate potential zones of electrically conductive contamination. A combination of geophysical methods and chemical analysis was implemented for the characterization and management of the landfill. Five different types of geophysical surveys were performed: (1) 2D electrical resistance tomography (ERT), (2) electromagnetic measurements using very low frequencies (VLF), (3) electromagnetic conductivity (EM31), (4) seismic refraction measurements (SR), and (5) ambient noise measurements (HVSR). The above geophysical methods were used with the aim of studying the subsurface properties of the landfill and to define the exact geometrical characteristics of the site under investigation.  相似文献