广东雷州珍稀海洋生物国家级自然保护区水体和沉积物中石油类含量与分布特征          下载免费PDF全文

刘芳  柯盛  周立喜  陈成琼  陈耀 《海洋开发与管理》2020,37(1):69-74

为了探讨广东雷州珍稀海洋生物国家级自然保护区海域水体和沉积物中石油类的含量及其分布特征,文章于2017年和2018年分别对保护区海域的石油类进行了调查。结果表明,保护区表层水体石油类含量为0.003~0.066mg/L,平均含量为0.015mg/L,平均污染指数为0.30,保护区水体中的石油类基本符合一类海水水质标准。保护区表层沉积物中石油类含量为3.0~54.8mg/kg,平均值为11.109mg/kg,符合海洋沉积物第一类质量标准。保护区水体和沉积物中石油类含量的变化规律基本相似,但是沉积物中石油类含量的变化更大。根据调查数据分析,保护区水体中石油类的主要来源是保护区社区小型渔船航行排放的石油类,以及保护区周边渔船在航行过程排放的石油类扩散到保护区海域。  相似文献   

Numerical modeling of flow and morphology induced by a solitary wave on a sloping beach     

《Applied Ocean Research》2019

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A GIS-based approach for detecting pollution sources and bioavailability of metals in coastal and marine sediments of Chabahar Bay,SE Iran     

《Chemie der Erde / Geochemistry》2015,75(2):185-195

Chabahar Bay in SE of Iran is a shallow semi-enclosed environment affected by anthropogenic activities. In this paper, 19 sediment samples were collected and concentration of selected metals (Cu, Pb, Zn, Cd, Ni, Cr, Co, V and Fe) was determined using ICP-MS analytical method. Sediment samples from five stations were also selected for sequential extraction analysis and concentration of metals in each fraction was determined using ICP-OES. In order to investigate the environmental quality of Chabahar Bay, geographic information system (GIS) along with geochemical data, environmental indices and statistical analyses were used. Calculated contamination degree (C_d) revealed that most contaminated stations (Ch3, S1 and S3) are located SE of Chabahar Bay and contamination decreases in a NW direction. The S9 station, west of the bay, is also contaminated. High organic matter (OM) content in the sediments is most likely the result of fuel and sewage discharge from fishing vessels along with discharge of fishing leftovers. Significant correlation coefficient among OM, Fe, Cu, Pb, Zn and Cd seemingly reflects the importance of the role that OM and Fe oxy-hydroxides play in the metals mobility. The results of hierarchical cluster analysis (HCA), computed correlation coefficient and sequential extraction analysis suggest that Cu, Pb, Zn and Cd probably come from antifouling and sea vessel paints, while Ni, Cr, Co, V and Fe are most likely contributed by ophiolitic formations located north of the bay and/or deep sea sediments. Average individual contamination factors (ICFs) indicated that the highest health hazard from the bay is posed by Cu, Pb and Zn.  相似文献   

Sources of polycyclic aromatic hydrocarbons (PAHs) to northwestern Saskatchewan lakes east of the Athabasca oil sands     

《Organic Geochemistry》2015

The past several decades have witnessed a significant expansion of mining activities in the Athabasca oil sands region, raising concerns about their impact on the surrounding boreal forest ecosystem. To better understand the extent to which distal sites are impacted by oil sands-derived airborne contaminants, we examine sources of polycyclic aromatic hydrocarbons (PAHs) in surface sediments and dated sediment cores from Saskatchewan lakes situated ∼100–220 km east–northeast of the main area of bitumen mining activities. The concentrations and fluxes of both parent and alkylated PAHs are low and show considerable variability over the past 70–100 years. Small yet discernible increases in PAH concentrations and fluxes occurred over the past 30 years, a trend which coincides with the rapid growth in bitumen production. However, several lines of evidence point to wildfires as the principal source of PAHs to these lakes: (1) the significant co-variations in most cores between retene (1-methyl-7-isopropyl phenanthrene) and other groups of parent and alkylated PAHs, (2) the similarity in compound specific δ¹³C signatures of the parent PAHs phenanthrene and pyrene in recently deposited surficial sediments and those corresponding to time intervals considerably pre-dating the large scale development of the oil sands and (3) the discernible up-core increases in the proportion of refractory carbon (i.e., char) in Rock-Eval 6 data. The collective evidence points to softwood combustion from boreal forest fires as the principal source of retene in sediments and the general increase in forest fire activity in this region over the past several decades as the source of refractory carbon. Mining activities associated with the Athabasca oil sands are thus not considered a major source of PAHs to these lakes.  相似文献   

Large-scale experiments on beach profile evolution and surf and swash zone sediment transport induced by long waves,wave groups and random waves   总被引：1，自引：0，他引：1  

T.E. Baldock  J.A. Alsina  I. Caceres  D. Vicinanza  P. Contestabile  H. Power  A. Sanchez-Arcilla 《Coastal Engineering》2011

New large-scale laboratory data are presented on the influence of long waves, bichromatic wave groups and random waves on sediment transport in the surf and swash zones. Physical model testing was performed in the large-scale CIEM wave flume at UPC, Barcelona, as part of the SUSCO (swash zone response under grouping storm conditions) experiment in the Hydralab III program (Vicinanza et al., 2010). Fourteen different wave conditions were used, encompassing monochromatic waves, bichromatic wave groups and random waves. The experiments were designed specifically to compare variations in beach profile evolution between monochromatic waves and unsteady waves with the same mean energy flux. Each test commenced with approximately the same initial profile. The monochromatic conditions were perturbed with free long waves, and then subsequently substituted with bichromatic wave groups with different bandwidth and with random waves with varying groupiness. Beach profile measurements were made at half-hourly and hourly intervals, from which net cross-shore transport rates were calculated for the different wave conditions. Pairs of experiments with slightly different bandwidth or wave grouping show very similar net cross-shore sediment transport patterns, giving high confidence to the data set. Consistent with recent small-scale experiments, the data clearly show that in comparison to monochromatic conditions the bichromatic wave groups reduce onshore transport during accretive conditions and increase offshore transport during erosive conditions. The random waves have a similar influence to the bichromatic wave groups, promoting offshore transport, in comparison to the monochromatic conditions. The data also indicate that the free long waves promote onshore transport, but the conclusions are more tentative as a result of a few errors in the test schedule and modifications to the setup which reduced testing time. The experiments suggest that the inclusion of long wave and wave group sediment transport is important for improved near-shore morphological modeling of cross-shore beach profile evolution, and they provide a very comprehensive and controlled series of tests for evaluating numerical models. It is suggested that the large change in the beach response between monochromatic conditions and wave group conditions is a result of the increased significant and maximum wave heights in the wave groups, as much as the presence of the forced and free long waves induced by the groupiness. The equilibrium state model concept can provide a heuristic explanation of the influence of the wave groups on the bulk beach profile response if their effective relative fall velocity is larger than that of monochromatic waves with the same incident energy flux.  相似文献   

A two-phase approach to wave-induced sediment transport under sheet flow conditions     

Xin Chen  Yong Li  Xiaojing Niu  Daoyi Chen  Xiping Yu 《Coastal Engineering》2011

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On the criteria for the initiation of motion in tidal inlets,deterministic and stochastic approaches     

Morteza Kolahdoozan  Hanifeh Imanian  Roger A. Falconer 《Coastal Engineering》2011

Details are given herein of the refinement and application of a three-dimensional layer integrated numerical model to predict morphological changes in tidal basins. The solution of governing differential equations, which consist of the conservation of mass and momentum for the hydrodynamics, the transport equation for the suspended sediment fluxes and the sediment mass conservation equation for the bed level changes are carried out by the use of Alternating Direction Implicit (ADI) Finite Difference Method (FDM). The model includes different criteria for the initiation of motion namely Shields (1936, Application of Similarity Principles and Turbulence Research to Bed load Movement, Hydrodynamics Laboratory, California Institute of Technology, Pub. No. 167), Kolahdoozan (1999, Numerical Modelling of Geomorphological Processes in Estuarine Waters, PhD Thesis, Department of Civil and Environmental Engineering, University of Bradford, Bradford, UK, 288) and Zanke (2003, On the Influence of Turbulence on the Initiation of Sediment Motion, International Journal of Sediment Research, 18(1), 17–31), to compare different aspects of flow conditions. As the flow is highly turbulent with the random nature of its components, many researchers have tried to express sediment transport processes by using stochastic approaches. In the current study both deterministic and stochastic methods are included in the numerical model to evaluate their accuracy and efficiency. To validate the numerical model results, laboratory measurements are used, with these being obtained from an earlier experimental program undertaken by the authors. Results of a short term bed level changes in a laboratory model harbor are included for the model verification purposes. Comparisons are undertaken using different criteria for the initiation of motion, with the results highlighting that the unsteadiness in the flow parameters included in the numerical model has a major effect on the bed level changes inside the harbor, in compare with the turbulence structure of the flow. The model is then applied to a real case study of the Humber Estuary, located in the UK, with comparisons being undertaken for different criteria for the initiation of motion, using both deterministic and stochastic approaches for the long term bed level predictions.  相似文献   

Particle fluxes in San Pedro Basin, California: A four-year record of sedimentation and physical forcing     

Lisa E. Collins  William BerelsonDouglas E. Hammond  Angela Knapp  Richard SchwartzDoug Capone 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(8):898-914

Moored sediment traps were deployed from January 2004 through December 2007 at depths of 550 and 800 m in San Pedro Basin (SPB), CA (33°33.0′N, 118°26.5′W). Additionally, floating sediment traps were deployed at 100 and 200 m for periods of 12-24 h during spring 2005, fall 2007, and spring 2008. Average annual fluxes of mass, particulate organic carbon (POC), ??¹³C_org, particulate organic nitrogen (PON), ??¹⁵N-PON, biogenic silica (bSiO₂), calcium carbonate (CaCO₃), and detrital material (non-biogenic) were coupled with climate records and used to examine sedimentation patterns, vertical flux variability, and organic matter sources to this coastal region. Annual average flux values were determined by binning data by month and averaging the monthly averages. The average annual fluxes to 550 m were 516±42 mg/m² d for mass (sdom of the monthly averages, n=117), 3.18±0.26 mmol C/m² d for POC (n=111), 0.70±0.05 mmol/m² d for CaCO₃ (n=110), 1.31±0.21 mmol/m² d for bSiO₂ (n=115), and 0.35±0.03 mmol/m² d for PON (n=111). Fluxes to 800 and to 550 m were similar, within 10%. Annual average values of ??¹³C_org at 550 m were −21.8±0.2‰ (n=108), and ??¹⁵N averages were 8.9±0.2‰ (n=95). The timing of both high and low flux particle collection was synchronous between the two traps. Given the frequency of trap cup rotation (4-11 days), this argues for particle settling rates ≥83 m/d for both high and low flux periods. The moored traps were deployed over one of the wettest (2004-2005, 74.6 cm rainfall) and driest (2006-2007, 6.6 cm) rain years on record. There was poor correlation (Pearson's correlation coefficient, 95% confidence interval) of detrital mass flux with: C_org/N ratio (r=0.10, p=0.16); ??¹⁵N (r=−0.19, p=0.02); and rainfall (r=0.5, p=0.43), suggesting that runoff does not immediately cause increases in particle fluxes 15 km offshore. ??¹³C_org values suggest that most POC falling to the basin floor is marine derived. Coherence between satellite-derived chlorophyll a records from the trap location (±9 km² resolution) and SST data indicates that productivity and export occurs within a few days of upwelling and both of these parameters are reasonable predictors of POC export, with a time lag of a few days to 2 weeks (with no time lag—SeaWiFS chlorophyll a and POC flux, r=0.25, p=0.0014; chlorophyll a and bSiO₂ flux, r=0.28, p=0.0002).  相似文献   

Distribution of continental red paleosols and their forming mechanisms in the Late Cretaceous Yaojia Formation of the Songliao Basin, NE China     

Xuebin Du  Xinong Xie  Yongchao Lu  Jianye Ren  Shun ZhangPenglin Lang  Tao ChengMing Su  Cheng Zhang 《Cretaceous Research》2011,32(2):244-257

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Accumulation and speciation of selenium in evaporation basins in California,USA   总被引：1，自引：0，他引：1  

Ji-Hun Ryu  Suduan Gao  Kenneth K. Tanji 《Journal of Geochemical Exploration》2011

The accumulation of selenium in evaporation basins (or ponds) in the San Joaquin Valley, California is of a great concern due to its potential hazards to environments. In this study, the accumulation, speciation and concentrations of Se were examined in waters as well as sediments in a system of the evaporation ponds. A significant decrease in the total dissolved Se concentration in Cell 1 in which drainage water with higher Se concentration was pumped from Inlet Channels indicated that the immobilization of Se was active in the Cell 1 and resulted in the higher Se concentration in sediments compared to the terminal cell such as Cell 9. The percentage of reduced Se species such as selenite [Se(IV)] and org-Se of total Se in drainage waters was also found increased in Cell 1 compared to Inlet Channels. The total dissolved Se concentrations in water along flow paths from Cell 1 were relatively constant except for terminal cells such as Cells 9 and 10, which showed higher total dissolved Se concentrations due to evapoconcentration. The percentage of reduced Se forms of total Se was inversely proportional to the percentage of Se(VI) depending on the redox condition of evaporation ponds along the flow paths. Sequential extractions of Se species in sediments indicated that organic associated Se and elemental Se were prevalent forms in sediments in the ponds system. The higher concentrations of elemental Se and organic associated Se in sediments in Cell 1 indicated that the immobilization of Se was active in the sediments compared to Cell 9, while the percentage of both fractions of total Se in sediments in Cells 1 and 9 was relatively constant. The organic materials from algae might provide carbon sources for Se reduction and Se sink in sediments in its elemental and organic associated forms.  相似文献