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Kun HE Yuming DONG Lin YIN Aiming ZHANG Zhen LI 《中国地球化学学报》2006,25(B08):101-101
Catalytic ozonation has attracted much attention in treatment of wastewater for its mild conditions. Phenol and its ramifications are common components in a wide variety of wastewaters including those from coal conversion processes, coking plants, petroleum refineries and several chemical industries. In this paper, natural brucite and magnesia have been successfully used in catalytic ozonation of phenol. And the mechanisms of catalysis were also investigated. From Figs. 1 and 2, it can be found that both brucite and magnesia have remarkable catalysis on degradation of phenol and removal of Chemical Oxygen Demand （COD）. The pH of solutions on the process of ozonation alone, catalytic ozonation with brucites and with magnesia were 6.35-2.76, 10.18-8.52 and 10.58-10.83, respectively. It can be concluded that alkali environment plays a critical role for catalytic ozonation of phenol. We also found that the alkaline minerals reacted on the surface with oxalic acid and other low molecular-weight acids which are intermediate products in ozonation, but those intermediate products could be mineralized into carbon dioxide completely with enough ozonation time. 相似文献
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原油在储层介质中的加水裂解生气模拟实验 总被引：5，自引：2，他引：5
采用高温高压热模拟实验方法,开展了原油在砂岩和火成岩储层介质中的加水裂解生气模拟实验研究.结果表明,原油开始大量裂解的温度是400℃,随模拟温度增加,甲烷相对含量增大,乙烷以上重烃气尤其是丙烷相对含量减小.其中砂岩的油水混合物裂解生气主要发生在450～500℃之间,生气窗范围小,对应的烃气产率高,火成岩的油水混合物裂解生气主要发生在450～600℃之间,生气窗范围大,对应的烃气产率小.模拟烃气的组分碳同位素分馏显著,随模拟温度增加呈变重趋势.在裂解生气过程中,水解加氢和催化作用对烃气的组成、产率和碳同位素分布有重要影响。 相似文献
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Data from the super-deep wells(PS10,PS14 and YS1)led to the discovery of widespread met-al-bearing hydrothermal fluids (or hot brines) related to basic magmas in the Lower Tertiary clastic sequence in the Dongpu Depression .In terms of SEM and EDAX analyses, pore-casting thin section examination of sandstone ,the composition and forming temperature of fluid inclusions ,the trace ele-ment composition of mustone and kerogen and organic geochemical analyses, it is demonstrated that the hydrothermal fluids existing in the area studied are ejecting fluids, which have a close bearing on diagenesis and sedimentation, rather than intrusive veins along the tectonic fractures.The main indicators of hydrothermal activity are:(1)abnormal alteration of kerogen;(2) high-temperature altered mineral assemblage;(30abnormal distribution of hydrocarbons;(4) specific assemblages and abnormal contents of heavy metals in mudstone and kerogen;(5) specific composi-tion of complex compounds and assemblages of fluid inclusions in sandstone;(6) periodic basaltic magma activity.Results of geological observations and laboratory simulating experiments demonstrated that the hydrothermal fluids have a close bearing on hydrocarbon generation in the Dongpu Depression. Two aspects of the effect of hydrothermal fluids are noticed:hydrothermal hydrocarbon production and strong metal catalysis in oil and gas generation. 相似文献
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CAO Hong MA Enbao WANG Xuehua CHEN Jiazang BIN Xiaobei 《《地质学报》英文版》2006,80(2):285-289
By loading nanometer anatase onto exfoliated graphite with the sol-gel method, exfoliated graphite-TiO2 composite （EG-TiO2） can be prepared, which can adsorb oil and can also degrade oil. In a technologic condition for preparing EG-TiO2, the impregnated number of times is the most important factor to influence oil-adsorbing capability, that is, when the impregnated number of times increases, the amount of saturation-adsorbed oil decreases. The study of EG-TiO2 photocatalytic degradation of machine oil based on the weight-loss method and infrared spectrum method indicates that EG-TiO2 has obvious effect of photocatalytic degradation for machine oil. Its performance is superior to pure nanometer TiO2 powder because nanometer TiO2 in EG-TiO2 has three-dimension laminar structure and comparatively high adsorption capability. 相似文献
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文章以北极航线战略作为中国海洋强国建设的切入点,在分析主要海权国家海运航线战略以及北极航线战略在政治、经济、军事、文化对海洋强国建设的影响的基础上,着重从5个方面探讨了北极航线战略对我国海洋强国建设的催化作用实质:一是中国对北极地区的科学考察,有助于深入海洋认知和强化海洋生态保护;二是中国商船在北极航线的安全通行,有助于提高海洋利用水平;三是中国对外贸易潜力的增长,有助于推动海洋经济发展;四是中国对外关系的发展,有助于进一步营造和谐海洋局面;五是中国对北极航线战略通道的利用,有助于加快建设海洋强国的步伐。 相似文献
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矿物在油气形成过程中的作用 总被引：4，自引：0，他引：4
模拟实验结果表明,矿物组成对煤岩样品的模拟实验结果具有很大的影响,不同的矿物以及同一种矿物在不同的有机质热演化阶段,对有机质形成石油和天然气的过程均具有非常明显的影响:高岭土矿物在高温热演化阶段对有机质形成气态烃的过程具有一定的催化能力;碳酸钙（CaCO3）在中—低热演化阶段能抑制气态物质的形成,而在较高的热演化阶段则对煤生成气态物质的过程具有一定的催化作用;四氧化三铁（Fe3O4）在主要的模拟实验阶段对煤生成气态物质的过程均具有一定的催化作用;硫化亚铁（FeS）在低温热演化阶段对天然气的形成具有一定的抑制作用,而在高温热演化阶段则对天然气的形成具有较明显的催化作用;元素硫（S）在不同的热演化阶段对天然气的形成过程均具有非常明显的催化作用。矿物介质不仅对气态产物的产率有比较明显的影响,而且对液态产物的产率也有较明显的影响。模拟实验结果表明:高岭土和四氧化三铁（Fe3O4）在中、低温模拟实验阶段对“氯仿沥青A”的形成具有较明显的催化作用;硫化亚铁（FeS）在整个模拟实验的全过程中对“氯仿沥青A”的形成均具有明显的催化作用;碳酸钙（CaCO3）矿物对“氯仿沥青A”的形成具有明显的抑制作用;元素硫（S）对“氯仿沥青A”的形成具有非常明显的催化作用。 相似文献
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黄铁矿对有机质成烃的催化作用讨论 总被引：22，自引：0，他引：22
粘土矿物，碳酸盐，石英等无机矿物对有机质演化的催化作用已被确认，有机质干酪根类型还与黄铁矿含量，形态有关，而其中硫的含量直接影响到干酪根反应的活化能，反应速率，指出黄铁矿也是一种有效的催化剂。鉴于世界原油中有很大一部分产自高硫酪根，深入研究其中的机理是当前石油地球化学中的一项刻不容缓的任务。 相似文献
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