南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N   总被引：1，自引：0，他引：1  

荣坤波  曾志刚  殷学博  陈帅  王晓媛  齐海燕  马瑶 《海洋学报(英文版)》2018,37(9):67-81

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.  相似文献   

基于“杂合以治”理论探讨陈大舜和法论治经验          下载免费PDF全文

郭雅玲  周德生 《应用海洋学学报》2018,34(10):16-19

陈大舜教授基于“杂合以治”理论，在杂合各种治疗手段的基础上实行和法论治，有较好的临床优势，疗效肯定。本文从杂合为和法均治、和法复治、和法轻治、和法预治、和法综治5个方面来系统阐述陈大舜教授和法论治的特色。并附验案1则，以资佐证。  相似文献   

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素     

王家录  任娟  王勇  李维杰  娄昭  陈佳 《热带地理》2020,40(2):335-345

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。  相似文献   

黑河中游夏季昼夜水汽同位素特征及水汽来源分析          下载免费PDF全文

孟鸿飞  张明军  王圣杰  邱雪  杜铭霞  张亚宁  余秀秀  周苏娥 《干旱区地理》2020,43(2):360-370

基于2012年6~8月的实测水汽同位素数据及相关气象数据，对黑河中游夏季昼夜的同位素基本特征、水汽来源方向及潜在蒸发源地进行了研究。结果表明：空气水汽线斜率白天大于夜晚和水汽过量氘值白天大于夜晚，综合说明白天局地蒸发较夜晚强烈；夏季受西风水汽影响显著。其中，6月主要受西风水汽和北冰洋水汽影响，7、8月主要受西风水汽和东南方向水汽影响，且8月受东南方向水汽影响最为明显；水汽运移路径上下垫面地形和气压带移动会影响水汽后向轨迹高度，西北方向上水汽输送通道较顺畅，风速较大，有利于水汽的输送；水汽蒸发源地主要集中在研究区周围及以东、以北部，其次是西北部。绿洲是主要的水汽蒸发源地，其次是城市和河流，白天较夜晚局地蒸发强烈且面积大。  相似文献   

平衡剖面的制作流程及其地质意义   总被引：9，自引：0，他引：9  

王运所  刘亚洲  张孝义  张剑峰  尹哲 《地球科学与环境学报》2003,25(1):28-32

平衡剖面技术是地质思维和计算机技术的结晶,使对断层构造的研究提高到定量阶段,其依据是在垂直构造走向的剖面上,地层长度和面积(2D)或体积(3D)是均衡的。在此原理基础上利用数学手段对盆地的构造发育史进行正演和反演模拟,直观地再现地下构造的原始几何形态,迅速提供地震剖面的构造解释方案,并对解释结果进行检验(不平衡的剖面其解释一般有问题),为深刻认识构造发育史、分析油气运移及聚集规律提供依据,提高了工作效率。其结果也为盆地模拟、油藏模拟、定量计算构造伸缩量等地质研究打下了坚实的基础[1]。  相似文献   

CO2—H2O平衡法分析常量水中氧同位素的一些计算问题          下载免费PDF全文

刘士琳  严正 《地震地质》1996,18(2):104-108

  相似文献   

晶质铀矿自发裂变产生钌,银,碲的同位素探索     

李岩  王驹 《国外铀金地质》1995,12(1):7-12

为了阐明对铀的自发裂变现象，采用热电离质谱测定法对几种类型晶质铀矿样品的Ｒｕ，ｔＥ和Ａｇ的同位素组成作了测定，由于自发裂变碎片有可能加入天然同位素中，在几个样品中的Ｒｕ，Ｔｅ清楚地显示出了＾９９Ｒｕ，＾１０１Ｒｕ，＾１０２Ｒｕ，＾１０４Ｒｕ，＾１２８Ｔｅ，＾１３０Ｔｅ同位素测量中得到裂变成因的Ａｇ，从Ｍｏｒｏｇｏｒｏ（坦桑尼亚）某晶质铀矿得到的Ｒｕ裂变模式表明，这种晶质铀矿可能已经处于中子诱发＾２  相似文献   

GDJ人卫目视观测数据采集和处理系统的研制     

何妙婵 《天文研究与技术》1996,(1)

本文介绍了ＧＤＪ跟踪打印经纬仪在人造卫星的观测中如何应用计算机对多圈卫星的目视观测资料进行实时采集、处理等工作过程的原理和方法。  相似文献   

钼都矿业好当家——记栾川县地矿局党组书记、局长王学     

张永强  古石 《资源导刊(河南)》2007,(8)

栾川是个矿业大县,以其丰富的钼矿资源而享有"中国钼都"的称号.矿山企业多就意味着监管难度大,工作不容易做好.然而,从2003年以来,栾川县地矿局先后被上级授予"市级文明单位"、"整顿和规范矿产资源开发秩序先进单位"、"市依法行政先进单位"、"党风廉政先进单位"等20多项荣誉称号.  相似文献