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1.
陈晨  苏本勋  景揭俊  肖燕  林伟  褚杨  刘霞  白洋 《岩石学报》2018,34(11):3302-3314
在现行板块构造理论的框架下,板块的初始俯冲是岩浆活动和构造运动发生转变的重要过程,亦是理解板块运动的关键节点。在俯冲起始过程中,主要存在四个方面的地质记录,分别为一系列地球化学成分多样的岩浆活动、SSZ型蛇绿岩、变质底板和玻安岩及其对应的铬铁矿床。特提斯造山带作为公认的研究板块构造理论尤其是初始俯冲的关键场所,一直备受地学界的重视。而土耳其南部构造带作为特提斯造山带的重要组成部分,亦是确定亚欧板块和阿拉伯板块之间缝合线存在的重要标志。该南部构造带是研究新特提斯洋俯冲起始的理想场所,上述关于俯冲初始的四个地质记录均保存良好,且有如下方面的重要特点:1)不同地区的镁铁质岩石甚至同一地区的镁铁质岩石具有不同的地球化学特征,从似洋中脊玄武岩,到过渡型岩石类型和玻安质岩石均有发育; 2)大部分蛇绿岩具有完整的序列,各单元及变质底板岩石中普遍发育侵入的基性岩脉,产状多变,是多期岩浆事件的产物; 3)蛇绿岩下部通常发育一套角闪岩相变质底板,且其年龄与蛇绿岩的形成年龄基本一致; 4)蛇绿岩中普遍发育铬铁矿床,以高Cr型为主,部分蛇绿岩中还赋存高Al-高Cr的过渡型铬铁矿,均被认为是幔源岩浆与地幔橄榄岩反应的产物。因而,这些地质体完整记录了新特提斯洋形成-俯冲-消减的演化过程。  相似文献   
2.
Retrograde hydrous metamorphism has produced three types of microstructures in chromite grains from chromitites and enclosing rocks of the Tapo Ultramafic Massif (Central Peruvian Andes). In semi-massive chromitites (60–80 vol% chromite), (i) partly altered chromite with homogeneous cores surrounded by lower Al2O3 and MgO but higher Cr2O3 and FeO porous chromite with chlorite filling the pores. In serpentinites (ii) zoned chromite with homogeneous cores surrounded by extremely higher Fe2O3 non-porous chromite and magnetite rims, and (iii) non-porous chromite grains. The different patterns of zoning in chromite grains are the consequences of the infiltration of reducing and SiO2-rich fluids and the subsequent heterogeneous interaction with more oxidizing and Fe-bearing fluids. During the first stage of alteration under reduced conditions magmatic chromite is dissolved meanwhile new metamorphogenic porous chromite crystallizes in equilibrium with chlorite. This reaction that involves dissolution and precipitation of minerals is here modeled thermodynamically for the first time. µSiO2-µMgO pseudosection calculated for unaltered semi-massive chromitites at 2 kbar and 300 °C, the lowest P-T conditions inferred from the Tapo Ultramafic Massif and Marañón Complex, predicts that chromite + chlorite (i.e., partly altered chromite) is stable instead of chromite + chlorite + brucite at progressive higher µSiO2 but lower µMgO. Our observation is twofold as it reveals that the important role of SiO2 and MgO and the open-nature of this process. P-T-X diagrams computed using the different P-T pathways estimated for the enclosing Tapo Ultramafic Massif reproduce well the partial equilibrium sequence of mineral assemblages preserved in the chromitites. Nevertheless, it is restricted only to the P-T conditions of the metamorphic peak and that of the latest overprint. Our estimations reveal that a high fluid/rock ratio (1:40 ratio) is required to produce the microstructures and compositional changes observed in the chromitites from the Tapo Ultramafic Massif. The circulation of SiO2-rich fluids and the mobilization of MgO from the chromitite bodies are linked with the formation of garnet amphibolites and carbonate-silica hydrothermalites (i.e., listwaenites and birbirites) in the ultramafic massif. The origin of these fluids is interpreted as a result of the dissolution of orthopyroxene and/or olivine from the metaharzburgites and metagabbros enclosed in the Tapo Ultramafic Massif.  相似文献   
3.
东波超镁铁岩体产在雅鲁藏布江缝合带的西段,与周边白垩纪沉积岩地层和火山岩以断层接触.航磁资料显示该岩体约400km2规模,地表出露连续,地下有一定延深.超镁铁岩体由亏损的地幔橄榄岩组成,主要有高镁的方辉橄榄岩、纯橄岩和少量二辉橄榄岩.方辉橄榄岩和二辉橄榄岩中橄榄石和斜方辉石属高镁型,分别为Fo=89.5~91.5和Mg#=90~91.5.但二辉橄榄岩中的Al2O3和CaO含量明显高于方辉橄榄岩.方辉橄榄岩中单斜辉石Mg#=92~95,二辉橄榄岩的Mg#=92~93,两者的值也重叠.二辉橄榄岩中的Al2O3和CaO含量要明显高于方辉橄榄岩.这些均为阿尔卑斯型地幔橄榄岩的典型特征.纯橄岩中的橄榄石Fo=92~93.2,其斜方辉石和单斜辉石的Mg#=~93,但Al2O3和CaO的含量比方辉橄榄岩和二辉橄榄岩的低.三种岩石的成分变化规律,反映了地幔部分熔融程度的差异.二辉橄榄岩铬尖晶石的Cr#值20~30,反映为典型深海橄榄岩特征,指示MOR环境.与其不同的是,方辉橄榄岩的铬尖晶石的Cr#=20~75,指示MOR和SSZ两者兼有环境.岩石的原始地幔标准化的REE和微量元素蛛网图模式支持了上述的认识.东波地幔橄榄岩中的岩石学特征与产有大型铬铁矿床的罗布莎地幔橄榄岩可对比,岩体中已多处发现块状铬铁矿石,其铬铁矿的Cr2O3含量56%~59%,表明东波是寻找铬铁矿大矿和富矿甚具前景的一个超镁铁岩体.  相似文献   
4.
The Merensky Reef and the underlying Upper Group 2 chromitite layer, in the Critical Zone of the Bushveld Complex, host much of the world’s platinum-group element (PGE) mineralization. The genesis is still debated. A number of features of the Merensky Reef are not consistent with the hypotheses involving mixing of magmas. Uniform mixing between two magmas over an area of 150 by 300 km and a thickness of 3–30 km seems implausible. The Merensky Reef occurs at the interval where Main Zone magma is added, but the relative proportions of the PGE in the Merensky Reef are comparable to those of the Critical Zone magma. Mineral and isotopic evidence in certain profiles through the Merensky Unit suggest either mixing of minerals, not magmas, and in one case, the lack of any chemical evidence for the presence of the second magma. The absence of cumulus sulphides immediately above the Merensky Reef is not predicted by this model. An alternative model is proposed here that depends upon pressure changes, not chemical processes, to produce the mineralization in chromite-rich and sulphide-rich reefs. Magma was added at these levels, but did not mix. This addition caused a temporary increase in the pressure in the extant Critical Zone magma. Immiscible sulphide liquid and/or chromite formed. Sinking sulphide liquid and/or chromite scavenged PGE (as clusters, nanoparticles or platinum-group minerals) from the magma and accumulated at the floor. Rupturing of the roof resulted in a pressure decrease and a return to sulphur-undersaturation of the magma.  相似文献   
5.
The studied serpentinites occur as isolated masses, imbricate slices of variable thicknesses and as small blocks or lenses incorporated in the sedimentary matrix of the mélange. They are thrusted over the associated island arc calc-alkaline metavolcanics and replaced by talc-carbonates along shear zones. Lack of thermal effect of the serpentinites upon the enveloping country rocks, as well as their association with thrust faults indicates their tectonic emplacement as solid bodies. Petrographically, they are composed essentially of antigorite, chrysotile and lizardite with subordinate amounts of carbonates, chromite, magnetite, magnesite, talc, tremolite and chlorite. Chrysotile occurs as cross-fiber veinlets traversing the antigorite matrix, which indicate a late crystallization under static conditions. The predominance of antigorite over other serpentine minerals indicates that the serpentinites have undergone prograde metamorphism or the parent ultramafic rocks were serpentinized under higher pressure. The parent rocks of the studied serpentinites are mainly harzburgite and less commonly dunite and wehrlite due to the prevalence of mesh and bastite textures. The serpentinites have suffered regional metamorphism up to the greenschist facies, which occurred during the collisional stage or back-arc basin closure, followed by thrusting over a continental margin. The microprobe analyses of the serpentine minerals show wide variation in SiO2, MgO, Al2O3, FeO and Cr2O3 due to different generations of serpentinization. The clinopyroxene relicts, from the partly serpentinized peridotite, are augite and similar to clinopyroxene in mantle-derived peridotites. The chromitite lenses associated with the serpentinites show common textures and structures typical of magmatic crystallization and podiform chromitites. The present data suggest that the serpentinites and associated chromitite lenses represent an ophiolitic mantle sequence from a supra-subduction zone, which were thrust over the continental margins during the collisional stage of back-arc basin.  相似文献   
6.
The chromites from the alpine type ultramafic intrusive of Sukinda, India, display a typical partly inverse spinel form and occur in two distinct zones: Brown Ore Zone (BOZ) and Grey Ore Zone (GOZ). The host ultramafites are mostly altered and are represented by the serpentinite, tremolite-talc(chlorite) schist, talc-serpentine schist and chlorite rock. The less altered variants are dunite, harzburgite and websterite. A dyke of orthopyroxenite runs through the main ultramafic body.The composition of olivine (Fo92), orthopyroxene (En92–89) and Al2O3 contents of the parental liquid (10.40–11.45%) determined from chromites, suggest that the parent melt is of boninitic affinity. The chemical plot of TiO2 content against cr# of chromites corroborates a boninitic parental melt. The Fe–Mg partitioning in olivine and chromite depicts the temperature for chromitites as 1200 °C. A compositional plot of mg# and cr# suggests crystallization at high pressure conditions, corresponding to the kimberlite xenolith field. From the PT diagram of pyrolite melting and mineral assemblage, the pressure of crystallization is stipulated to be ≥1.2 GPa. The fO2 values estimated from Fe3+/Cr+Al+Fe3+ ratios range from 10−8.3 to 10−9.3 for the GOZ and 10−7.1 to 10−7.3 for the BOZ. The fO2 values together with the pressure range suggest crystallization at upper mantle conditions. The heterogeneity in chemical composition and fO2 conditions for the GOZ and BOZ could be linked to heterogeneity in the upper mantle.  相似文献   
7.
祁连山蛇绿岩型超镁铁岩铬铁矿床成矿的主要特征   总被引:4,自引:0,他引:4  
祁连山造山带目前已发现不同规模的超镁铁岩体(群)1000余个,产有铬铁矿床(点)和矿化点80余处,这些岩体及其矿产主要产在北祁连优地斜增生地体边部的海沟带中,少数产在祁连中间地块的边部。岩体成因类型为蛇绿岩组合中的超镁铁质单元,铬铁矿的富集部位是地幔橄榄岩和堆积杂岩带底部的纯橄榄岩。岩石多为铝过饱和系列,岩体的平均化学成分接近于斜辉橄榄岩;Cr203的平均含量大于0.40%,Al203的平均含量近于或者大于1%。铬尖晶石的化学参数特征反映出低铁富镁的介质对形成富铬尖晶石是有利的。富铬岩体中Cr、Co、Ti、V的含量较高。  相似文献   
8.
从铬的地球化学性状、铬铁矿的形成过程, Al3+, Fe3+对 Cr3+的制约机制及矿石矿物共生组合特征讨论了控制铬铁矿矿石质量的因素,这一研究对评价矿石质量有重要意义。  相似文献   
9.
 In Oman, the convergence between Arabia and Eurasia resulted in the Late Cretaceous overthrusting of oceanic crust and mantle lithosphere onto the Arabian continental margin. During this compressional event, a part of the continental plate was subducted to a depth of more than 60 km (0.5 GPa, 250–350  °C to more than 2.0 GPa, 550  °C) resulting in progressive metamorphism of the continental margin sediments, well exposed in the Saih Hatat tectonic window, northeastern Oman Mountains. We attempt to constrain the possibility of one continuous history of extension (starting along the east Arabian continental margin in the Permian) that was followed by one continuous history of convergence starting at 90 Ma near a dead oceanic ridge. This compression resulted in the observed progressive metamorphism by ophiolite overthrusting onto the continental margin. Constraining arguments are the palaeogeographic setting before ophiolite obduction of the As Sifah units and the Hawasina Complex near Ghurba. Detrital chromites in the Triassic–Cretaceous metasediments of the Hawasina Complex are compared with magmatic Semail chromites, and the whole-rock chemistry of these metasediments and associated metabasites are investigated. In contrast to former hypotheses, differences in the chemical composition between detrital and magmatic chromites, and the probable origin of all detrital chromites in the Hawasina Basin from Permian age oceanic rocks, suggest that the high-pressure metamorphic sediments of As Sifah can be considered as part of the basal deposits of the Hawasina Basin. Received: 1 September 1998 / Accepted: 18 January 1999  相似文献   
10.
元古代蛇绿岩及铬铁矿   总被引:2,自引:1,他引:1  
鲍佩声 《岩石学报》2019,35(10):2971-2988
本文总结了国外典型元古代蛇绿岩的岩石组合、野外产状、地球化学资料以及成矿特征,并与显生宙蛇绿岩进行了对比,继而探讨元古代板块构造演化和铬铁矿成因。资料表明,早元古代和中-新元古代均有蛇绿岩的存在,但前者较少,仅见于Canadian地盾的Cape Smith Belt中的Prutuniq蛇绿岩(2. 05~2. 0Ga)和芬兰Fennoscandian地盾的Outokumpu和Jormua蛇绿岩(时代为1. 97~1. 96Ga),而中-新元古代的蛇绿岩则见于世界许多地区,如埃及东部沙漠区(~750Ma)和非洲东北部地区(ca.900~800Ma)等。与显生宙蛇绿岩相比,这些老蛇绿岩具如下特征:(1)它们均为被肢解的蛇绿岩,大多与"弧火山岩"和(或)混杂岩伴生,经历不同程度的变形和变质(具绿片岩相-角闪岩相组合);(2)岩石组合大多较齐全,壳层组合发育,以镁铁-超镁铁岩(堆晶岩)、辉长岩、镁铁质席状岩床(墙)杂岩、火山岩为代表;层状镁铁-超镁铁岩的韵律层以及矿物的隐晶变化等均提示了岩浆多期次活动及开放岩浆房的特征;(3)元古代蛇绿岩中既有高铝型铬铁矿,也有高铬型铬铁矿,且主要寄主于纯橄岩(或蛇纹岩)中;高铝型和高铬型直接受控于熔体的熔融程度及含水流体的参与,反映了铬铁矿形成于俯冲带演化的不同阶段;铬铁矿规模均较小,且均以低TiO 2为特征,均为岩浆分异作用的产物,明显区别于显生宙熔融残余成因的豆荚状铬铁矿;(4)元古代蛇绿岩常伴有硫化物Cu-Co-Zn-Au矿,且铬铁矿含Zn较高(Zn=0. 11%~0. 18%)(如芬兰Outokumpu蛇绿岩);橄榄岩及铬铁矿中常含较高的MnO (高达1. 79%,如埃及东部的Wizer蛇绿岩);(5)元古代蛇绿岩具多种成因:主要为俯冲带成因(如埃及蛇绿岩、北东非蛇绿岩、芬兰Outokumpu蛇绿岩),少量为洋中脊成因(加拿大Purtuniq蛇绿岩)及裂谷成因(芬兰Jormua蛇绿岩)等。  相似文献   
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