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1.
胡大千  韩春元  马瑞  刘越  王静  高正虹 《岩石学报》2012,28(9):3042-3050
本文使用D/max-2500X射线衍射仪研究了内蒙古锡林郭勒地区上古生界泥质岩石伊利石的成因标志,讨论了有机质镜质体反射率对变质温度的表征。研究区上古生界泥质岩石伊利石的标型特征为:伊利石结晶度分布于0.28~>0.77之间,平均值0.40;伊利石(白云母)多型以2M1型为主,2M1+1Md多型和1Md多型相对较少;伊利石(白云母)b0值变化于8.983~9.046之间,平均值9.019,指示其形成于成岩-极低级变质作用。有机质镜质体反射率具有示踪变质温度的作用,应用Barker and Pawlewiez(1986,1994)、Barker and Goldsteinl(1990)和Mullis et al.(2001)建立的镜质体反射率地质温度计,对研究区上古生界泥质岩石变质温度进行了估算,揭示古地温处于136~321℃之间,温度估算值主要分布在180~260℃之间,平均值为245℃,这表明研究区上古生界遭受了成岩-极低级变质作用,变质程度属近变质带。研究区上古生界泥质岩石的Ro值主要分布在1.01%~3.67%之间,表明有机质演化处于成熟-过成熟阶段,泥质岩石具有生烃的能力,部分层位可能具有形成油气资源的潜力。  相似文献   
2.
赞皇变质杂岩位于华北克拉通中部造山带中南段、太行山东麓低山区。出露于该变质杂岩区中南部的含石榴石的斜长角闪片麻岩、泥质片麻岩,均保存了三期矿物组合:进变质、峰期变质和退变质矿物组合。这两大类变质岩石中,进变质阶段矿物组合(M1)以石榴石变斑晶核部的包裹体矿物组合为代表,变质高峰期矿物组合(M2)由石榴石变斑晶"边部"和基质矿物组成,退变质阶段矿物组合(M3)主要是环绕石榴石边部发育的"白眼圈"状后成合晶矿物组合。泥质片麻岩中的石榴石变斑晶均保存了明显的成分环带,且在边部很窄的范围内XMn有所增加、Mg/(Mg+Fe)有所降低,指示存在变质高峰期后的退变质过程。温度与压力计算结果表明,赞皇斜长角闪片麻岩所经历的进变质阶段(M1)温度约为640~710℃、 压力约为8.2~8.6kbar;高峰期(M2)变质温度超过810℃,压力大于12.1kbar;退变质阶段(M3)的温压范围为590~670℃和3.2~5.6kbar。此前的研究已说明泥质片麻岩的进变质阶段(M1)变质温度为660~690℃,压力为9.0~9.2kbar;高峰期(M2)变质温度超过780℃,压力大于12.5kbar。变质高峰属于中压相系的顶部至高压相系的底部。斜长角闪片麻岩、泥质片麻岩均记录了典型的顺时针P-T轨迹,并显示近等温减压(ITD)的退变质片段。对泥质片麻岩中多颗锆石的变质增生边的SHRIMP U-Pb定年表明,变质高峰期时代为1821±17Ma。变质作用历史说明赞皇变质岩区卷入了华北克拉通东部陆块和西部陆块之间的俯冲-碰撞、随后的快速隆升过程,为华北克拉通中部造山带早元古代末期(~1850Ma)存在的造山事件提供了新的证据 。  相似文献   
3.
浓度是溶液中客观存在的物理性质,活度则指非理想溶液(包括非理想固溶体)中组分的"有效浓度"。本文以石榴子石-黑云母(GB)温度计、石榴子石-Al2SiO5矿物-斜长石-石英(GASP)压力计为例,探讨了矿物活度模型对于温度计与压力计的影响。将石榴子石和黑云母作为理想或非理想固溶体,根据实验数据建立的不同版本的石榴子石-黑云母温度计,都能较好地重现实验温度,还能识别递增变质带、倒转变质带、热接触变质晕中,不同地带变质温度的系统性变化。但是,将石榴子石和黑云母同时作为理想固溶体的温度计,系统误差明显较大,计算温度系统性偏低。同时采用石榴子石和黑云母非理想活度模型,得到的温度计精确度高。将石榴子石和斜长石都作为理想固溶体建立的GASP压力计,计算压力明显偏高,不能准确识别Al2SiO5矿物的稳定域,有明显的系统误差。如果同时采用石榴子石与斜长石的非理想活度模型,即便不同活度模型之间热力学参数有很大差别,得到的GASP压力计准确度都较高,还能准确识别Al2SiO5矿物的稳定域。迄今为止,还严重缺乏适用于多种岩石类型和宽广温度-压力范围的通用型矿物活度模型。此外,虽然矿物温度计、压力计不涉及流体、熔体,但是其计算结果的确能准确反映客观地质事实,并不受流体、熔体的影响。  相似文献   
4.
Abstract: The Kanamaru pegmatite is one of the two largest pegmatite deposits in Japan and is rich in K–feldspar, which is maximum microcline. The mica minerals and microcline from this ore deposit were studied for K-Ar ages and δ18O ratios. Biotite gives K-Ar age of 78. 5 Ma, but microcline is much younger in age of 66. 0 and 58. 3 Ma. Oxygen isotopic equilibrium temperature of the biotite-quartz pair is 625°C. Using closure temperature of the K-Ar system for biotite and microcline, cooling rate of the pegmatite is calculated to be 88°C/m. y. at the beginning but 12°C/m. y. in the later period of the cooling history. The microcline is slightly depleted in 18O, yielding apparent equilibrium temperatures of 230°C and 155°C on quartz-microcline pairs. It is suggested that the fluid phase, magmatic and partly meteoric in origin, contained in the solidifying pegmatite, was interacted with the original orthoclase and converted it to microcline during the subsolidus stage.  相似文献   
5.
适用于幔源包体的地质温度计   总被引:25,自引:11,他引:25  
徐义刚 《岩石学报》1993,9(2):167-180
  相似文献   
6.
This contribution attempts to summarize the principles, sample preparation, analytical procedures, influencing factors, and geological applications of Raman Spectroscopy of Carbonaceous Material (RSCM) thermometry. Irreversible graphitization of carbonaceous material in sedimentary rocks occurs during the process of reaching peak metamorphic temperature and can be effectively quantified by Raman spectroscopy. However, in addition to temperature, other factors, such as structural and compositional heterogeneity of carbonaceous materials, structural damage caused by polishing, wavelength and energy of laser used for analyses, hematite content,etc., also have significant influence on the Raman signals of carbonaceous materials. Therefore, fresh samples should be collected for analyses to eliminate the influence of hematite. Further, standard experimental procedure should be practiced to avoid the effects of polishing and laser parameter setups. Additionally, multiple (usually more than 25) analyses per sample should be carried out for deriving statistical average and uncertainty values so as to minimize the influence of sample heterogeneity. RSCM thermometry is applicable to a temperature range between 100~700 ℃, and has been widely used in many fields of geological studies, including metamorphism and deformation of orogens, sediment burial history, fault gouge characteristics and evolution, and maturation grade of carbonaceous materials,etc.  相似文献   
7.
李义曼  庞忠和  罗霁  陈凯 《地质论评》2021,67(2):67030018-67030018
热储温度是开展地热资源研究的关键参数之一。地热勘查中常用基于地热流体化学和同位素数据的经验公式来评价没有钻孔或者钻孔未达到实际热储层情况下深部热储的温度。SiO2地温计应用最为广泛,对于发生了绝热沸腾的地热流体,通常采用Fournier等提出的100℃沸腾条件下的校正公式。考虑到海拔会影响沸点,本文从SiO2溶解度方程和温度相关性着手,评价了SiO2地温计沸腾校正方法在高原地区的适用性。结果表明Fournier(1977)及Fournier 和 Potter(1982)提出的100℃条件下SiO2绝热沸腾校正方法得到的误差分别为2.4%和1.1%,可以代表深部热储温度,即SiO2地温计沸腾校正方法在高原地区也是适用的。  相似文献   
8.
Hourglass sector zoning, and related polar overgrowths, are common features of metamorphic tourmaline, developing as a result of variations in element preference on the different growth surfaces. For sector-zoned crystals, three domains are present for each growth zone (c +, c and a), with compositional differences most distinct for Ca and Ti, and among c + and c sectors. Intersector differences vary, commonly showing decreasing fractionation from core to rim attributed to increasing metamorphic grade. Here we show that intersector element partitioning is temperature dependent and derive empirical geothermometers based on c + c and c + a partitioning of Ca and Ti. These thermometers are applicable over a range of temperatures and bulk-rock compositions. Intersector partitioning is not affected by re-equilibration and records and preserves complete T-histories of individual tourmaline grains from prograde to peak and on to retrograde growth. Information on element mobility is preserved by tourmaline composition, because intersector partitioning is independent of element concentration. These factors make intersector partitioning an ideal tool to elucidate the thermal history of tourmaline grains and thus their host environment and tourmaline’s refractory nature preserves these signatures even into the sedimentary record. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.  相似文献   
9.
黑云母—斜方辉石温度计的重新标度及其应用   总被引:4,自引:2,他引:2  
吴春明  潘裕生 《岩石学报》1999,15(3):463-468
黑云母斜方辉石是较为常见的共生矿物对, 它们之间 Fe Mg 交换模式反应的标准熵变与标准体积变化量之比很大, 具备了构成温度计的必要条件。根据 Fonarev and Konilov 的平衡实验数据, 考虑了黑云母、斜方辉石中 Fe Mg 的非理想混合效应, 得出了合理的黑云母、斜方辉石中 Fe Mg 的交换能数据。此外还采纳了 Dasgupta 等关于黑云母活度的数据、von Seckendorff and O' Neill关于斜方辉石活度的数据和 Pattino Douce 等关于黑云母中 AlⅥ、 Ti对黑云母活度效应的数据, 重新标度了黑云母斜方辉石温度计。该温度计重现实验温度的误差为±60℃, 应用于天然岩石的温度计算误差一般小于±70℃, 适用于绿帘角闪岩相至麻粒岩相的变质岩变质温度的估算。  相似文献   
10.
Along grain boundaries of quartz from metamorphic and igneous rocks complex interfingering (sutures) may occur. Under the light microscope the lengths of the sutures range from approximately 10–1000 m. The sutured grain boundaries are statistically self-similar over one to two orders of magnitude. They represent fractals. Their mathematical counterpart are Koch curves which are developed after two to four iterations. The fractal (Hausdorff-Besicovitch) dimensions D of sutured quartz grain boundaries from different grades of metamorphism are between ca. 1.05 and 1.30. The D-value decreases with increasing temperature during formation of the sutures. On a statistical basis, D can be used as a measure of this temperature and, therefore, as a deformation-related thermometer.  相似文献   
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