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Geochemistry and petrogenesis of Sikait leucogranite, Egypt: an example of S-type granite in a metapelitic sequence 总被引：1，自引：0，他引：1
The Sikait leucogranite (SLG) is a body of porphyritic garnet granite intruded a metapelitic sequence and interlayered orthogneisses.
Multiple deformation and low- to medium-grade metamorphism of the sequence was closely associated with pluton emplacement.
Textural features of the SLG indicate that subsolidus plastic deformation was induced during the extensive thrusting. The
granite is strongly peraluminous, alkali-rich and HFS (high field-strength) elements-depleted with low contents of REE, all
facts that substantiate the geochemical characteristics of S-type granites.
The geologic and geochemical features are consistent with a dehydration melting model of the hosted metapelites to generate
the peraluminous SLG. However, geochemical modelling of trace elements and REEs suggest that the anatectic partial melt was
subsequently affected by fractional crystallization of feldspars. This could explain much of the chemical attributes of SLG.
Received: 20 September 1994 / Accepted: 2 August 1996 相似文献
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Empirical garnet-muscovite-plagioclase-quartz geobarometry in medium- to high-grade metapelites 总被引：2，自引：0，他引：2
Based on the net transfer reactions among garnet, muscovite, plagioclase, and quartz (for both Mg and Fe end-member models), the garnet-muscovite-plagioclase-quartz (GMPQ) geobarometry was empirically calibrated under the physical conditions of P=1.0-11.4 kbar and T=505-745 °C for 128 natural metapelitic rock samples collected from the literature. The input temperatures and pressures were simultaneously determined by the garnet-biotite thermometer and the garnet-aluminosilicate-plagioclase-quartz (GASP) barometer. The GMPQ calibrations adopted the same asymmetric quaternary solid solution model of garnet and the same Al-avoidance asymmetric ternary model of plagioclase as the calibrations of the garnet-biotite geothermometer and the GASP geobarometer. A symmetric Fe-Mg-AlVI ternary solid solution model of muscovite was adopted, and the Margules parameters of muscovite were obtained through regression. The Mg and Fe model reactions, along with the assumption of whether the ferric iron content in muscovite is 0% or 50%, resulted in four GMPQ barometry formulae. The GMPQ barometry formulae reproduce the input GASP pressures well within ±1.0 kbar (mostly within ±0.5 kbar). For both aluminosilicate-bearing and aluminosilicate-absent samples, the GMPQ barometry formulae yield identical pressures for every sample, whether the sample was included or not in calibrating the barometers. For each of the Mg or Fe model reaction, the formulae gave identical pressures within ±40 bars. The random error of the GMPQ barometry may be expected as ±1.4 kbar. The dP/dT slopes of these GMPQ formulae are close to that of the GASP barometer in the P-T space. Applications of the GMPQ barometry to aluminosilicate-absent metapelites within a limited geographic area without postmetamorphic structural discontinuity generally show no pressure difference. It may be concluded that the GMPQ barometry formulae derived in this work may be used as practical tools for metamorphic pelites under the conditions of 505-745 °C and 1-11.4 kbar, in the composition range of Xgros>3% in garnet and XAn>17% in plagioclase. 相似文献
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P.L. Dharmapriya Sanjeewa P.K. Malaviarachchi Leo M. Kriegsman K. Sajeev Andrea Galli Y. Osanai N.D. Subasinghe C.B. Dissanayake 《地学前缘(英文版)》2017,8(5):1115-1133
Here we report the occurrence of garnet porphyroblasts that have overgrown alternating silica-saturated and silica deficient microdomains via different mineral reactions. The samples were collected from ultrahigh-temperature (UHT) metapelites in the Highland Complex, Sri Lanka. In some of the metapelites, garnet crystals have cores formed via a dehydration reaction, which had taken place at silica-saturated microdomains and mantle to rim areas formed via a dehydration reaction at silica-deficient microdomains. In contrast, some other garnets in the same rock cores had formed via a dehydration reaction which occurred at silica-deficient microdomains while mantle to rim areas formed via a dehydration reaction at silica-saturated microdomains. Based on the textural observations, we conclude that the studied garnets have grown across different effective bulk compositional microdomains during the prograde evolution. These microdomains could represent heterogeneous compositional layers (paleobedding/laminations) in the precursor sediments or differentiated crenulation cleavages that existed during prograde metamorphism. UHT metamorphism associated with strong ductile deformation, metamorphic differentiation and crystallization of locally produced melt may have obliterated the evidence for such microdomains in the matrix. The lack of significant compositional zoning in garnet probably due to self-diffusion during UHT metamorphism had left mineral inclusions as the sole evidence for earlier microdomains with contrasting chemistry. 相似文献
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内蒙古集宁三岔口夕线堇青石榴二长片麻岩变质作用及年代学研究 总被引：7，自引：7，他引：0
三岔口夕线堇青石榴二长片麻岩出露于华北克拉通孔兹岩带东部的集宁变质杂岩中,该岩石保留了典型的减压反应结构。系统的岩相学观察和矿物化学研究结果表明,三岔口地区夕线堇青石榴二长片麻岩保存了两个阶段变质作用的矿物组合及相应的变质反应结构,其中峰期变质阶段M1的矿物组合为石榴石+夕线石+黑云母+石英+斜长石+钾长石+钛铁矿±磁铁矿;峰后减压的M2-1变质阶段矿物组合为石榴石+堇青石+夕线石+石英+斜长石+钾长石+钛铁矿±尖晶石,M2-2阶段的矿物组合为石榴石+堇青石+黑云母+石英+斜长石+钾长石+钛铁矿+磁铁矿±尖晶石。自峰期变质阶段到峰后减压阶段,典型的转变(减压)反应包括:Grt+Sil+Melt→Crd+Bt+Fe-oxide和Grt+Sil→Crd+Spl。相平衡模拟结合传统地质温压计限定峰期变质阶段的温压条件为T=852~862℃,P=9.3~10.2kbar;峰期后近等温减压的M2-1和M2-2阶段的温压条件分别为854~880℃和7.0~7.4kbar,820~848℃和5.3~6.4kbar。三岔口夕线堇青石榴二长片麻岩记录了典型的近等温减压型的顺时针P-T轨迹。阴极发光图像特征显示夕线堇青石榴二长片麻岩存在大量变质锆石,LA-ICP-MS U-Pb定年结果表明,所有变质锆石记录了十分一致的207Pb/206Pb年龄,其变质时代为1912±11Ma。变质作用历史说明内蒙古孔兹岩带东段的集宁地体卷入了华北克拉通西部的阴山陆块和鄂尔多斯陆块之间的俯冲-碰撞,并经历了古元古代(~1912Ma)的麻粒岩相变质作用后快速折返至地表的过程。 相似文献
5.
柴北缘HP-UHP变质带多期构造热事件的再厘定:鱼卡地区高压变泥质岩锆石和独居石U-Pb定年 总被引：3，自引：3，他引：0
柴北缘高压-超高压变质带西段鱼卡地区变泥质岩中夹有榴辉岩透镜体,已有的研究显示变泥质岩的变质程度也达到了榴辉岩相,并与榴辉岩一起经历了高压-超高压变质作用,是柴北缘曾经历早古生代大陆深俯冲作用的直接证据,也是研究柴北缘大陆深俯冲过程重要的岩石"探针"。本文选择柴北缘西段鱼卡超高压变质单元中的3件蓝晶石榴白云母石英片岩HP变泥质岩样品分别进行了SHRIMP、LA-ICP-MS锆石和原位独居石U-Pb定年。样品Q06-1-2的锆石给出了920±18Ma(MSWD=1.3)的加权平均年龄,其CL图像特征和极低的Th/U比显示其为变质年龄,代表了与罗迪尼亚超大陆碰撞拼合相关的变质事件。样品A03-11-2.2的锆石给出了450±7Ma(MSWD=0.2)的年龄,认为其代表变泥质岩的榴辉岩相变质年龄。样品A03-14-11的薄片原位独居石定年给出了439±8Ma(MSWD=0.072)的加权平均年龄,结合岩相学观察,认为其可能为榴辉岩相峰期之后的早期退变质年龄。这些资料显示柴北缘鱼卡地区早古生代大陆深俯冲的时限为440~450Ma。结合已有研究资料,鱼卡高压变泥质岩记录了新元古代早期和早古生代两期变质事件,进一步证明了柴北缘地区经历了格林威尔期和早古生代两期造山事件 相似文献
6.
麻粒岩相变质作用与花岗岩成因-I:变质泥质岩/杂砂岩高温-超高温变质相平衡 总被引：5，自引：5，他引：0
麻粒岩相岩石作为洞察下地壳的窗口一直备受重视。二十世纪九十年代以来麻粒岩研究的一个重要进展是利用变质相平衡的定量研究方法模拟岩石中所发生的深熔变质反应、熔体成分变化、及熔体丢失对变质矿物组合的影响等。本文利用KASH、NKASH和KFMASH等简单体系的相平衡关系,做出P-T投影图、组分共生图解和基于固定全岩成分的P-T视剖面图解,并结合有关实验岩石学结果,讨论了高温和超高温条件下变质泥质岩和杂砂岩中的变质熔融反应、矿物组合、全岩成分与P-T条件之间的相互关系。多数变质泥质岩和杂砂岩中饱和流体固相线熔融反应可利用NKASH体系中有水流体参与的熔融反应模拟,在没有外来流体注入时,这些反应可形成<3mol%熔体。在不同体系中白云母脱水熔融反应型式及其P-T条件不同,如在NKASH和KFMASH体系中模拟计算的白云母脱水熔融反应与相应的实验结果相似,分别控制了白云母分解熔融的温度下限和上限;白云母的分解温度会随着其中Fe、Mg和Ti含量的增加而升高,也随着共生斜长石中钙长石组分增加而升高,泥质岩中白云母脱水熔融可以形成~10mol%熔体。在KFMASH体系中黑云母脱水熔融反应表现为4条单变反应,其理论计算的温度比实验模拟的结果低一些。在NCKFMASH体系或实际岩石中黑云母脱水熔融反应为滑动反应,如NCKFMASH体系中黑云母从其开始熔融到最后消失在泥质岩中可跨越~100℃,在杂砂岩中可跨越30~50℃。黑云母的稳定温度随着镁值升高而升高,其稳定上限受钛影响更大,黑云母脱水熔融可以形成超过30mol%~40mol%熔体。KFMASH体系中的相平衡模拟表明以出现斜方辉石+夕线石和假蓝宝石为特征的超高温组合易于出现于富镁泥质岩中,而对正常成分泥质岩在达到1000℃的超高温条件下,主要出现石榴石+夕线石(即夕线榴),该组合在更高温度反应形成假蓝宝石+尖晶石。利用饱和水固相线反应和白云母与黑云母分解反应可以更好地限定不同的变质相。如中压和低压条件下低角闪岩相和高角闪岩相的界限可利用NKASH体系中有水流体和白云母参与的熔融反应和亚固相线条件下的白云母分解反应限定;实验确定的泥质岩中黑云母开始熔融与消失的反应可分别用于限定高角闪岩相与(正常)麻粒岩相的界限,以及(正常)麻粒岩相和超高温麻粒岩相的界限。因此,从矿物组合角度,正常麻粒岩相可限定在黑云母开始熔融到完全消失的温度范围,超高温麻粒岩相可限定在黑云母消失(有石英存在)之后的温度范围。 相似文献
7.
Hartmut Jödicke Jörn H Kruhl Christian Ballhaus Peter Giese Jürgen Untiedt 《Physics of the Earth and Planetary Interiors》2004,141(1):37-58
In order to better understand the nature of deep crustal high electrical conductivity, we studied the electrical properties of a tilted section of a former lower continental crust exposed in the Calabrian arc of the Alpine-Apennine mountain system. Geoelectric field measurements and impedance measurements on rock samples showed that these high-grade metamorphic rocks are generally highly resistive as expected for crystalline, electrolytically conducting rocks of low porosity. This holds for graphite-free metabasites as well as for metapelites which generally contain accessory, up to 3% biogenic graphite in the form of isolated grains. Clearly as an exception, a group of thin stratiform black horizons with thicknesses of 1-15 cm within the metapelitic series was detected by means of self-potential (SP) measurements. Rock samples from these horizons exhibit high, quasi-metallic bulk conductivities of up to 50 S/m (0.02 Ωm) in agreeement with up to 20% syngenetic graphite, forming a network of interconnected streaks or crack fillings. The high amount of carbon most probably originates from organic matter of Corg-rich black shales. Relative enrichment of the low mobility graphitic matter compared to the carbon content of the assumed protoliths may have been due to pressure solution and partial melting during prograde metamorphism, without major contribution of a fluid phase, resulting in isolated graphite flakes. Although enriched, graphite in this form has little effect on electrical conductivity. For the Calabrian black horizons, microscopic analyses make conceivable that, in a further decisive step, isolated graphite grains were mechanically smeared to continuous pathways during uplift by shearing, producing hereby the observed graphitic network which is needed to generate high conductivity. As Corg-rich black shales are common members of sedimentary sequences throughout the earth’s history, good conductors of this type may be expected in the continental crust at any depth depending on tectonic and metamorphic history, with the exception of magmatic protoliths. Regarding the extremely high conductivity of the meta-black shale samples containing syngenetic sheared graphite, a total thickness of a few meters of such rocks is sufficient to explain magnetotelluric high conductivity anomalies in the deep crust. 相似文献
8.
Graphite-bearing slates and phyllites (0.4–1.2 vol.% graphite) are progressively metamorphosed in the 3 kbar aureole of the 425 Ma Ballachulish intrusion, Scotland. Two major dehydration reactions are crossed: the chlorite-out reaction at ca. 550 °C (forming cordierite + biotite), and the muscovite-out reaction at 625 °C (forming Al2SiO5 + K-feldspar). Graphite persists to the highest grades and shows no significant variation in abundance with grade, except for a possible decrease in the highest grade rocks. Variable graphite abundance in rocks at the same grade reflects primary sedimentological heterogeneity. Texturally, graphite grains and aggregates in the rock matrix become coarser grained and more widely separated as grade increases. These thermally induced textural modifications of graphite are superimposed on mechanically induced features, such as graphite segregations along cleavages and crenulations, that formed prior to contact metamorphism. Mass balance modelling, assuming internal fluid generation, shows that the amount of graphite consumed during contact metamorphism in the aureole ranges between 0.1 and 0.3 vol.%, depending on the amount of chlorite and muscovite in the protolith. Because the amount of C dissolved in a C–O–H fluid decreases with increasing pressure, and the Ballachulish aureole is at relatively low pressure, these results are a maximum for regional metamorphism, suggesting that graphite will persist through a regional metamorphic cycle if it is initially present in volumes > ca. 0.2 vol.%. 相似文献
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