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小秦岭文峪金矿床流体包裹体研究及矿床成因 总被引：5，自引：2，他引：3
文峪金矿位于小秦岭矿田南部,其产出受脆-韧性剪切带控制,赋矿围岩为太华群变质杂岩.根据脉体穿切关系和矿物交代关系,可以将文峪金矿流体成矿过程分为早、中、晚三个阶段,其热液石英中发育CO2-H2O型、纯CO2型和H2O溶液型三种类型流体包裹体.平阶段石英中原生包裹体主要是CO2-H2O型和纯CO2型,其成分为CO2+H2O±N2±CH4,均一温度集中在290～330℃,盐度为1.02％～9.59％ NaCleqv;中阶段为主成矿阶段,该阶段石英中包含了所有3种类型的包裹体,其中以CO2-H2O型包裹体为主,获得CO2-H2O和水溶液包裹体均一温度集中在250～290℃,盐度为0.02％～12.81％NaCleqv;晚阶段石英仅发育水溶液型包裹体,具有较低的均一温度(114～239℃)和盐度(4.18％～8.95％ NaCleqv).根据CO2-H2O型包裹体计算早、中阶段压力分别为130 ～ 178MPa和85 ～ 150MPa,对应的成矿深度分别为4.7～6.5km和3.1～5.5km.总体而言,文峪金矿的初始流体具有中高温、富CO2、低盐度的变质流体特征,晚成矿阶段流体演化为低温、低盐度水溶液流体,流体的不混溶导致了主成矿期矿质的大量沉淀,文峪金矿为中浅成的造山型矿床. 相似文献
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西秦岭铧厂沟金矿床流体包裹体特征研究及矿床成因 总被引：3，自引：0，他引：3
铧厂沟金矿位于西秦岭勉略缝合带南侧,其产出受韧脆性剪切带控制,赋矿围岩为泥盆系细碧岩、凝灰质绢云千枚岩和灰岩。根据脉体穿切关系和矿物交代关系,可以将铧厂沟金矿分为早、中、晚3个成矿阶段。在铧厂沟金矿的石英中发育了CO2-H2O型、纯CO2型、H2O溶液型和含子矿物型四种类型流体包裹体。早期石英中原生包裹体主要是CO2-H2O型和纯CO2型,其成分为CO2+H2O±N2±CH4±H2S,均一温度集中在320~360℃,盐度为0.43%~5.14% NaCleqv;中阶段为主成矿阶段,该阶段石英中包含了所有四种类型的包裹体,其中H2O溶液型包裹体占了大多数,CO2-H2O和水溶液包裹体均一温度集中在240~320℃,盐度为0.43%~11.19% NaCleqv;晚阶段石英仅发育水溶液型包裹体,具有较低的均一温度(118~228℃)和盐度(0.18%~6.59% NaCleqv)。根据CO2-H2O型包裹体计算主成矿阶段压力为70~195MPa,成矿深度为5~7km。总体而言,铧厂沟金矿的初始流体具有中高温、富CO2、低盐度的变质流体特征,晚成矿阶段流体演化为低温、低盐度水溶液流体,流体的不混溶导致了主成矿期的矿质的大量沉淀,铧厂金矿为中浅成的造山型矿床。 相似文献
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Visible gold in arsenian pyrite at the Shuiyindong Carlin-type gold deposit, Guizhou, China: Implications for the environment and processes of ore formation 总被引：13，自引：0，他引：13
Wenchao Su Bin Xia Hongtao Zhang Xingchun Zhang Ruizhong Hu 《Ore Geology Reviews》2008,33(3-4):667-679
Carlin-type gold deposits are best known for the scarcity of visible gold in their ores. It has long been recognized that the majority of gold is “invisible”, such that it cannot be resolved by conventional microscopy, and resides in arsenian pyrite. Shuiyindong differs in that sub-μm to μm-sized native gold is present in arsenian pyrite veinlets and disseminations. It is also the largest (55 tonnes) and highest grade (7 to 18 ppm), stratabound, Carlin-type gold deposit in Guizhou, China and has produced 5 tonnes of gold from sulfide refractory ores extracted by underground mining methods. In this study, an electron microprobe analyzer (EMPA) was used to map the spatial distribution of “invisible” gold and sub-μm to μm-size visible gold particles in arsenian pyrite in high-grade ore samples from the Shuiyindong. The samples studied are hosted in Permian bioclastic ferroan limestone of the Longtan Formation and exhibit evidence of decarbonation, silicification and sulfidation. Arsenian pyrite with detectable Au (> 400 to 3800 ppm) is disseminated in altered limestone and was deposited in two stages separated by an episode of corrosion in a veinlet.The results show that there are two populations of native gold in arsenian pyrite. One is comprised of sub-μm size gold particles (0.1 to 0.2 μm) that are occasionally present in the gold-bearing arsenian pyrite disseminated in the host rocks. This arsenian pyrite is interpreted to have been formed by sulfidation of ferroan calcite and dolomite. Another is comprised of coarser (1 to 6 μm) native gold grains present in the arsenian pyrite veinlet, either on the first stage where it has been corroded or on the second stage. The lack of fluid inclusion or other evidence of boiling and the low iron content of fluid inclusions in quartz, suggest the veinlet formed by sulfidation of another fluid containing Fe. The Fe-bearing fluid may be a depleted ore fluid that gained Fe by dissolution of ferroan limestone after H2S had been consumed. The association of the largest visible gold grains with an episode of corrosion suggests that fluids episodically became undersaturated with arsenian pyrite while remaining saturated with gold (e.g., pH decrease or an increase in the oxidation state). This may have resulted from incursion of relatively acidic or oxidized fluids that were able to dissolve arsenian pyrite and remain saturated with gold. In this case, sulfidation of iron from the host rock, was the most important depositional mechanism for Au-bearing arsenian pyrite with, or without, grains of native gold. 相似文献
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甘肃阳山金矿碳氢氧同位素与成矿流体来源 总被引：16，自引：10，他引：6
甘肃文县阳山金矿的探明黄金储量已达308t,平均品位4.74g/t,是我国地质勘查储量最大的金矿床。该矿床产于西秦岭造山带,是一个同碰撞形成的类卡林型金矿床,矿体受EW向韧脆性剪切带控制,赋矿围岩为泥盆系碳质千枚岩-板岩-碳酸盐-硅质岩和侵入其中的花岗斑岩脉。热液石英的流体包裹体之δ~(13)C_(CO_2)(PDB)值为-2.5‰～-5.6‰,δ~(87)C_(CH_4(PDB))值为-23.1‰～-32.6‰,说明成矿流体来源于碳酸盐地层或相似岩石建造的变质或/和改造脱水作用。该结论尚被流体氢氧同位素研究结果所证明,成矿早阶段和主阶段流体的δ~(18)O_W值介于9.5‰～15.3‰,δD_W值为-86‰～-73‰。两件矿化晚阶段流体的δ~(18)O_W氧分别为2.7‰和6.8‰,表明有强烈的大气降水热液混入。总体而言,成矿流体系统从早到晚、从深到浅,由变质热液演变为大气降水热液。特别补充说明,上述研究结果和认识与我们根据流体包裹体和矿床地质研究得出的结论相吻合。 相似文献
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甘肃阳山金矿流体包裹体地球化学和矿床成因类型 总被引：16，自引：19，他引：16
西秦岭造山带内的甘肃阳山金矿是我国最新发现的规模最大的金矿床。矿床受 EW 韧脆性剪切带控制,赋矿围岩为泥盆系碳质碳酸盐-千枚岩-板岩和侵入其中的花岗斑岩脉。流体成矿过程包括:形成石英-绢云母-黄铁矿组合的早阶段,形成石英-黄铁矿-毒砂和石英-毒砂-黄铁矿以及石英-碳酸盐-辉锑矿-自然金组合的主成矿阶段,形成碳酸盐-石英网脉的晚阶段。早阶段流体包裹体以含 CO_2包裹体为主,CO_2含量为7.3%～21.5mol%,均一温度集中于270℃～300℃,盐度<3wt.%NaCl eqv;主阶段发育纯 CO_2包襄体、水溶液包裹体和少量含 CO_2包裹体,均一温度集中于210℃～270℃,盐度集中在<2 wt.%NaCl eqv 和3～5 wt.%NaCl eqv 两个范围;晚阶段只发育水溶液包裹体,均一温度集中在160℃～210℃,盐度<3 wt.%NaCl eqv。主阶段流体包裹体类型的多样性、相似的均一温度和流体盐度的双峰特征均指示流体沸腾现象的存在,其流体包裹体捕获温度为210℃～375℃,压力为85～222MPa;赋矿断层的阀门式活动导致主阶段流体系统交替于静岩和静水压力之间,成矿深度为8.5km 左右,成矿流体系统发育在早侏罗世大陆碰撞造山过程。矿床地质特征类似于卡林型金矿。但赋存于蚀变花岗斑岩中矿体既非造山型,也不同于卡林型,成矿流体具造山型矿床特征。因此,阳山金矿可能代表一种新的金矿类型,建议称为"阳山型金矿"。 相似文献
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河南省内乡县银洞沟银矿床流体成分研究 总被引：6，自引：8，他引：6
河南省内乡县银洞沟银矿床是产于东秦岭北部二郎坪地体中的断控脉状矿床,主要赋矿围岩为二郎坪群小寨组绢云石英片岩。流体包裹体的气相、液相和稀土元素研究表明,成矿流体的 CO_2含量为12.829%～22.172mol%,属于 CO_2-NaCl-H_2O 体系,与世界造山型流体成矿系统一致。成矿流体系统在早阶段主要为来自赋矿地层改造-变质脱水作用的深源变质水,经中阶段沸腾,向晚阶段大气降水热液演化。在早阶段,Ag 等成矿元素通过与 Cl~-等离子络合而被萃取、富集到成矿流体中,并被搬运;流体沸腾导致大量金属成矿物质在中阶段快速沉淀。而不同深度、不同阶段的流体包裹体中 Mg~(2 )、Ca~(2 )、REE 等含量差异可由围岩的热液蚀变所致。 相似文献
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河南内乡县银洞沟银多金属矿床碳-氢-氧同位素地球化学 总被引：2，自引：10，他引：2
河南内乡银洞沟银多金属矿床赋存于东秦岭北坡的二郎坪群,属于断裂构造控制的脉状造山型银多金属矿床成矿流体δ~(18)O 值为2.7～9.6‰,δD 值为-95～-73‰,δ~(13)C 值为0.1～0.9‰。早阶段流体为源于含海相碳酸盐的岩石组合的变质脱水,晚期流体来自大气降水的循环。矿区南侧含大理岩的秦岭群符合早阶段变质流体的源区岩性特征,因此认为,在中生代扬子与中朝大陆碰撞过程中,秦岭群板片沿朱夏断裂向北陆内俯冲到二郎坪地体之下,在二郎坪地体之下变质脱水,导致造山型银/金矿床成矿流体系统发育,流体在赋矿构造的韧脆性转变带或韧脆性转变期卸载成矿物质,形成银洞沟大型银多金属矿床。 相似文献
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