Phase equilibria modelling coupled with U–Pb zircon and monazite ages of garnet–cordierite gneiss from Vallikodu Kottayam in the Kerala Khondalite Belt,southern India are presented here.The results suggest that the area attained peak P–T conditions of^900C at 7.5–8 kbar,followed by decompression to 3.5–5 kbar and cooling to 450–480C,preserving signatures of the partial melting event in the field of high to ultra-high temperature metamorphism.Melt reintegration models suggest that up to 35%granitic melt could have been produced during metamorphism at^950C.The U–Pb age data from zircons(~1.0–~0.7 Ga)and chemical ages from monazites(~540 Ma and^941 Ma)reflect a complex tectonometamorphic evolution of the terrain.The^941 Ma age reported from these monazites indicate a Tonian ultra-high temperature event,linked to juvenile magmatism/deformation episodes reported from the Southern Granulite Terrane and associated fragments in Rodinia,which were subsequently overprinted by the Cambrian(~540 Ma)tectonothermal episode. 相似文献
Corundum (ruby-sapphire) is known to have formed in situ within Archean metamorphic rocks at several localities in the North Atlantic Craton of Greenland. Here we present two case studies for such occurrences: (1) Maniitsoq region (Kangerdluarssuk), where kyanite paragneiss hosts ruby corundum, and (2) Nuuk region (Storø), where sillimanite gneiss hosts ruby corundum. At both occurrences, ultramafic rocks (amphibole-peridotite) are in direct contact with the ruby-bearing zones, which have been transformed to mica schist by metasomatic reactions. The bulk-rock geochemistry of the ruby-bearing rocks is consistent with significant depletion of SiO2 in combination with addition of Al2O3, MgO, K2O, Th and Sr relative to an assumed aluminous precursor metapelite. Phase equilibria modelling supports ruby genesis from the breakdown of sillimanite and kyanite at elevated temperatures due to the removal of SiO2. The juxtaposition of relatively silica- and aluminum-rich metasedimentary rocks with low silica ultramafic rocks established a chemical potential gradient that leached/mobilized SiO2 allowing corundum to stabilize in the former rocks. Furthermore, addition of Al2O3 via a metasomatic reaction is required, because Al/Ti is fractionated between the aluminous precursor metapelites and the resulting corundum-bearing mica schist. We propose that Al was mobilized either by complexation with hydroxide at alkaline conditions, or that Al was transported as K-Al-Si-O polymers at deep crustal levels. The three main exploration vectors for corundum within Archean greenstone belts are: (1) amphibolite- to granulite-facies metamorphic conditions, (2) the juxtaposition of ultramafic rocks and aluminous metapelite, and (3) mica-rich reactions zones at their interface. 相似文献
Garnet pyroxenite from high pressure granulite facies occurs with different mineral assemblages which involve garnet, clinopyroxene, orthopyroxene, plagioclase, amphibole and quartz with spinel developing as symplectite with orthopyroxene and plagioclase in large cracks. Three successive parageneses have been identified. The primary assemblage is characterised by the presence of quartz. The second assemblage involves orthopyroxene–plagioclase–hornblende symplectite, and the third assemblage is characterised by the development of spinel in symplectites with orthopyroxene and plagioclase. Using THERMOCALC (V2.7), a quantitative pseudosection in the system CaO–FeO–MgO–Al2O3–SiO2–H2O has been calculated. The assemblage involving quartz developed at high pressure, while the assemblage involving spinel developed at lower pressure. The peak of metamorphism in Tin Begane was calculated at 860 °C and 13.5 kb with aH2O=0.2. These conditions are followed by a decrease of pressure down to 4.8 kb. 相似文献
Within the metamorphic basement of the Coastal Cordillera of central Chile, the Western Series constitutes the high-pressure (HP)/low-temperature (LT) part (accretionary prism) of a fossil-paired metamorphic belt dominated by metagreywackes. In its eastern part, blocks derived from small lenses of garnet amphibolite with a blueschist facies overprint are locally intercalated and associated with serpentinite and garnet mica-schist. Continuously developed local equilibria were evaluated applying various independent geothermobarometric approaches. An overall anticlockwise PT path results. The prograde path evolved along a geothermal gradient of 15 °C/km, passing the high-pressure end of greenschist facies until a transient assemblage developed within albite-epidote amphibolite facies transitional to eclogite facies at peak metamorphic conditions (600–760 °C, 11–16.5 kbar; stage I). This peak assemblage was overprinted during an external fluid infiltration by an epidote blueschist facies assemblage at 350–500 °C, 10–14 kbar (stage II) indicating nearly isobaric cooling. The retrograde equilibration stage was dated with a Rb–Sr mineral isochron at 305.3±3.2 Ma, somewhat younger (296.6±4.7 Ma) in an adjacent garnet mica-schist. Localized retrograde equilibration continued during decompression down to 300 °C, 5 kbar. The retrograde evolution is identical in the garnet amphibolite and the garnet mica-schist.
The counterclockwise PT path contrasts the usual clockwise PT paths derived from rocks of the Western Series. In addition, their ages related to stage II are the oldest recorded within the fossil wedge at the given latitude. Its “exotic” occurrence is interpreted by the path of the earliest and deepest subducted material that was heated in contact with a still hot mantle. Later accreted and dehydrated material caused hydration and cooling of the earliest accreted material and the neighbouring mantle. After this change also related to rheological conditions, effective exhumation of the early subducted material followed at the base of the hydrated mantle wedge within a cooler environment (geothermal gradient around 10–15 °C/km) than during its burial. The exotic blocks thus provide important time markers for the onset of subduction mass circulation in the Coastal Cordillera accretionary prism during the Late Carboniferous. Continuous subduction mass flow lasted for nearly 100 Ma until the Late Triassic. 相似文献
When graphite is present, carbon‐bearing species dissolve in the C‐O‐H fluid and lower the activity of water (). Accordingly, metamorphic reactions that involve water, namely dehydration and partial melting reactions, adjust their P–T positions to accommodate the change of . In this modelling study, pseudosections are calculated for graphite‐bearing systems that are either closed or that progressively lose fluid and/or melt. The diagrams incorporate a new model of CO2 solubility in felsic melts that we derived to be compatible with a recently published melt model. As the result of the lowered in the carbon‐bearing systems, the temperature displacements of the solidus can be as large as 50 °C at low pressures in cordierite‐bearing zones (<4 kbar), but are smaller than 15 °C at mid‐pressure P–T conditions (4–9 kbar). In the supersolidus region, the phase relations among silicate minerals + melt are very close to those in carbon‐free systems. The fluid CO2 content increases as temperature increases in the supersolidus assemblages. The CO2‐rich fluid can be stable in granulite facies conditions in an oxidized system. In graphitic systems, melt and/or cordierite dominate the CO2 budget of high‐grade rocks. During cooling, the fluid that exsolves from such crystalizing melt is CO2‐rich. In addition to the phase relations, the pseudosections presented in this study enable researchers to quantitatively investigate the evolution of phase modes, including graphite, along specific metamorphic P–T paths. At low pressures in the cordierite stability field, graphite is predicted to precipitate as the pressure increases or temperature decreases in the subsolidus assemblages, or temperature increases in the region of melt + fluid coexistence. On the other hand, the graphite abundance remains nearly constant along the mid‐pressure P–T series, but the graphite mode in the supersolidus region may increase due to residual enrichment if the melt is extracted. The modelling results show that metamorphic processes in closed systems lead to only small changes in graphite mode (a few tenths of a per cent). This strongly suggests that open‐system behaviours are required for large amounts of graphite deposition, including fluid infiltration and mixing or residual enrichment processes in high‐grade rocks. In addition to P–T pseudosections, P/T–XO diagrams (XO = O/(H + O) in the fluid) illustrate the thermodynamic features of internal buffering from another perspective, and explore the dependence of phase relations on the externally imposed redox state. If the system is equilibrated with CO2 or CH4‐rich infiltrating fluid, the temperature displacements of metamorphic reactions can be larger than 50 °C, compared with carbon‐free systems. 相似文献