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1.
苏北超基性岩某些超高压变质特征 总被引：10，自引：2，他引：8
苏北芝麻坊超基性岩体,位于大别—苏鲁超高压变质带东段的核心部位,与基性榴辉岩紧密伴生,是苏北最具代表性的岩体之一。根据多年来的成果资料,研究它的超高压变质特征,对研究整个苏鲁超高压变质带具有重大意义。对岩体的形态特征、岩相学特征、特别是矿物学特征,如镁铝榴石特征的研究,结合金刚石的选出,都有力的证实苏北超基性岩是在超高压变质环境下生成的,同时也反映其是由华北地块与扬子地块俯冲碰撞而从地壳深处挤压上来的幔源物质。 相似文献
2.
Compositions of picroilmenite and pyrope concentrates from Carboniferous sandstones in the Arkhangelsk kimberlite province were analyzed by EPMA and LAM ICP MS in Analytic Center of V.S. Sobolev’s Institute of Geology and Mineralogy, SD RAS, Novosibirsk. The results from single grain thermobarometry (Ashchepkov et al., 2010, Ashchepkov et al., 2011, Ashchepkov et al., 2012) for garnet, spinel, ilmenite and clinopyroxene suggest heating of the base of the lithospheric mantle to 1400 °C (45 mw/m2) at 7.0–7.5 GPa and to 900 °C (35 mw/m2) at 3.5–5.5 GPa in an interval corresponding to a lens enriched in chromite and clinopyroxene. The pipes from the eastern fields reveal smoother mantle geotherms and lower temperature PT paths. Mantle columns beneath the kimberlites from northern (Verkhotinskoe field) and western pipes (Kepinskoe field) show heating from the lithosphere base to 5.0 GPa and stepped PT paths shown by chromites probably due to interaction with magmas which caused local Ti-enrichment near 3.0 and 5.5 GPa. The PT paths in the mantle columns beneath the alnöite pipes reveal higher temperature and relatively shallow PT conditions with two major clusters around 3.0 and 5.0 GPa. Trace element patterns for garnets vary from S-type typical of harzburgites to those with a hump in MREE (middle REE) typical for pyroxenites. Lherzolitic garnets with sinusoidal decrease of LREE show distinctive HFSE enrichment. Trace element ratios (Sm/Er)n and (La/Yb)n of garnets correlate positively with pressures estimates by single grain thermobarometry (Ashchepkov et al., 2010, Ashchepkov et al., 2011, Ashchepkov et al., 2012) but only poorly with Cr2O3 content. Enrichment in HFSE of all garnets is related to metasomatism that accompanied the picroilmenite-forming event.Ilmenites reveal two compositional trends. One corresponds to fractionation within conduits at the lower mantle (6.0–7.0 GPa) without contamination. A second trend at <6.0 GPa, formed due to assimilation fractional crystallization (AFC), is characterized by Fe and Cr increase with decreasing pressure. Similar trace element patterns of the various in HREE in ilmenites, possibly partly due to garnet assimilation from wall rock peridotites. The PT conditions and geochemistry for the minerals from the Carboniferous sediments are similar to those from the Lomonosovskoe deposit and Arkhangelskaya pipe (Lehtonen et al., 2009). 相似文献
3.
S. Quartieri G. Antonioli C. A. Geiger G. Artioli P. P. Lottici 《Physics and Chemistry of Minerals》1999,26(3):251-256
The incorporation and site preference of minor amounts (about 1 wt%) of Yb3+ in synthetic pyrope (Mg3Al2Si3O12) and grossular (Ca3Al2Si3O12) garnet were studied by X-ray Absorption Fine-Structure (XAFS) Spectroscopy. The measurements, performed in the temperature
range 77–343 K at both Yb LI- and LIII-edges, demonstrate that Yb3+ enters the garnet structure and is located in the dodecahedral site in both samples. The coordination environment of Yb3+ in the two samples was compared to that of the X-site cation in end-member synthetic pyrope and grossular and in Yb3Al5O12 as determined by single-crystal X-ray diffraction. The local geometry around Yb3+ is different from that of Mg and Ca in the bulk of the garnet, and also from that of Yb3+ in Yb3Al5O12.
Τhe XAFS results indicate that, (1) structural relaxation occurs around Yb3+ in the garnet structure; (2) the host garnet matrix exerts a major structural control on the incorporation of Yb3+, and (3) minor amounts of Yb3+ in garnet are located in structural sites and not in ill-defined defects.
Received: 15 January 1998/ Revised, accepted: 21 July 1998 相似文献
4.
Elastic wave velocities for dense (99.8% of theoretical density) isotropic polycrystalline specimens of synthetic pyrope (Mg3Al2Si3O12) were measured to 1,000 K at 300 MPa by the phase comparison method of ultrasonic interferometry in an internally heated
gas-medium apparatus. The temperature derivatives of the elastic moduli [(∂Ks/∂T)
P
= −19.3(4); (∂G/∂T)
P
= −10.4(2) MPa K−1] measured in this study are consistent with previous acoustic measurements on both synthetic polycrystalline pyrope in a
DIA-type cubic anvil apparatus (Gwanmesia et al. in Phys Earth Planet Inter 155:179–190, 2006) and on a natural single crystal by the rectangular parallelepiped resonance (RPR; Suzuki and Anderson in J Phys Earth 31:125–138,
1983) method but |(∂Ks/∂T)
P
| is significantly larger than from a Brillouin spectroscopy study of single-crystal pyrope (Sinogeikin and Bass in Phys Earth
Planet Inter 203:549–555, 2002). Alternative approaches to the retrieval of mixed derivatives of the elastic moduli from joint analysis of data from this
study and from the solid-medium data of Gwanmesia et al. in Phys Earth Planet Inter 155:179–190 (2006) yield ∂2
G/∂P∂T = [0.07(12), 0.20(14)] × 10−3 K−1 and ∂2
K
S
/∂P∂T = [−0.20(24), 0.22(26)] × 10−3 K−1, both of order 10−4 K−1 and not significantly different from zero. More robust inference of the mixed derivatives will require solid-medium acoustic
measurements of precision significantly better than 1%. 相似文献
5.
Kinetics of hydrogen extraction were investigated by FTIR spectroscopy on a Dora Maira pyrope single crystal. Annealing experiments were performed at ambient pressure, between 1073 and 1323 K, and under two different redox conditions (pO2=0.21 atm and pO2 10–16 atm). During hydrogen extraction the two principal OH absorption bands behave independently. The OHa triplet, centred on 3651 cm–1, decreases at least five times faster than the OHb band at 3602 cm–1. This suggests the presence of two distinct H defects, each with its own kinetics, which are slightly dependent on oxygen partial pressure:Both kinetics are slower than previous data (Wang et al. 1996), but activation energies are similar. At the same time as the OHa bands decrease, an exchange of hydrogen from OHa to OHb occurs. The extent of this transfer can be modelled by assuming it is directly proportional to the fraction of OHa band which has been removed, independent of temperature. This suggests that OHb defects could be produced by partial dehydrogenation of OHa defects. Activation energies and values of diffusion coefficients are very close to those found by Kohlstedt and Mackwell (1998) for the diffusion of metal vacancies in olivine. Thus it is very likely that cation vacancies control the kinetics of dehydrogenation reactions in pyrope. 相似文献
6.
Li同位素在斜顽辉石、镁铝榴石及镁铝尖晶石晶格内扩散与分馏的理论计算研究 总被引：1，自引：0，他引：1
斜顽辉石、镁铝榴石和镁铝尖晶石作为辉石族、石榴石族以及尖晶石族中的重要端元,是地球上地幔主要组成矿物。Li同位素是重要的地幔地球化学示踪剂,其在橄榄石、辉石和石榴石等地幔矿物中的扩散分馏的性质对理解Li同位素作为地幔地球化学示踪剂非常重要。我们通过经典力场经验势方法,从原子尺度上计算研究了不同温压条件下Li同位素在斜顽辉石、镁铝榴石和镁铝尖晶石晶格中分别通过不同的填隙机制和取代空位机制迁移的活化能和其在不同晶格位上的分馏效应。我们发现Li同位素是通过取代空位机制在斜顽辉石、镁铝榴石和镁铝尖晶石中进行迁移扩散。Li同位素在不同晶格位上的分馏作用计算表明,在三种矿物中重同位素7Li会更多地进入晶格填隙位中,而6Li则相对更多进入Mg位。温度是影响这种分馏作用的一个关键因素,相应的结果可用来解释地幔Li同位素组成特征及冷却条件下的同位素分馏等科学问题。 相似文献
7.
Rare centimeter-sized superzoned garnets (SZGs) were discovered in two coesite-bearing whiteschists of the Brossasco-Isasca Unit (BIU), southern Dora-Maira massif (DMM), Western Alps. The superzoned garnet consists of a reddish-brown almandine core crowded with inclusions of staurolite, chloritoid, kyanite, chlorite and paragonite, and of a pinkish pyrope rim with sporadic inclusions of kyanite, and magnesian chlorite. The core–rim contact is relatively sharp and marks the termination of the inclusion-rich portion. The core composition of the superzoned garnet is almost identical to, or slightly richer in Mg, than that of the rim of porphyroblastic garnet in metapelites from the same unit. In the rim of the superzoned garnet, Mg–Fe ratio increases abruptly towards the outermost rim, whose composition is identical to that of the common pyrope in the whiteschist. At the core–rim boundary, there is no chemical gap. Chloritoid and staurolite are common inclusions in the core of the superzoned garnet in the whiteschist and in the porphyroblastic garnet in the metapelite. The staurolite composition (Si=2.00 and total R2+<2.0 for O=23 basis) and its reverse Fe–Mg distribution with respect to garnet suggest a HP origin. The Fe–Mg distribution between chloritoid and garnet is reverse in the superzoned garnet, but normal in the garnet of metapelite. Because normal Fe–Mg distribution was reported from other eclogite-facies metapelites, a model petrogenetic grid was constructed in the FMASH model system considering St, Cld, Ky, Chl, Grt, and assuming the following Fe–Mg partitioning of St>Grt>Cld>Chl. The resulting petrogenetic grid suggests that the core of the superzoned garnet contains incompatible assemblages, such as St–Cld–Chl vs. Cld–Chl–Ky. New and literature data and results of experiments in the KFASH system suggest that: (1) the superzoned garnet was formed under a single prograde high-pressure/ultra high-pressure (HP/UHP) Alpine metamorphism, (2) the almandine inclusion-rich core of the superzoned garnet crystallized at disequilibrium in a pelitic composition system at around 600°C and less than 16 kbar, probably from a former metapelite xenolith included in a Variscan granitoid, and (3) the chemical environment of the host rock suddenly changed from the normal pelite to the whiteschist composition by a metasomatic process during the rim growth, i.e., at a stage close to the UHP climax. 相似文献
8.
The Dalnyaya kimberlite pipe(Yakutia,Russia) contains mantle peridotite xenoliths(mostly Iherzolites and harzburgites) that show both sheared porphyroclastic(deformed) and coarse granular textures,together with ilmenite and clinopyroxene megacrysts.Deformed peridotites contain high-temperature Fe-rich clinopyroxenes,sometimes associated with picroilmenites,which are products of interaction of the lithospheric mantle with protokimberlite related melts.The orthopyroxene-derived geotherm for the lithospheric mantle beneath Dalnyaya is stepped similar to that beneath the Udachnaya pipe.Coarse granular xenoliths fall on a geotherm of 35 mWm-2 whereas deformed varieties yield a 45 mWm-2)geotherm in the 2-7.5 GPa pressure interval.The chemistry of the constituent minerals including garnet,olivine and clinopyroxene shows trends of increasing Fe~#(=Fe/(Fe+Mg))with decreasing pressure.This may suggest that the interaction with fractionating protokimberlite melts occurred at different levels.Two major mantle lithologies are distinguished by the trace element patterns of their constituent minerals,determined by LA-ICP-MS.Orthopyroxenes,some clinopyroxenes and rare garnets are depleted in Ba,Sr,HFSE and MREE and represent relic lithospheric mantle.Re-fertilized garnet and clinopyroxene are more enriched.The distribution of trace elements between garnet and clinopyroxene shows that the garnets dissolved primary orthopyroxene and clinopyroxene.Later high temperature clinopyroxenes related to the protokimberlite melts partially dissolved these garnets.Olivines show decreases in Ni and increases in Al,Ca and Ti from Mg-rich varieties to the more Fe-rich,deformed and refertilized ones.Minerals showing higher Fe~#(0.11-0.15) are found within intergrowths of low-Cr ilmenite-clinopyroxene-garnet related to the crystallization of protokimberlite melts in feeder channels.In P-f(O_2) diagrams,garnets and Cr-rich clinopyroxenes indicate reduced conditions at the base of the lithosphere at-5 log units below a FMQ buffer.However,Cr-poor clinopyroxenes,together with ilmenite and some Fe-Ca-rich garnets,demonstrate a more oxidized trend in the lower part of lithosphere at-2 to 0 log units relative to FMQ.Clinopyroxenes from xenoliths in most cases show conditions transitional between those determined for garnets and megacrystalline Cr-poor suite.The relatively low diamond grade of Dalnyaya kimberlites is explained by a high degree of interaction with the oxidized protokimberlite melts,which is greater at the base of the lithosphere. 相似文献
9.
The Buffalo Hills kimberlites define a province of kimberlite magmatism occurring within and adjacent to Proterozoic crystalline basement termed the Buffalo Head Terrane in north-central Alberta, Canada. The kimberlites are distinguished by a diverse xenocryst suite and most contain some quantity of diamond. The xenocryst assemblage in the province is atypical for diamondiferous kimberlite, including an overall paucity of mantle indicator minerals and the near-absence of compositionally subcalcic peridotitic garnet (G10). The most diamond-rich bodies are distinguished by the presence of slightly subcalcic, chromium-rich garnet and the general absence of picroilmenite, with the majority forming a small cluster in the northwestern part of the province. Barren and near-barren pipes tend to occur to the south, with increasing proximity to the basement structure known as the Peace River Arch. Niobian picroilmenite, compositionally restricted low-to moderate-Cr peridotitic garnet, and megacrystal titanian pyrope occur in kimberlites closest to the arch. Major element data for clinopyroxene and trace element data for garnet from diamond-rich and diamond-poor kimberlites suggests that metasomatism of lithospheric peridotite within the diamond stability field may have caused destruction of diamond, and diamond source rocks proximal to the arch were the most affected. 相似文献
10.
An updated classification scheme for mantle-derived garnet, for use by diamond explorers 总被引：1，自引：0，他引：1
Mantle-derived garnets recovered in diamond exploration programs show compositional variations in Cr, Ca, Mg, Fe and Ti that reflect the chemical, physical and lithological environments in which they occur, occasionally together with diamond. The association of diamond with mantle garnet has progressed through a number of geochemical advances, most notably those of Dawson and Stephens (1975) and Gurney (1984), which are integrated in this work with less well known petrological advances made primarily in xenolith and experimental petrology. A simple, robust garnet classification scheme is formulated which accommodates empirical garnet–diamond relationships for peridotitic (G10, G9, G12), megacrystic (G1), Ti-metasomatised (G11), pyroxenitic (G4, G5) and eclogitic (G3) lithologies in eight distinct garnet classes. The calcium-saturation characteristics of harzburgitic (G10), lherzolitic (G9) and wehrlitic (G12) garnets are described by a Ca-intercept projection that also shows promise as a relative barometer for garnet lherzolite (Grütter and Winter, 1997). Thermobarometric aspects of garnet–diamond associations are highlighted in the scheme through the use of the minor elements Mn and Na, though analysis by anything other than an electron microprobe is not required for classification. A “D” suffix is added to the G10, G4, G5 or G3 categories to indicate a strong compositional and pressure–temperature association with diamond. The scheme remains open to improvement, particularly with regard to delineation of pyroxenitic (or websteritic) diamond associations and to advances in Ca-in-garnet and Na-in-garnet thermobarometry. 相似文献