Isotope geochemistry of Mississippi Valley Type stratabound F-Ba-(Pb-Zn) ores of Hammam Zriba (Province of Zaghouan,NE Tunisia)     

《Chemie der Erde / Geochemistry》2017,77(3):477-486

The Hammam Zriba F-Ba-(Zn-Pb) ore deposit in the Province of Zaghouan in north-eastern Tunisia is hosted in the shallow dipping unconformity between green marls with chalky biomicritic limestones of Campanian age and Uppermost Jurassic carbonates. The mineralization consists mainly of fluorite and barite with minor sphalerite and galena. Calcite is the main gangue mineral. Two types of Zn-Pb sulfides can be distinguished according to the geometry of the orebodies, i.e., lenticular or stratiform ores, intra-karstic fillings. Sulfur isotope compositions (δ³⁴S) of barite range from 14.7 to 17.2‰, indicating that sulfur was derived from Triassic evaporites and the higher ones (19–25.7‰) are due to reservoir effect associated with thermo-chemical sulfate reduction (TSR) or bacterial sulfate reduction (BSR) under conditions of restricted sulfate supply. δ³⁴S of galena and sphalerite in lenticluar and intra-karstic orebodies range from −13.8 to 2.1‰, and could be explained by multiple sources of reduced sulfur: Triassic evaporites, diagenetic primary sulfides as well as sulfur from organic matter. Both TSR and BSR as potential contributors of sulfur are needed for sulfide precipitation. Lead isotope compositions of galena exhibit very similar: ²⁰⁶Pb/²⁰⁴Pb (18.858–18.876), ²⁰⁷Pb/²⁰⁴Pb (15.667–15.684), and ²⁰⁸Pb/²⁰⁴Pb (38.680–38.747) ratios, and plot between the upper crust and orogene average growth curves, reflecting involvement of a mixing and subsequent homogenization of Pb isotopic compositions of different source Pb reservoirs. The underlying Paleozoic basement rocks were the plausible source of metals. The economic ore (fluorite F1) mineralization was formed during the Eocene-Miocene compressional phase. During this deformation phase, deep-seated basinal brines have been circulated as hydrothermal fluids that have interacted with the Paleozoic rocks, thereby leaching metals, and have been channelized through subsidiary faults associated with the major regional NE–SW-trending deep-seated Zaghouan-Ressas fault. Hydrothermal fluids then migrated to the site of deposition where they got mixed with shallow, cooler, metal-depleted, TSR- and BSR-derived sulfur-rich fluids, which triggered the precipitation of the ores.  相似文献   

安徽池州铜山铜矿深部找矿实践与启示   总被引：4，自引：0，他引：4  

SUN Ya-li  张立明  ZHANG Hong-zhou  刘青 《云南地质》2008,27(1):40-45

铜山铜矿资源储量日益枯竭。危机矿山接替资源勘查中,采用地质、物探综合手段圈定异常区,经深部钻探验证,取得突破。  相似文献   

秦岭泥盆系层控铅锌矿床成因模式探讨     

黄书俊  曾永超 《矿产与地质》1991,(3)

在论述秦岭泥盆系层控铅锌矿床的黄铁矿微量元素,硫、铅、氢、氧同位素,矿物气液包裹体均一温度及成分.区域地层元素丰度等方面特征的基础上,提出了该类型属海底含矿热泉溢出沉积和隐伏含矿热泉贯入沉淀的成因模式.  相似文献   

Carbonate-hosted siliceous crust type mineralization of Carnic Alps (Italy-Austria)     

Luciano Brigo  Gianfranco Camana  Franco Rodeghiero  Roberto Potenza   《Ore Geology Reviews》2001,17(4)

A carbonate-hosted stratabound siliceous crust type (SCT) mineralization (base metal sulphides, barite, fluorite) occurs over large areas of Carnic Alps and Karawanken in the Eastern Alps. It concerns a pervasively silicified lithological unit, up to some tens of metres thick, which caps the unconformity landscapes developed on epicontinental Devonian–Dinantian carbonates. The SCT mineralization is directly overlaid by different transgressive siliciclastic sediments, which range from Lower Carboniferous to Lower Permian. The presence of fragments of the SCT mineralization in the transgressive siliciclastic sediment bounds its whole lithological evolution within a short stratigraphic interval of Lower Carboniferous age. Selected features of the regional and lithostratigraphic setting are discussed. The chemical characterisation is based on the statistical evaluation of compositional data of 581 selected samples. Three significant groups of elements have been distinguished: (1) the hydrological and metasomatically active elements (Si, Ba, F), which show a strong negative correlation amongst themselves and characterise the silica-saturated aqueous solutions; (2) the terrigenous elements (Al₂O₃, K₂O, Fe_tot, TiO₂, B, Be, Ce, La, Nb, V, Y, Zr), which suggest a continental margin environment for silica deposition; (3) the sulphide metals (Cu, Pb, Zn, Ni, Sb, As, Hg, Cd), which define the metalliferous signature of the SCT mineralization.Some consistent, but still debatable genetic aspects of the SCT mineralization are as follow: (1) silica may be supplied by illitization of clay-rich basinal sediments during their diagenesis. δ¹⁸O of microcrystalline quartz ranges from +18.5‰ and +24.6‰ and is very similar to δ¹⁸O of authigenic quartz deriving from diagenetic processes of illitization of clay-rich basinal sequences. (2) The diagenetic evolution of these sediments may trigger off the movement of silica-rich marine pore waters. δ³⁴S of barite ranges from +15.5‰ to +19.3‰ with an average of +17.7‰ and are in good agreement with δ³⁴S of sulphate in ocean waters of Upper Devonian–Lower Carboniferous age. (3) A convective hydrological system, connected with sinsedimentary transtensive tectonics, active in the Carnic Alps since the Frasnian, may be the transport mechanism of aqueous solutions. (4) A weak drop in pH in the dominant carbonate environment represents the conditions for silica precipitation.SCT mineralization, showing persistent, independent and distinct characters, occurs over large areas also in other sites of the Alpine belt and outside Italy and Austria. Therefore, it points to important markers for some sedimentary sequences as well as to a worldwide significant cyclic metallogenic event. It represents a new ore deposit-type within the carbonate-hosted mineralization.  相似文献   

伊通县放牛沟地区早古生代岩浆演化特征及其与矿产关系   总被引：1，自引：0，他引：1  

贾大成 《吉林地质》1990,9(2):49-56

伊通县放牛沟早古生代岩浆活动较为强烈,其发展演化与放牛沟多金属硫化物矿床关系极为密切。岩浆活动特点是先喷发后侵入,先期形成钙碱系列的火山—沉积岩系,后期为Ⅰ型中酸性岩浆侵入。该矿床既有火山沉积特征,又有后期岩浆热动力改造特点,其形成受控于岛弧构造环境、火山活动形成的矿源层、后期热动力改造等因素。  相似文献   

铜陵地区层控矽卡岩型矿床地质特征和成矿条件   总被引：7，自引：0，他引：7  

夏元法 《矿产与地质》1999,13(6):338-342

铜陵地区层控矽卡岩型矿床,主要分布于中石炭统黄龙组白云岩段。研究分析铜官山、冬瓜山、天马山、新桥等矿区地质特征、成矿物质和含矿流体的来源后,认为该类矿床属同生沉积—岩浆热液叠加改造成因。  相似文献   

辽东裂谷中的玉石成矿研究     

白永俊  王洪波  单晓刚 《地质找矿论丛》2005,20(Z1):134-138

辽东裂谷内的辽河群南带为玉石成矿有利部位,大石桥组三段为主蕴矿层,其层间断裂为主要的布矿和储矿构造.辽河期黑云二长花岗岩及其脉岩与富镁质碳酸盐岩接触部位对成矿最有利.玉石产于中-高温、高压、SiO2不饱和的封闭型地质环境中,为层控型热液交代为主的复合成因矿床.  相似文献   

云南盈江老山寨铅锌矿矿床成因     

解文伟  刀俊山  黄俊坤 《云南地质》2010,29(2):146-148,137

铅锌矿赋存于关上组,含矿岩性为变质角岩化泥晶灰岩。北东向次级构造控矿,赋矿层位稳定,找矿标志明显,属地层、构造控制及热液叠加层控矿床。  相似文献   

安徽铜陵矿集区铜官山矿田胶状黄铁矿矿物学特征及其对成矿作用的制约     

徐亮  谢巧勤  周跃飞  陈平  孙少华  陈天虎 《岩石学报》2019,35(12):3721-3733

铜官山矿田是铜陵矿集区内五大矿田之一,矿田内顺层产出的层状硫化物矿体是铜金矿床的主矿体,矿体内含有较多的胶状黄铁矿,其成因的争议制约了对铜金矿床成矿作用的解析。本文主要利用场发射扫描电镜(FE-SEM)等纳米矿物学手段,并结合光学显微镜、粉晶X射线衍射(XRD)、微区激光拉曼光谱分析等方法,对矿田内铜官山矿床及天马山矿床内层状硫化物矿体中胶状黄铁矿矿石的矿物组成、微形貌、微结构等特征进行系统研究,结果表明胶状黄铁矿矿石多呈胶状、鲕状结构,具有同心环状构造,同心环被赤铁矿、菱铁矿与黄铜矿脉穿切。同心环主要由白铁矿+有机质与胶状黄铁矿交替组成。胶状黄铁矿的黄铁矿颗粒粒径从纳米至亚微米均有分布,以自形-半自形立方体为主,少数呈他形,脉体边部胶状黄铁矿颗粒较大,自形程度较高,重结晶显著。矿石中含有少量白云石、伊利石微晶体,与胶状黄铁矿紧密共存,显示典型沉积特征。共存石英磨圆度较高,存在次生加大现象,表面存在胶状黄铁矿印模,显示为碎屑成因。这些综合信息表明胶状黄铁矿非岩浆热液成因,而是与石炭系地层同沉积成岩成因,并可能有微生物作用参与。高孔隙率、高化学活性及较高有机质含量的胶状黄铁矿可能为燕山期岩浆热液演化的含铜成矿流体提供了沉淀剂,对矿田内铜金硫化物矿体的层控性发挥了重要的控制作用。  相似文献   

云南安宁禄脿小村锰铁矿矿床成因及找矿标志     

杨定炳  李迅  庄荣寿  周丽英 《云南地质》2010,29(3):364-366,350

昆阳群美党组军哨段中亚段第二层砂质板岩为铁锰矿源层,严格受地层层位控制,具有后期改造特征,属沉积—改造—层控矿床。  相似文献