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1.
本文报道了青藏高原北拉萨地块纳木错西缘变质辉长岩和花岗片麻岩的锆石U-Pb定年、岩石地球化学和锆石Hf同位素分析结果。锆石LA-ICP-MS定年结果表明,变质辉长岩和花岗片麻岩的原岩形成时代分别为720±6Ma和732±7Ma,相当于新元古代中期。变质辉长岩为钙碱性系列,具有Nb、Ta和Ti负异常,与岛弧玄武岩类似。变质辉长岩中锆石具有较高的εHf(t)值(+5. 2~+9. 7),应当是源自俯冲环境下相对亏损的地幔楔。花岗片麻岩原岩为I型花岗质岩石,并且具有较为均一的锆石εHf(t)值(-3. 3~+0. 3),可能形成于地壳内古元古代变质火成岩的部分熔融作用。结合区域地质资料,变质辉长岩和花岗片麻岩的原岩应当形成于新元古代中期的洋壳俯冲消减过程。北拉萨地块上的前寒武纪岩浆和变质记录与东非造山带的活动时限较为一致,因而北拉萨地块可能与东非造山带具有亲缘性。  相似文献   
2.
The Lagoa Real uranium (U) province, referred to as Lagoa Real, is located in the state of Bahia, north-eastern Brazil. Lagoa Real has ∼112,000 metric tonnes and average grade of 2700 ppm of U3O8, being one of the largest U deposits in the world and the largest in Brazil. Despite its economic and strategic importance, there are gaps in the geological knowledge of the Lagoa Real U deposits. One of them is the lack of extensive whole-rock chemical data sets. Here, we present whole-rock chemical analyses for major and trace elements, including the rare-earth elements (REE), from barren country rocks to uraniferous ore shoot, systematically sampled from an exploratory drill hole. The chemical data indicate that albitite rocks, with and without uraniferous mineralisation, cannot result from sodic syenitic magmatism, as proposed by recent studies. Petrographical and geochemical evidence supports the previously suggested concept that the Lagoa Real albitite rocks resulted from sodic metasomatism of the granitic country rock, known as the São Timóteo granite. Their ore-mineral assemblages and geochemical characteristics are similar to albitite-hosted U deposits worldwide.  相似文献   
3.
The Um Rus tonalite-granodiorite intrusion(~6 km2)occurs at the eastern end of the Neoproterozoic,ENE-trending Wadi Muba rak shear belt in the Central Eastern Desert of Egypt.Gold-bearing quartz veins hosted by the Um Rus intrusion were mined intermittently,and initially by the ancient Egyptians and until the early 1900 s.The relationship between the gold mineralization,host intrusion,and regional structures has always been unclear.We present new geochemical and geochronological data that help to define the tectonic environment and age of the Um Rus intrusion.In addition,field studies are integrated with EPMA and LA-ICP-MS data for gold-associated sulfides to better understand the formation and distribution of gold mineralization.The bulk-rock geochemical data of fresh host rocks indicate a calc-alkaline,metaluminous to mildly peraluminous,I-type granite signature.Their trace element composition reflects a tectonic setting intermediate between subduction-related and within-plate environments,presumably transitional between syn-and post-collisional stages.The crystallization age of the Um Rus intrusion was determined by in situ SHRIMP 206 Pb/238 U and 207Pb/235U measurements on accessory monazite grains.The resultant monazite U-Pb weighted mean age(643±9 Ma;MSWD 1.8)roughly overlaps existing geochronological data for similar granitic intrusions that are confined to major shear systems and are locally associated with gold mineralization in the Central Eastrn Desert(e.g.,Fawakhir and Hangaliya).This age is also consistent with magmatism recognized as concomitant to transpressional tectonics(D2:~650 Ma)during the evolution of the Wadi Mubark belt.Formation of the gold-bearing quartz veins in NNE-SSW and N-S striking fault segments was likely linked to the change from transpressional to transtensional tectonics and terrane exhumation(D3:620-580 Ma).The development of N-S throughgoing fault arrays and dike swarms(~595 Ma)led to heterogeneous deformation and recrystallization of the mineralized quartz veins.Ore minerals in the auriferous quartz veins include ubiquitous pyrite and arsenopyrite,with less abundant pyrrhotite,chalcopyrite,sphalerite,and galena.Uncommon pentlandite,gersdorffite,and cobaltite inclusions hosted in quartz veins with meladiorite slivers are interpreted as pre-ore sulfide phases.The gold-sulfide paragenesis encompasses an early pyrite-arsenopyrite±loellingite assemblage,a transitional pyrite-arsenopyrite assemblage,and a late pyrrhotite-chalcopyrite-sphalerite±galena assemblage.Free-milling gold/electrum grains(10 sμm-long)are scattered in extensively deformed vein quartz and in and adjacent to sulfide grains.Marcasite,malachite,and nodular goethite are authigenic alteration phases after pyrrhotite,chalcopyrite,and pyrite and arsenopyrite,respectively.A combined ore petrography,EPMA,and LA-ICP-MS study distinguishes morphological and compositional differences in the early and transitional pyrites(PyⅠ,PyⅡ)and arsenopyrite(ApyⅠ,ApyⅡ).Py I forms uncommon small euhedral inclusions in later PyⅡand Apy II.PyⅡforms large subhedral crystals with porous inner zones and massive outer zones,separated by narrow As-rich irregular mantles.The Fe and As contents in PyⅡare variable,and the LA-ICP-MS analysis shows erratic concentrations of Au(<1 to 177 ppm)and other trace elements(e.g.,Ag,Te,and Sb)in the porous inner zones,most likely related to discrete sub-microscopic sulfide inclusions.The outer massive zones have a rather homogenous composition,with consistently lower abundances of base metals and Au(mean 1.28 ppm).The early arsenopyrite(Apy I)forms fine-grained euhedral crystals enriched in Au(mean 17.7 ppm)and many other trace elements(i.e.,Ni,Co,Se,Ag,Sb,Te,Hg,and Bi).On the other hand,ApyⅡoccurs as coarsegrained subhedral crystals with lower and less variable concentrations of Au(mean 4 ppm).Elevated concentrations of Au(max.327 ppm)and other trace elements are measured in fragmented and aggregated pyrite and arsenopyrite grains,whereas the undeformed intact zones of the same grains are poor in all trace elements.The occurrence of gold/electrum as secondary inclusions in deformed pyrite and arsenopyrite crystals indicates that gold introduction was relatively late in the paragenesis.The LAICP-MS results are consistent with gold redistribution by the N-S though-going faults/dikes overprinted the earlier NNW-SSE quartz veins in the southeastern part of the intrusion,where the underground mining is concentrated.Formation of the Um Rus intrusion and gold-bearing quartz veins can be related to the evolution of the Wadi Mubarak shear belt,where the granitic intrusion formed during or just subsequent to D2 and provided dilatation spaces for gold-quartz vein deposition when deformed by D3 structures.  相似文献   
4.
Lu-Hf同位素体系及其岩石学应用   总被引:120,自引:174,他引:120  
Lu-Hf是近几年来发展极为迅速的一门同位素定年和地球化学示踪技术。本文对这一同位素体系的发展历史、岩石学应用和存在的问题进行了全面的评述,对目前常见的样品溶解、质谱测定和激光剥蚀技术进行了全面介绍。虽然Lu-Hf同位素的发展历史可划分为TIMS、hot-SIMS、MC-ICPMS三个阶段,但MC-ICPMS仪器的出现,使Hf同位素发展速度明显加快。在介绍了Lu-Hf同位素的基本地球化学行为和基本原理之后,本文对这一同位素体系在岩石学上的应用作了全面的介绍,内容包括含石榴石和磷灰石岩石的同位素定年、早期大陆地壳形成与演化、不同端元地幔的性质及成因、岩浆作用过程的Hf同位素鉴别、区域地球动力学演化、变质作用过程中的Hf同位素变化等。最后对Lu的衰变常数、测定标准(JMC475溶液和固体锆石/斜锆石标准)的Hf同位素组成及Hf同位素的封闭温度等问题进行了讨论。  相似文献   
5.
6.
《地学前缘(英文版)》2020,11(4):1145-1161
The Budunhua Cu deposit is located in the Tuquan ore-concentrated area of the southern Great Xing'an Range,NE China.This deposit includes the southern Jinjiling and northern Kongqueshan ore blocks,separated by the Budunhua granitic pluton.Cu mineralization occurs mainly as stockworks or veins in the outer contact zone between tonalite porphyry and Permian metasandstone.The ore-forming process can be divided into four stages involving stage Ⅰ quartz-pyrite-arsenopyrite;stage Ⅱ quartz-pyrite-chalcopyrite-pyrrhotite;stage Ⅲ quartz--polynetallic sulfides;and stage IV quartz-calcite.Three types of fluid inclusions(FIs) can be distinguished in the Budunhua deposit:liquid-rich two-phase aqueous FIs(L-type),vapour-rich aqueous FIs(V-type),and daughter mineral-bearing multi-phase FIs(S-type).Quartz of stages Ⅰ-Ⅲ contains all types of FIs,whereas only L-type FIs are evident in stage Ⅳ veins.The coexisting V-and S-type FIs of stages Ⅰ-Ⅲ have similar homogenization temperatures but contrasting salinities,which indicates that fluid boiling occurred.The FIs of stages Ⅰ,Ⅱ,Ⅲ,and Ⅳyield homogenization temperatures of 265-396℃,245-350℃,200-300℃,and 90-228℃ with salinities of3.4-44.3 wt.%,2.9-40.2 wt.%,1.4-38.2 wt.%,and 0.9-9.2 wt.% NaCl eqv.,respectively.Ore-forming fluids of the Budunhua deposit are characterized by high temperatures,moderate salinities,and relatively oxidizing conditions typical of an H_2 O-NaCl fluid system.Mineralization in the Budunhua deposit occurred at a depth of0.3-1.5 km,with fluid boiling and mixing likely being responsible for ore precipitation.C-H-O-S-Pb isotope studies indicate a predominantly magmatic origin for the ore-forming fluids and materials.LA-ICP-MS zircon U-Pb analyses indicate that ore-forming tonalite porphyry and post-ore dioritic porphyrite were formed at 151.1±1.1 Ma and 129.9±1.9 Ma,respectively.Geochemical data imply that the primary magma of the tonalite porphyry formed through partial melting of Neoproterozoic lower crust.On the basis of available evidence,we suggest that the Budunhua deposit is a porphyry ore system that is spatially,temporally,and genetically associated with tonalite porphyry and formed in a post-collision extensional setting following closure of the Mongol-Okhotsk Ocean.  相似文献   
7.
The Gföhl Unit is the largest migmatite terrain of the Variscan orogenic root domain in Europe. Its genesis has been until now attributed to variable degrees of in situ partial melting. In the Rokytná Complex (Gföhl Unit, Czech Republic) there is a well-preserved sequence documenting the entire migmatitization process on both outcrop and regional scales. The sequence starts with (i) banded orthogneiss with distinctly separated monomineralic layers, continuing through (ii) migmatitic mylonitic gneiss, (iii) schlieren migmatite characterised by disappearance of monomineralic layering and finally to (iv) felsic nebulitic migmatite with no relics of the original banding.

While each type of migmatite shows a distinct whole-rock geochemical and Sr–Nd isotopic fingerprint, the whole sequence evolves along regular, more or less smooth trends for most of the elements. Possible mechanisms which could account for such a variation are that the individual migmatite types (i) are genetically unrelated, (ii) originated by equilibrium melting of a single protolith, (iii) formed by disequilibrium melting (with or without a small-scale melt movement) or (iv) were generated by melt infiltration from external source. The first scenario is not in agreement with the field observations and chemistry of the orthogneisses/migmatites. Neither of the remaining hypotheses can be ruled out convincingly solely on whole-rock geochemical grounds. However in light of previously obtained structural, petrologic and microstructural data, this sequence can be interpreted as a result of a process in which the banded orthogneiss was pervasively, along grain boundaries, penetrated by felsic melt derived from an external source.

In terms of this melt infiltration model the individual migmatites can be explained by different degrees of equilibration between the bulk rock and the passing melt. The melt infiltration can be modelled as an open-system process, characterised by changes of the total mass/volume and accompanied by gains/losses in many of the major- and trace elements. The modelling of the mass balance resulted in identification of a component added by a heterogeneous nucleation of feldspars, quartz and apatite from the passing melt. This is in line with the observed presence of new albitic plagioclase, K-feldspar and quartz coatings as well as resorption of relict feldspars. At the most advanced stages (schlieren and nebulitic migmatites) the whole-rock trace-element geochemical variations document an increasing role for fractional crystallization of the K-feldspar and minor plagioclase, with accessory amounts of monazite, zircon and apatite.

The penetrating melt was probably (leuco-) granitic, poor in mafic components, Rb rich, with low Sr, Ba, LREE, Zr, U and Th contents. It probably originated by partial melting of micaceous quartzo-feldspathic rocks.

If true and the studied migmatites indeed originated by a progressive melt infiltration into a single protolith resembling the banded orthogneiss, this until now underappreciated process would have profound implications regarding rheology and chemical development of anatectic regions in collisional orogens.  相似文献   

8.
This investigation deals with the Nigerian iron-formations and their host rocks and is based on about 560 mineral analyses (electron-microprobe) and 93 whole-rock analyses (64 iron-formations and 29 host rocks). The manganese-rich and Al-bearing iron-formations occurring in various schist belts of the northern and southern part of West-Nigeria consist of the magnetite-free silicate, the magnetite–silicate and the quartz-rich hematite facies.Iron-formations and host rocks originated from submarine-volcanogenic exhalations enriched in Fe, Mn and CO2 and from Al2O3, SiO2 and alkali (K2O and Na2O)-rich continental-derived pelitic to psammitic material. From these sources and their interaction and controlled by the volcanogenic activity, differently composed protoliths were deposited in the marine basin during the Birimian time. Subsequent metamorphism of greenschist to low amphibolite facies conditions during the Eburnian time led to the formation of the metaprotoliths of the magnetite–silicate (consisting of predominantly magnetite and quartz and subordinate of garnet and amphibole), the silicate facies (consisting of garnet, amphibole and rarely Mn-bearing ilmenite and quartz) and the metasediment phyllite. Garnets are predominantly almandine–spessartine solid solutions, whereas amphiboles are Mn and Ca-bearing grunerite–cummingtonite solid solutions. In the course of a second tectono-metamorphic event of Pan-African age, the magnetite–silicate facies iron-formation/phyllite association was transformed into the hematite facies and muscovite/biotite schists, whereas the silicate facies is characterized by extensive silicification features. The hematite facies and the silicified silicate facies are restricted to southern Nigeria where the second and heterogeneous tectono-metamorphic event is more pronounced (amphibolite facies conditions) than in northern Nigeria.The genesis, summarized as the metamorphic model, shows that the carbonate-rich (siderite, rhodochrosite and subordinate magnesite and calcite) protoliths were metamorphically transformed into the silicate and magnetite–silicate facies. The separation of Mn and Fe, leading to manganese-bearing iron-formations and iron-bearing manganese-formations was explained by varying pH-conditions, under which siderite (pH: 6.8–9.4) and rhodochrosite (pH: 9–11) precipitated.Similar to the Gunfit and Biwabik iron-formations of Minnesota, USA, the iron-formation of Bingi (Maru schist belt), now present in the form of the fayalite bearing silicate facies, was overprinted by contact metamorphism caused by a gabbro intrusion.  相似文献   
9.
Ketzin, in the Northeast German Basin (NEGB), is the site for pilot injection of CO2 (CO2SINK project) into a saline aquifer (the Upper Triassic Stuttgart Formation) situated at a depth of about 630–700 m. This paper reports the baseline characterization of the reservoir formation based on new core material and well-logs obtained from one injection well and two observations wells, drilled at a distance from 50 m to 100 m from each other. The reservoir is lithologically heterogeneous and made up by fluvial sandstones and siltstones interbedded with mudstones showing remarkable differences in porosity. The thickest sandstone units are associated with channel sandstone, whose thickness varies over short lateral distances. In-depth petrographic, mineralogical, mineral-chemical, and whole-rock geochemical analysis were performed focusing on the sandstone intervals, which display the best reservoir properties for CO2 injection. The dominantly fine-grained and well to moderately-well sorted, immature sandstones classify as feldspathic litharenites and lithic arkoses. Quartz (22–43 wt.%), plagioclase (19–32 wt.%), and K-feldspar (5–13 wt.%) predominate mineralogically. Muscovite plus illite and mixed-layer minerals are omnipresent (4–13 wt.%). Quartz, feldspar, as well as meta-sedimentary and volcanic rock fragments comprise the most abundant detrital components, which often are rimmed by thin, early diagenetic coatings of ferric oxides, and locally of clay minerals. Feldspar grains may be unaltered and optically clear, partially to completely dissolved, partially altered to sheet silicates (mainly illite), or albitized. Analcime and anhydrite constitute the most widespread, often spatially associated pore-filling cement minerals. Authigenic dolomite, barite, and coelestine is minor. The percentage of cements ranges in total from about 5 vol.% to 32 vol.%. Except of samples intensely cemented by anhydrite and analcime, total porosities of the sandstones range from 13% to 26%. The fraction of intergranular porosity varies between 12% and 21%. About 1–5% porosity has been generated by dissolution of detrital plagioclase, K-feldspar, and volcanic rock fragments. The comparatively large modal abundance of feldspars, micas, chlorite, clay minerals, Fe–Ti-oxides, and analcime account for the richness in Ti, Al, Fe, Mg, Na, and K, and the paucity in Si, of the Stuttgart sandstones relative to mature sandstones. Altogether, these sandstones are comparatively rich in minerals that may potentially react with the injected CO2.  相似文献   
10.
赣东北婺源-德兴地区新元古代地层中浅变质火山岩主要由变质玄武岩、英安岩和流纹岩组成.全岩地球化学分析表明浅变质玄武岩具有拉斑玄武岩的地球化学特征,起源于尖晶石辉橄岩低度部分熔融,英安岩岩浆起源于壳源杂砂岩部分熔融,流纹岩可能为英安质岩浆结晶分异的产物.LA-ICP-MS锆石U-Pb同位素定年揭示婺源浅变质英安岩形成于861±8Ma,德兴张村西浅变质流纹岩形成于860±3Ma,铜厂铜矿矿区凝灰质板岩形成于860±6Ma,均为早新元古代Tonian期.同时这些定年样品中保存了2.8 ~2.5Ga、2.0~1.7Ga和~1.0Ga的继承或捕获锆石记录.结合浅变质玄武岩和英安质火山岩的地球化学特征和成因,这套岩石最有可能形成于新元古代早期安第斯型活动大陆边缘弧后盆地构造背景.  相似文献   
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