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沃溪矿床位于湘西雪峰隆起区的转折部位,是该区金锑钨矿床的典型代表。该矿床成矿元素及成矿期次较为复杂,各成矿阶段的形成时代长期存在争议。本次研究在对沃溪矿床详细野外调查及岩相学观察的基础上,对深部中段矿体中的白钨矿、磷灰石及浅部中段矿体中的黑钨矿开展了U-Pb同位素分析。依据本次所获年龄数据,结合观察到的矿脉交切关系、矿物共生组合等特征,本文认为沃溪矿床除了加里东期成矿作用之外,还存在燕山期成矿作用。其中,白钨矿形成相对较早,成矿年龄为149.0±12Ma、144.8±1.7Ma、139.8±6.1Ma;黑钨矿与白钨矿同时生成(或稍晚),成矿年龄为137.8±3.9Ma、134.8±5.1Ma;自然金、辉锑矿主要在白钨矿、黑钨矿形成以后通过沉淀而成,且自然金在晚阶段(125.8±5.6Ma、123.8±4.6Ma)石英-碳酸盐脉中仍有少量产出。综合已有年代学资料推测,沃溪矿床可能在经历了加里东期陆内造山成矿作用之后,还经受了燕山期伸展构造背景下深部流体不同程度的叠加改造作用。而该矿床发现的矿脉原地破裂后被后期矿物胶结等现象,则指示其矿脉的形成与液压致裂作用有关,这种作用导致矿脉反复裂开-愈合,有利于成矿元素(尤其是金)的活化迁移和再富集沉淀。 相似文献
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Nd-Sr-Pb isotopic constraints on metal and fluid sources in W-Sb-Au mineralization at Woxi and Liaojiaping (Western Hunan,China) 总被引：9，自引：0，他引：9
This paper presents Nd-Sr-Pb isotope data on scheelite, inclusion fluids and residues of gangue quartz, and sulfides from the W-Sb-Au ore deposits at Woxi and Liaojiaping (LJP) in the Xuefeng Uplift Belt (XUB), Western Hunan, China. Sm and Nd concentrations in scheelite from Woxi are much lower than in scheelite from LJP and can be distinguished by their high 147Sm/144Nd ratios of ~1.25 from the much lower ratios around 0.26 in scheelites from the LJP. Nd values (compared to values at 200 Ma, which is the average timing of granitoid emplacement during the Indosinian-Yanshanian periods in the XUB) are around –10 for the LJP and compare well with the range of –5 to –11 defined by the granitoids, whereas they are around –27 for scheelite from Woxi. This might indicate that REEs in the mineralizing fluids at LJP originated from granitoids that are concentrated along the southern border of the XUB, whereas in the case of Woxi, the original fluids might have been masked by REEs released during intense high-temperature wall rock alteration of unexposed Precambrian basement rocks at depth. Sr isotopes of scheelite from these two deposits show similar relations to host / nearby rocks, in that 87Sr/86Sr (T=200 Ma) ratios of ~0.721 for LJP scheelite agree with values ranging between 0.718 – 0.726 for granitoids, whereas these ratios are much higher (i.e. 0.745) for scheelite from Woxi and correspond to the 87Sr/86Sr (T=200 Ma) ratio range of 0.743 – 0.749 for Precambrian host slates. Crushing experiments to release inclusion fluids from gangue quartz and sulfides deposited during later stages of ore deposition in both deposits failed to provide accurate and geologically meaningful two-point (fluid-residue) tie lines in Rb-Sr isochron diagrams. However, Sr released from fluid inclusions generally reveals lower initial 87Sr/86Sr ratios than the respective residues and shows affinities to 87Sr/86Sr (T=200 Ma) values of Indosinian-Yanshanian granitoids, both at Woxi and LJP. Pb stepwise leaching of scheelite and sulfides did not result in sufficient spreads in Pb isotope diagrams and therefore no information regarding exact mineralization ages in the two deposits could be deduced. Overall, ore Pb isotopes reveal upper crustal signatures and are compatible with Pb isotope signatures of the predominant Precambrian slates in the Woxi area. Steep trajectories through late stage quartz-sulfide mineralization in Pb isotope diagrams may hint at mixing scenarios involving Pb from the host rocks and a component with lower 207Pb/204Pb and 208Pb/204Pb ratios relative to 206Pb/204Pb ratios, which cannot be linked to any known reservoir in the XUB mining district. Sr isotopes of four out of seven residual sulfide samples from Woxi plot along a paleomixing line at an age of 199 ± 8 Ma, supporting a mixing scenario for the fluids indicated by the Pb isotopes and pointing to a possible genetic relationship with the emplacement of Indosinian—Yanshanian granitoids. The budgets of REEs, Rb-Sr and Pb in the original fluids were severely affected by contamination of these elements apparently during intense wall rock alteration but, after sealing of the major pathways, the mineralizing fluids tend to have better preserved their original signatures. These attest a genetic relationship between the metallogeny in the XUB W-Sb-Au province and the emplacement of Indosinian-Yanshanian granitoids during Mesozoic intracontinental tectonic uplift and thrusting.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial handling: B. Lehmann 相似文献
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湖南沃溪金锑钨矿床是江南造山带中金、锑、钨、均达到大型规模的典型矿床,其自然金的金成色值极高(＞998)。本文聚焦湖南沃溪金锑钨矿床中金矿化作用,通过ICP- MS测试和包裹体显微测温实验查明不同矿物与围岩的元素地球化学特征和成矿流体特征,并通过热力学模拟分析自然金的成矿条件,探讨金成色值及金银比值对金矿化的指示作用和研究价值。ICP- MS测试结果显示,金银比值在白钨矿(103~520)和黄铁矿(69~673)中相对较高,在辉锑矿(6~65)和围岩(0. 3~35)中相对较低,在石英(6~199)中则变化较大。基于包裹体显微测温结果(200~350℃),本文建立了自然金成矿流体的热力学模型,分析并查明在黄铁矿与绢云母共生的自然金成矿流体中,硫离子浓度比温度更容易影响金溶解度,且金成色值主要与温度呈正相关,与硫离子浓度呈负相关。通过对比研究和讨论,认为沃溪矿床大量金矿化可能形成于温度较高和硫离子浓度较低的白钨矿成矿流体中,而极高成色值的自然金可能与高金银比值的白钨矿和黄铁矿共生。上述方法和结论可为其他金矿床的研究提供新思路。 相似文献
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湘西沃溪钨锑金矿床超纯自然金 总被引：2，自引：0，他引：2
湘西沃溪钨锑金矿床产有自然界中十分罕见的超纯自然金。超纯自然金的Au含量在99 %以上 ,Fisher成色接近1000。自然金中含有Ag、Pb、Zn、Cu、As、Sb、Hg、Bi等显微化学组分。与一般自然金相比 ,超纯自然金的Ag 含量显著偏低 ,而Pb、Zn、As、Sb、Hg、Bi等显微化学组分含量趋于偏高 ,且较稳定。理论分析表明 ,超纯自然金的形成与强氧化性的酸性成矿流体有关。流体中金、银主要以MeCl2-(Me=Au或Ag)的络合物形式迁移。推断矿床成矿可能与区域中酸性岩浆活动有成因联系。 相似文献
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伸展型脆-韧性剪切带对沃溪钨锑金矿床的构造控制 总被引：6，自引：0，他引：6
湖西沃溪钨锑金矿床受控于一条伸展型顺层脆-韧性剪切带。带内岩石在非共轴顺层剪切构造动力作用下发生变形分解，形成泥质构造根岩强变形带和砂质构造根岩弱变形域。泵吸中心-弱变形城中的承压矿液沿砂质构造根岩的ab面发生水力压裂而产生“D”型张剪裂隙。构造-流体双重动力系统的周期性振荡使主裂隙系统发生周期性的破裂-愈合作用而形成条带状复脉。矿液是通过隐蔽的低角度正断层、强变形带内的构造面理及弱变形城中的微裂隙系统运移的，说明在靠近滑脱面的弱变形城中水力压裂作用会增强，其矿化类型将以蚀变岩型为主、脉型为辅。 相似文献
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本文以矿床地质特征为基础,对赋矿围岩的有机质特征进行了初步探讨。在热液作用下,岩石中的Au+、Au3+等组分被有机质还原,有机质转变为二氧化碳。未蚀变岩石、钨矿化蚀变岩石和金锑矿化蚀变岩石的有机质热解色谱谱形、有机质热解参数、有机质成熟度等都有一定差别。未蚀变岩石的热解烃呈一次突发式释放,有机质的最高热解温度、产率指数、降解潜率和烃指数较低,有机质的成熟度最低(位于未成熟区)。钨矿化蚀变岩石的热解烃呈两次缓慢式释放,有机二氧化碳含量较高,有机质类型指数较低,有机质的成熟度较高(位于油区)。金锑矿化蚀变岩石的热解烃呈一次缓慢式释放,有机质的最高热解温度、可溶烃量、产率指数、有效碳、降解潜率和烃指数都较高,有机质成熟度最高(位于气区)。 相似文献
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湘西沃溪金锑钨矿床黄铁矿矿物学研究 总被引：5，自引：0，他引：5
本结合矿床地质背景，从时间空间分布，晶体形态，化学成分（包括主成分，微量元素，元素对比值，元素组合等）晶胞参数，热电性，反射光谱等方面对黄铁矿进行比较详细的研究，确定了本矿床黄铁矿在上述诸方面的标型特征，为指导找矿勘探提供了重要的理论依据。 相似文献
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