Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry     

Katharina Marger  Matthieu Harlaux  Andrea Rielli  Lukas P. Baumgartner  Andrea Dini  Barbara L. Dutrow  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):593-615

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   

低压密闭消解-电感耦合等离子体发射光谱法测定地质样品中的硼     

杜宝华  盛迪波  罗志翔  王全 《岩矿测试》2020,39(5):690-698

采用酸溶-电感耦合等离子体发射光谱法(ICP-OES)测定地质样品中的全硼量,关键环节在于如何防止样品消解过程中硼元素的损失,降低测量过程中的基体干扰、光谱干扰和记忆效应。基于以上问题,本文采用氢氟酸-硝酸-高氯酸-磷酸在低压密闭溶样罐中消解样品,溶出的硼元素与少量磷酸充分络合,防止硼的挥发损失;以基体及主成分浓度与样品相类似的地质类固体标准物质绘制标准曲线做线性校准,有效匹配和降低样品的基体干扰;采用仪器自带的操作软件,观察分析谱线附近是否存在其他元素的干扰,来确定背景扣除最佳的位置及宽度,降低ICP-OES测量中的光谱干扰;以10%的王水作为进样系统的冲洗液,有效消减测量过程中的记忆效应。当稀释因子为200时,方法的检出限(3SD)为1.2μg/g,定量限(10SD)为4.0μg/g;用岩石、土壤及水系沉积物国家一级标准物质对精密度及准确度进行分析验证,11次测定相对标准偏差为1.8%～7.9%,相对误差为-3.6%～6.3%;以外检分析结果为参考,对硼含量在定量限以上的样品测定,相对误差为-9.3%～12.5%。  相似文献   

中国硼矿床成矿规律概要与找矿远景分析     

王莹  熊先孝 《矿床地质》2022,41(5):939-951

硼矿是重要的化工矿产资源,广泛应用于玻璃工业、陶瓷工业、洗涤剂和农用化肥。2014年至今,中国地质调查局组织编写的中国矿产地质志,全面总结了中国硼矿的资源特征和成矿规律。文章依托中国矿产地质志项目,总结了中国硼矿的成矿规律,圈定了硼矿找矿远景区,对未来硼矿的找矿工作有一定的参考价值。文章选取了具有代表性的矿床进行详细解剖工作,分别建立了现代盐湖型和沉积变质型典型硼矿床的预测模型。中国硼矿床的主要类型包括现代盐湖型、沉积变质型、地下卤水型、矽卡岩型和海相火山岩型。目前,中国共发现硼矿的矿产地216处,查明资源储量7575.69万t（B₂O₃）,分布在辽宁、西藏、青海、湖北等14个省（市、自治区）。在成矿时代上,中国硼矿主要形成于新生代、古元古代和中生代。在空间上,中国硼矿可划分为14个Ⅲ级成矿区带和11个矿集区。根据硼矿成矿预测成果,本文圈定了10个硼矿找矿远景区和8个优先勘查区,其中优先勘查区主要集中在青海油泉子（地下卤水型）,昆特依（现代盐湖型）,辽宁夹皮沟-红石砬子、吉林高台沟（沉积变质型）,西藏扎布耶茶卡、依布茶卡、麻米错、班戈错（现代盐湖型）等地区。  相似文献   

湘南地区芙蓉锡矿床中硼矿化的发现及意义     

李小赛  李厚民  李立兴  沈宏飞 《矿床地质》2021,40(6):1351-1356

硼矿是中国重要的紧缺矿产,长期依赖进口,找寻新的硼矿资源迫在眉睫.笔者在湘南地区芙蓉锡矿床新发现了矽卡岩型硼矿化,硼矿物包括硼镁铁矿、遂安石和氟硼镁石,1件典型样品的X射线粉晶衍射分析结果表明硼矿物总含量达到47.4％,换算成w(B)(以B2O3计)约为9.5％,高于5％的硼矿最低工业品位.该发现预示着湘南地区,乃至华南与高分异花岗岩有关的钨锡多金属矿集区有良好的硼成矿潜力,在今后的找矿过程中,需加强与钨锡多金属共伴生的硼矿化评价工作.  相似文献   

Sources of Inaccuracy in Boron Isotope Measurement Using LA-MC-ICP-MS     

Jan Fietzke  Eleni Anagnostou 《Geostandards and Geoanalytical Research》2023,47(3):481-492

Laser ablation multi-collector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) has become a valuable tool for the in situ measurement of the boron isotope composition of geological samples at high (tens to hundreds of μm) spatial resolution. That said, this application suffers from significant analytical challenges. We focus in this study on the underlying processes of two of the main causes for inaccuracies using this technique. We provide empirical evidence that not only Ca ions (Sadekov et al. 2019, Standish et al. 2019, Evans et al. 2021) but also Ar ions, that are reflected within the flight tube of the mass spectrometer, are the source for previously reported issues with spectral baselines. We also address the impact of plasma conditions on the instrumental mass fractionation as a source for matrix- and mass-load-related analytical biases. Comparing experimental data with the results of a dedicated release and diffusion model (RDM) we estimate that a close to complete (~ 97%) release of boron from the sample aerosol is needed to allow for consistently accurate LA boron isotope measurement results without the need for corrections.  相似文献   

ROCKS & MINERALS DETERMINATION AND ANALYSIS     

《Abstract of Chinese Geological Literature》2014,(3)

正20141456 Chen Juan(Laboratory of High Temperature and High Pressure Study of the Earth’s Interior,Institute of Geochemistry,Chinese Academy of Sciences,Guiyang550002,China);Tang Hongfeng Progress in Analytical Methods of Tungsten Isotope and Experimental Research on Digestion of Whole  相似文献   

辽东地区硼找矿概率-地球化学块体资源评价   总被引：1，自引：0，他引：1  

周永恒  张璟  徐山  李守义 《地球科学》2011,36(4):747-754

利用地球化学块体理论进行矿产资源评价的资源量预测工作中,大多是基于地球化学数据本身,虽考虑了除成矿物源之外的如地层、构造等地质背景因素的影响,但仅限于定性阶段,多用于地球化学块体含矿性的分析及远景区的分级.在充分研究地质背景因素的基础上,认为如地层、构造等富集因素与成矿物质基础是矿床形成的2个必要条件,因此,在资源量计算的工作中,还应考虑富集因素的影响,据此建立了找矿概率-地球化学块体法,并将其应用于辽东硼资源量的定量评价中.结果表明,辽东地区硼矿资源潜力较大并符合客观实际.   相似文献   

辽东地区硼矿体赋存特征及成矿预测     

徐大地  荆友广  秦健  薛卫疆  刘来成  侯跃武  陈福恩 《地质与资源》2005,14(3):208-212

辽东地区硼矿床受控于华北地台东北部大石桥-凤城-宽甸古隆起构造带.元古宇辽河群下部里尔峪组含硼岩系呈W-E、NE向、长约350 km、宽60 km的长条带状展布.硼矿体发育于里尔峪组蛇纹石化镁橄岩或蛇纹石化富镁大理岩中,具有明显的层控和岩控特征.虎皮峪-红石砬子-清河近东西向线状紧密的复式背、向斜间多期次次级的背、向斜发育,表现出明显的塑性变形.硼矿体在走向和倾向上具尖灭膨缩现象.围岩蚀变强烈.大量的电气石化使围岩中硼元素的含量偏高;蛇纹石化镁橄岩或蛇纹石化富镁大理岩的Ca/Mg比值波动极大,表明其与成矿关系十分密切;含硼岩系的厚度与矿体的关系呈正相关性,当厚度超过35 m时就有可能成矿,且厚度越大,矿体的规模和矿石质量越好.在部分地区,赋矿的褶皱构造完全倒转,有里尔峪组的层序倒转,混合岩段反转至上部,且混合岩化明显增强,形成混合岩化花岗岩,而其下部250~600 m是含硼岩系,发育优质隐伏硼矿.据辽东地区硼矿体的这些特征,推测了4个成矿远景区.  相似文献   

Modern and Pleistocene boron isotope composition of the benthic foraminifer Cibicidoides wuellerstorfi     

Brbel Hnisch  Torsten Bickert  N. Gary Hemming 《Earth and Planetary Science Letters》2008,272(1-2):309-318

Here we present the first species-specific study of boron isotopes in the epibenthic foraminifer species Cibicidoides wuellerstorfi. Coretop samples from a water depth profile from 1000 to 4500 m on the northern flank of the Walvis Ridge are 4.4‰ lower than the values expected, based on calculations of the δ¹¹B_borate of ambient seawater. Similar values for this foraminifer species are presented from ODP site 668B at the Sierra Leone Rise, in the equatorial Atlantic. The consistency between data of the same species suggests the offsets are primary, rather than diagenetic. Glacial C. wuellerstorfi from ODP 668B and Walvis Ridge have boron isotope compositions only slightly different to interglacial samples, that is no larger than + 0.10 pH units, or + 23 µmol kg^− 1 in [CO₃²⁻] above the reconstructed glacial lysocline, and − 0.07 pH units, or − 14 µmol kg^− 1 in [CO₃²⁻] below. We use these results to suggest that glacial deep water pH in the Atlantic was similar to interglacial pH. The new data resolve the inconsistency between the previously reported high bottom water pH and the lack of significant carbonate preservation of the glacial deep ocean.  相似文献   

扎仓茶卡低品位固体硼矿矿物学与地球化学特征及可选性研究          下载免费PDF全文

张维策  赵元艺 《盐湖研究》2020,28(1):33-44

西藏自治区扎仓茶卡盐湖是我国重要的超大型固体硼镁矿产地,经多年开采,高品位硼矿资源(B_2O_3≥28%)已采掘殆尽,但矿区内仍堆有大量低品位矿石,这不仅是对环境的威胁,也是对资源的浪费。在采集样品的基础上,开展了基于X射线衍射与扫描电镜的矿物组成的鉴定和化学组分分析,为低品位矿石的综合利用提供理论依据。研究结果表明,扎仓茶卡盐湖低品位硼矿的矿物种类有库水硼镁石、柱硼镁石、石英、钠长石、微斜长石、方解石、白云母、文石、水菱镁矿、石膏和锰热臭石共11种,其中仅有库水硼镁石和柱硼镁石两种硼矿物,平均含量分别为21.14%与8.99%,且硼矿样品中B_2O_3平均含量高达13.50%,有巨大的经济利用价值。考虑到扎仓茶卡有着丰富的卤水资源,且低品位硼矿主要为库水硼镁石,可利用卤水及矿物的密度差来进行重选,该库水硼镁石为易选型。这种方法不仅能实现矿区内低品位矿的回收利用,而且生产成本低廉、绿色环保,将进一步促进区域经济发展。  相似文献