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《Limnologica》2017
The near-to-nature approach has been established as best practice for stormwater management. However, pollutant mobility within such systems and its impact on small receiving waters are partly unexplained. The study takes place in an urbanised headwater catchment in south-western Germany with an area of 0.4 km2. Runoff from roofs, roads, parking lots and gardens is collected in wells or trenches and stored in private and public dry detention basins. Accordingly, this study investigates pollutant input to a detention pond, removal efficiency and the associated effects on the receiving water.Grab samples with high temporal resolution of the receiving water (16 flood events with 315 samples and 41 baseflow samples), the three inflows of the detention basin and its outflow (four flood events with 64 samples) were taken. The outflow of the dry pond is recovered in the hydro- and chemographs of the receiving water. Runoff from roads with increased traffic volume caused the highest PAH inputs and runoff from the residential area showed the highest zinc concentrations, which partly infringe European Environmental Quality Standards. Yearly pollutant inputs (DOC, TSS, PAH, nutrients, metals) from the settlement into the tributary are reduced in the detention pond by up to 80%. 相似文献
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Li?ka Jesenica is a sinking river situated in the Dinaric karst environment of the Lika region of Croatia. The two main karst springs, Veliko Vrelo and Malo Vrelo, provide the majority of Li?ka Jesenica's water. Because of the quality and abundance of the water they contain, these springs are strategically important to the public water supply. Previous knowledge regarding the springs` karst system has been negligible. Therefore, a bulk hydrogeological research program was conducted with the purposes of establishing protection zones and assessing the springs' water‐supply potential. The research work comprised the following methods: hydrogeological mapping, setting up of monitoring stations for evaluating discharge and water quality, time series analyses (hydrograph–chemograph), hydrochemical analyses, and geophysical surveys. The main results and conclusions of the research include the following: (i) confirmation that both springs drain a common aquifer; (ii) determination of the highly vulnerable nature of the karst systems; (iii) identification of the Veliko Vrelo Spring's more direct connection to the aquifer‐drainage system in comparison to the Malo Vrelo; (iv) estimation of the positions and depths of the springs` main feeding conduits; (v) confirmation of the extent of the geologically presumed catchment area; and (vi) finally, establishment of sanitary protection zones. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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Using hydro‐chemograph analyses to reveal runoff generation processes in a Mediterranean catchment 
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下载免费PDF全文 The paper deals with the hydro‐chemical analysis performed in order to reveal processes, sources, paths and timing of the runoff generation in an experimental catchment representative of the hilly, terrigenous and forested watershed in the Mediterranean humid eco‐region of southern Italy. The analysis is based on the data recorded at the outlet of the catchment during 2013–2014. A mixing law procedure was applied on discharge (Q) and electrical conductivity (EC) data, by using the Q–EC end members previously collected at selected groundwater, sub‐surficial and surficial stations. In this way, we found four bound curves delimiting fields in a Q–EC plot, each with hydro‐chemograph value ranges. At annual time scale, the analysis revealed a seasonal behaviour of the hydrological response, different for the wet period, when the aquifer is recharging, and the dry periods, when the aquifer is discharging, despite frequent summer rain showers. At event time scale, the catchment seems to show the behaviour of a typical hydro‐geomorphic threshold system. We interpreted this behaviour as due to a progressive addition of water from distinctive components (i.e. deep aquifer, riparian corridor, hillslope and hollow), each with originally different mechanisms of runoff production (i.e. groundwater, groundwater ridging, saturation excess, infiltration excess and soil pipe exfiltration) and response time. During the event, the contributing areas enlarge upward the riparian corridors and the zero‐order basins, where the aforementioned components become superposed and the mechanisms interact more and more. We hypothesize that the threshold values between different states of the system are defined by the intersections of the boundary curves on the Q–EC plot. Different patterns in the Q–EC hysteretic cycles are prevalently related to the pre‐event soil saturation and groundwater contributions to stormflow and recharge mechanisms. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
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岩溶水系统的水化学曲线及其在水文地质研究中的应用 总被引：5，自引：0，他引：5
为了认识水文地质条件与岩溶泉水化学之间的关系,以西南地区的6个典型岩溶水系统丫吉试验场S31号泉、毛村地下河、官村地下河、陈旗岩溶泉、青木关地下河以及金佛山水房泉为例进行研究。通过对比发现,在这些强烈非均质的山区裸露型岩溶水系统中,仪器能够实现自动化监测的电导率、温度和pH值等指标的水化学曲线存在差异。分析可知控制水化学变化的主要因素如下:首先是降雨补给引起系统的水量与碳酸盐岩溶解过程的变化;其次是CO2气体随降雨进入含水层,促进碳酸盐岩的溶解;最后是地表污染物的淋滤。当电导率、水温、pH曲线出现降低和碳酸盐岩矿物饱和指数下降时,反映的是岩溶水的稀释作用;当电导率曲线出现高峰时,反映的是岩溶水补给的CO2效应,此时水中二氧化碳分压(pCO2)升高;当场雨中水化学曲线的变化滞后于水文动态曲线时,反映的是岩溶管道的活塞流效应;与人类活动有关的NO3-等污染物质量浓度在降雨后出现高峰,反映土壤的降雨淋滤作用,并可能影响电导率的变化趋势。某个系统的水化学曲线趋向于经常出现某几种效应,并且彼此的类型不同,表明了降雨补给的面状渗流方式和集中灌入方式对岩溶水影响的强弱不同,以及系统在径流方式和调蓄机制上的差异。一般而言:以面状补给方式为主的系统,水化学曲线多表现为CO2效应,较少出现稀释作用;而岩溶发育强烈的系统,降雨补给受控于溶蚀裂隙和管道,其水化学曲线较多出现稀释作用,较少出现CO2效应;以管道为主要径流方式的系统易出现活塞流效应,而包气带厚度大和含水层储水能力强的系统水化学变化被减弱。 相似文献
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Anomalous behaviour of specific electrical conductivity (SEC) was observed at a karst spring in Slovenia during 26 high‐flow events in an 18‐month monitoring period. A conceptual model explaining this anomalous SEC variability is presented and reproduced by numerical modelling, and the practical relevance for source protection zoning is discussed. After storm rainfall, discharge increases rapidly, which is typical for karst springs. SEC displays a first maximum during the rising limb of the spring hydrograph, followed by a minimum indicating the arrival of freshly infiltrated water, often confirmed by increased levels of total organic carbon (TOC). The anomalous behaviour starts after this SEC minimum, when SEC rises again and remains elevated during the entire high‐flow period, typically 20–40 µS/cm above the baseflow value. This is explained by variable catchment boundaries: When the water level in the aquifer rises, the catchment expands, incorporating zones of groundwater with higher SEC, caused by higher unsaturated zone thickness and subtle lithologic changes. This conceptual model has been checked by numerical investigations. A generalized finite‐difference model including high‐conductivity cells representing the conduit network (“discrete‐continuum approach”) was set up to simulate the observed behaviour of the karst system. The model reproduces the shifting groundwater divide and the nearly simultaneous increase of discharge and SEC during high‐flow periods. The observed behaviour is relevant for groundwater source protection zoning, which requires reliable delineation of catchment areas. Anomalous behaviour of SEC can point to variable catchment boundaries that can be checked by tracer tests during different hydrologic conditions. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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Pascale M. Biron Andr G. Roy Franois Courschesne William H. Hendershot Benoît Ct Jim Fyles 《水文研究》1999,13(11):1541-1555
The relationship between stream discharge and the concentration of different solutes reflects the hydrological processes occurring in a catchment, but is also strongly affected by antecedent moisture conditions. In this study, the effects of antecedent conditions were examined for a small forested watershed near Montréal (Québec) by comparing data from sequences of fall events for two years of contrasting antecedent moisture conditions. The relationship between discharge and stream water chemistry was also quantified using cross‐correlation analysis. Results show that concentrations of dissolved organic carbon, nitrate and calcium increased during storm events with dry antecedent conditions but that the relationships were weaker under wet conditions. For both years, concentrations of sulfate, silicon and sodium and the pH were negatively correlated with discharge (cross‐correlations from −0·20 to −0·53). With dry antecedent conditions, there was a general decrease in the concentration of all solutes with time, whereas concentrations remained at about the same level under wet conditions. The concentration–discharge relationships for sulfate shifted frequently from higher concentrations during the rising limb to higher concentrations during the falling limb from one event to another as a result of changing antecedent conditions. Although the contrast in antecedent moisture conditions between the two years was moderate in comparison with that reported in other studies (25% dryer than average in 1995 and 12% wetter than average in 1996), the hydrochemistry of the stream was markedly different. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献
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