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Abstract: The hydrothermal alteration patterns associating with the gold prospect hosted by metavolcanics in the Dungash area, Eastern Desert of Egypt, were investigated in order to assign their relationship to mineralization. The metavolcanics of andesitic composition are generated by regional metamorphism of greenschist facies superimposed by hydrothermal activity. Epidote and chlorite are metamorphic minerals, whereas sericite, carbonates, and chlorite are hydrothermal alteration minerals. The auriferous quartz vein is of NEE‐SWW trend and cuts mainly the andesitic metavolcanics, but sometimes extends to the neighbouring metapyroclastics and metasediments. Quartz‐sericite, sericite, carbonate‐sericite, and chlorite‐sericite constitute four distinctive alteration zones which extend outwards from the mineralized quartz vein. The quartz‐sericite and sericite zones are characterized by high contents of SiO2, K2O, Rb, and As, the carbonate‐sericite zone is by high contents of CaO, Au, Cu, Cr, Ni, and Y, and the chlorite‐sericite zone is by high contents of MgO, Na2O, Zn, Ba, and Co. Gold and sulphide minerals are relatively more abundant in the carbonate‐sericite zone followed by the sericite one. The geochemistry of the alteration system was investigated using volume‐composition and mass balance calculations. The volume factors obtained for the different alteration zones, mentioned above (being 1.64, 1.19, 1.17, and 1.07, respectively), indicate that replacement had taken place with a volume gain. The mass balance calculations revealed addition of SiO2, K2O, As, Cu, Rb, Ba, Ni, and Y to the system as a whole and subtraction of Fe2O3 from the system. Initial high aK+ and aH+ for the invading fluids is suggested. As the fluids migrated into wallrocks, they became more concentrated in Mg, Ca, and Na with increasing activities of CO2 and S. The calculated loss‐gain data are in agreement with the microscopic observations. Breakdown of ferromagnesian minerals and feldspars in the quartz‐sericite, sericite, and chlorite‐sericite zones accompanied by loss in Mg, Fe, Ca, and Na under acidic conditions and low CO2/H2O ratio may obstruct the formation of carbonates and sulphides, and the precipitation of gold in these zones. The role of metamorphic fluids in the area is expected to be restricted to the liberation of Au and some associated elements from their hosts.  相似文献   
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湖南芙蓉锡矿区是近年来新发现并正在进行勘查的新矿区,该矿区以锡矿产于花岗岩大岩体内部和潜在的巨大找矿潜力而引人注目,在野外初步调查的基础上,结合室内工作,认为芙蓉锡矿及其相关的岩浆岩在许多方面与众不同,如:产于岩体内部,蚀变花岗岩中浸染状石矿化,锡石-硫化物型及锡石-磁铁矿型等不同类型的矿化同时存在,绿泥石化发育且不同类型的锡矿化对应于不同的绿泥石成分,花岗岩类岩石低SiO2,高Sr等地球化学异常,本文主要探讨矿化及含矿岩体的某些地球化学异常并提出深部找铜的意见。  相似文献   
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鹿井铀矿田位于桃山-诸广铀成矿带的南西部,是华南最主要花岗岩型铀矿田之一,碎裂蚀变岩型铀矿化在该矿田占主导地位,小山铀矿床是近年来新发现的碎裂蚀变岩型铀矿床之一。绿泥石化是该铀矿化重要的蚀变类型和找矿标志,然而针对绿泥石特征及其与铀成矿的关系研究较为薄弱。本文以钻孔ZK1-1揭露的热液蚀变带为研究对象,对绿泥石开展精细矿物学研究。结果表明:(1)小山铀矿床主要存在4种形态类型的绿泥石,分别为黑云母蚀变型、长石蚀变型、裂隙充填型和与铀矿物密切共生型;(2)绿泥石以富铁的铁镁绿泥石为主,部分为蠕绿泥石;(3)绿泥石的形成温度在213.5~249.8℃之间,平均值为233.4℃,属中低温条件;(4)绿泥石形成于低氧逸度、高硫逸度的还原环境,形成机制包括溶解—沉淀和溶解—迁移—沉淀,其中晶质铀矿、独居石以及磷钇矿矿物发生溶解,形成铀石—钍石矿物;(5)绿泥石蚀变改变了围岩性质、铀的赋存状态以及物理化学环境,促使铀的活化、迁移以及沉淀。  相似文献   
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泥岩埋藏成岩过程中绿泥石的演化途径及意义   总被引:1,自引:0,他引:1       下载免费PDF全文
粘土矿物是泥质沉积岩重要的组成部分。在温度、压力、阳离子及水/岩比值等多种因素的共同作用下,埋藏成岩过程常常伴随着不同粘土矿物间的相互转化:蒙脱石、伊利石、高岭石和磁绿泥石等矿物均可发生绿泥石化。但各种矿物发生绿泥石化条件及反应机制不同,形成的绿泥石在化学成分及构型方面也有很大差异,通过X-射线衍射(XRD)、电子探针(EMPA)和高分辨率透射电子显微镜(HRTEM)等测试手段可识别出不同类型的绿泥石,区分不同转化序列并分析其转化机制。不同转化序列形成的绿泥石,不仅受温度的控制,还受阳离子类型和浓度的控制,在利用绿泥石作为地温计时需慎重;不同转化序列绿泥石化过程中都有水的参与,并伴有氢离子释放或消耗,这将会对有机质生烃产生影响。因此,关注泥岩埋藏成岩过程中绿泥石演化途径的差异,对拓宽绿泥石化的地质应用领域,特别是粘土矿物—有机质的协同作用具有重要的意义。  相似文献   
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