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为研究缅甸翡翠中的哪些部位适合做烧红处理以及该部位能被烧红的原因,采用加热实验、偏光显微镜、红外光谱及差热分析方法对缅甸翡翠样品的原生部位、雾部位的加热前、后的特征进行了测试与分析。结果显示,翡翠中的蓝雾部位及黄雾部位适合做烧红处理,原生部位不适合烧红处理,蓝雾部位可以被烧成黄色及红色,黄雾部位可以被烧成红色。雾部位适合用来做烧红处理的原因在于,在低温的加热条件下,蓝雾部位中的大量的Fe2+发生价态变化,实现由绿泥石向针铁矿的转变所导致,该过程由表及里逐步进行。原生部位的主要矿物硬玉需被加热更高的温度,在破坏其晶格的情况下,才可以呈现出红色,且该红色不具有褐色调。  相似文献   
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近两年,我国珠宝市场上出现了大量的"西安绿""丹东绿"等绿色印材,其多被用来仿冒绿色寿山石("月尾绿"),并以高价售卖。采用X射线粉末衍射仪,电感耦合等离子质谱仪,扫描电子显微镜等测试仪器,对"西安绿""丹东绿"的矿物组成、化学成分以及微观结构进行分析,并与寿山"月尾绿"的宝石矿物学特征进行了对比。结果表明,"月尾绿"主要由铬云母组成,Cr,Fe元素是其呈浅绿色并略带灰黄色调的主要原因之一;"西安绿"主要由伊利石组成,其Cr,V元素的质量分数远高于"月尾绿"中的,且前者几乎不含Fe元素,这可能是其呈艳丽绿色的主要原因;"丹东绿"主要由斜绿泥石组成,Fe元素的质量分数较高且几乎不含Cr元素,致使其呈现较深的暗绿色。扫描电子显微镜的观察结果发现,与"月尾绿"相比,"西安绿"中伊利石的片晶厚、粒度小,"丹东绿"中斜绿泥石的片晶薄、堆积紧密,挠性发育。这三种绿色印章石在绿色色调、光泽、密度、内含物等方面存在不少的差异,可作为其鉴别特征。  相似文献   
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Chromitites, associated with upper mantle spinel peridotites from the Voidolakkos and Xerolivado districts, located in the Vourinos ophiolite complex, northwestern continental Greece, were re‐investigated with respect to their structural and textural mode of occurrence, as well as their compositional signatures. They include variably deformed banded and podiform chromitite bodies made up of massive, semi‐massive, nodular, anti‐nodular, schlieren and disseminated chromian spinel. Chromitites have suffered intense shearing that was more severe in all but disseminated textured ore. Deformation has partly produced elongation of chromian spinel nodules and widespread protocataclastic zones within chromitites. The examined deposits are composed of magnesiochromite that shows a quite restricted range of Cr# [Cr/(Cr + Al)] values varying between 0.76 and 0.83, whereas Mg# [Mg/(Mg + Fe2+)] ranges from 0.55 to 0.67 accompanied by relatively low content in TiO2 (<0.15 wt.% on average). Compositional data indicate that these high‐Cr chromitite bodies crystallized from melts of boninitic affinities that have been compositionally modified after reaction with depleted harzburgite, followed by interaction with relatively undifferentiated low SiO2 melts within an intertwined system of dunite channels in the mantle wedge below the fore‐arc region of a supra‐subduction zone (SSZ). Magnesiochromite displays limited textural modification, being scarcely transformed to an opaque spinel phase along grain boundaries and fracture walls. The opaque spinel phase is characterized by elevated Cr# (0.76–0.97), relatively low Mg# (0.33–0.63) and low Fe3+# (≤0.14) and corresponds to ferrian chromite. Microscopic studies revealed that ferrian chromite is paragenetically associated with clinochlore even in unaltered chromitite specimens and the degree of serpentinization does not correlate with the frequency and abundance of alteration effects on magnesiochromite. Therefore, it is supported that regional metamorphism prior to serpentinization was responsible for the formation of the ferrian chromite–clinochlore association. In addition, magnesiochromite alteration was systematically recorded only in variably sheared chromitites displaying protocataclastic brecciation, thus it can be claimed that metamorphism was mainly governed by deformation mechanisms, which took place during the transition from ductile to semi‐brittle conditions. Ferrian chromite can be locally erratically enriched in MnO and ZnO, which is attributed to a Mn‐ and Zn‐bearing, slightly acid post‐magmatic fluid that invaded the chromitites across weakness zones. Overall, the data suggest that after magnesiochromite equilibration with the intergranular olivine, both phases were partly replaced by ferrian chromite and clinochlore, respectively, during a brief, fluid assisted episode of retrogade metamorphism that took place within a temperature interval between 700 and 300 °C, before ocean‐floor alteration. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
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新疆萨尔托海铬铁矿硼的地球化学晕特征及其地质意义   总被引:1,自引:0,他引:1  
本文通过对该区铬铁矿的矿床学及硼的地球化学晕特征等方面的详细研究,提出萨尔铬铁矿矿床后期成矿的看法,根据硼异常与矿体之间的密切关系,分析了该矿床后期成矿特征及形成机理。通过原始岩浆结晶分异作用产生的含大量H_2O,B,S,CO_2等挥发分的含矿熔融体最终是在岩体蛇纹石化之后凝固的,其产物除造矿铬尖晶以外,还有脉石矿物斜绿泥石、磁黄铁矿、针镍矿等热液矿物。  相似文献   
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