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1.
Silica depleted melting of pelites. Petrogenetic grid and application to the Susqueda Aureole, Spain 总被引：2，自引：0，他引：2
Metapelitic rocks in the low pressure contact metamorphic aureole around the Susqueda igneous complex, Spain show a number of features that make them an ideal testing ground for the modelling of silica‐undersaturated melting. Rocks in the aureole experienced localized depletion in silica by the segregation of quartz veins during a pre‐anatectic, regional cordierite‐andalusite grade metamorphic event. These rocks were then intruded by gabbroic to dioritic rocks of the Susqueda igneous complex that formed a migmatitic contact metamorphic aureole in the country rocks. This migmatisation event caused quartz‐saturated hornfels and restite formation in rocks that had experienced no quartz vein segregation in the previous regional metamorphic event, but silica‐undersaturated melting in those rocks that were previously depleted in silica. Silica‐undersaturated melting is investigated using a new petrogenetic P–T projection and equilibrium pseudosections calculated in the KFMASH and NCKFMASH systems, respectively. The grid considers quartz absent equilibria and a range of phases that form typically in silica‐undersaturated bulk compositions, for example corundum. It is shown that the quartz‐rich precursors in the Susqueda contact aureole produced about 10% melt during contact metamorphism. However, most of this melt was extracted leaving behind rocks with restitic bulk compositions and minor leucosome segregation. It is suggested that the melt mixed with the host igneous rocks causing an apparent magmatic zoning from diorite in the centre of the complex to tonalite at the margins. In contrast, the quartz‐poor precursors (from which the quartz veins segregated) melted in the silica‐undersaturated field producing a range of assemblages including peritectic corundum and spinel. Melting of the silica‐undersaturated rocks produced only negligible melt and no subsequent melt loss. 相似文献
2.
Xenoliths of quartz‐absent Fe‐rich aluminous metapelite are common within the platinum group element‐rich mafic/ultramafic magmatic rocks of the Platreef. Relative to well‐characterized protoliths, the xenoliths are strongly depleted in K2O and H2O, and have lost a substantial amount of melt (>50 vol.%). Mineral equilibria calculations in the NCKFMASHTO system yield results that are consistent with observations in natural samples. Lower‐grade rocks that lack staurolite constrain peak pressures to ～2.5 kbar in the southern Platreef. Smaller xenoliths and the margins of larger xenoliths comprise micro‐diatexite rich in coarse acicular corundum and spinel, which record evidence for the metastable persistence of lower‐grade hydrous phases and rapid melting consequent on a temperature overstep of several hundred degrees following their incorporation in the mafic/ultramafic magmas. In the cores of larger xenoliths, temperatures increased more slowly enabling progressive metamorphism by continuous prograde equilibration and the loss of H2O by subsolidus dehydration; the H2O migrated to xenolith margins where it may have promoted increased melting. According to variations in the original compositional layering, layers became aluminosilicate‐ and/or cordierite‐rich, commonly with spinel but only rarely with corundum. The differing mineralogical and microstructural evolution of the xenoliths depends on heating rates (governed by their size and, therefore, proximity to the Platreef magmas) and the pre‐intrusive metamorphic grade of the protoliths. The presence or absence of certain phases, particularly corundum, is strongly influenced by the degree of metastable retention of lower‐grade hydrates in otherwise identical protolith bulk compositions. The preservation of fine‐scale compositional layering that is inferred to be relict bedding in xenolith cores implies that melt loss by compaction was extremely efficient. 相似文献
3.
大别山北部红刚玉矿产在太古代大别山群黑云角门外长片麻岩以及超基性岩中。赋存红刚玉的刚玉黑云二长片麻岩的原始岩石为富铝泥质岩，在角门岩相变质条件下，通过两种脱硅方式，即变质分异作用和超基性岩侵位，形成刚玉黑云二长片麻岩。它们形成的温压条件：Ｔ＝５００℃～７００℃，Ｐ＝０．４～０．７ＧＰａ。刚玉形成的可能的化学机制是白云母在缺硅条件下的分解。 相似文献
4.
Rachelle B. Turnier Yaron Katzir Kouki Kitajima Ian J. Orland Michael J. Spicuzza John W. Valley 《Journal of Metamorphic Geology》2020,38(1):53-70
Corundum (Crn), including sapphire, occurs in emery pods surrounded by marble on the island of Naxos, Greece. The emery formed from bauxite deposited in karst that was metamorphosed to 400–700°C at 20–15 Ma. Many of these rocks initially appeared well suited for refractory accessory mineral (RAM) thermometry, which uses oxygen isotope fractionation between a RAM – corundum – and a modally dominant phase with faster diffusion of oxygen – calcite (Cc) – to determine peak metamorphic temperatures. However, previous attempts at oxygen isotope thermometry were confounded by highly variable fractionations (Δ18O) measured at mm-scale and the uncertain calibration of Δ18O(Cc-Crn) versus temperature. Secondary ion mass spectrometry (SIMS) permits in situ analysis of δ18O in corundum and calcite at the 10-μm scale in adjacent grains where textures suggest peak metamorphic equilibrium was attained. SIMS analyses of adjacent mineral pairs in eight rocks yield values of Δ(Cc-Crn) that systematically decrease from 7.2 to 2.9‰ at higher metamorphic grade. Pairing these data with independent temperature estimates from mineral isograds yields an empirical calibration of 1,000 lnα(Cc-Crn) = 2.72 ± 0.3 × 106/T2 (T in K). The new fractionations (2.7‰ at 1,000 K) are significantly smaller than those calculated from the modified increment method (6.5‰ at 1,000 K; Zheng, Geochimica et Cosmochimica Acta, 1991, 55:2299–2307; Zheng, Mineral Mag, 1994, 58A:1000–1001), which yield unreasonably high temperatures of 630 to 1,140°C when applied to the new Naxos data. The new calibration of Δ(Cc-Crn) can be combined with published fractionations to calculate A-factors for corundum versus a range of 14 other minerals. These new fractionation factors can be used for thermometry or to constrain the genesis of corundum. A compilation of gem corundum δ18O values shows that many igneous sapphires, including important deposits of basalt-associated sapphire, are mildly elevated in δ18O relative to the calculated range in equilibrium with mantle values (4.4–5.7‰) and formed from evolved magmas. 相似文献
5.
S. V. Vysotsky V. V. Yakovenko A. V. Ignat’ev A. A. Karabtsov 《Russian Journal of Pacific Geology》2009,3(1):64-68
This paper reports an oxygen isotopic study of corundums and associated minerals from the Yogo lamprophyres (Montana, US), plagioclase-corundum inclusions in alkali basalt (Tunkin depression, Russia), and from modern alluvium of Podgelbanochnyi alkaline basaltic volcano (Primorye, Russia). It is shown that all sapphires genetically related to mafic magmatic rocks have a similar oxygen isotopic composition (the variations of δ18O are within 2.5‰) with most values plotting between +4.5 and +7.0‰ SMOW. The oxygen isotopic ratios in the associated minerals (olivines, pyroxenes, mica, and others) and host rocks are plotted in the same interval. This indicates that the sapphire crystallized during evolution of the parental mafic magma. However, there are xenogenic corundums, which were only transported by basaltic magma to the Earth’s surface. They have a sharply distinct oxygen isotopic composition, which suggests their disequilibrium with the host lavas, and, correspondingly, a different genetic nature. 相似文献
6.
根据棕刚玉难熔的特点,采用二次熔矿方式对样品进行分解,经盐酸酸化的浸提液用电感耦合等离子体发射光谱法测定硅、铁、钛、钙、镁、锆的含量。第一次加入硼酸-碳酸钠(质量比2∶1)熔矿,熔剂中大量硼酸的存在可以确保棕刚玉样品无需研磨而分解完全;但所得熔融物极难提取,通过提高熔剂中碳酸钠的比例后进行第二次熔矿,使熔融物酸化浸取变得快速简单。对硼酸-碳酸钠混合溶剂的比例、熔矿温度和时间、称样量和样品粒度等实验条件进行优化,分析结果表明方法检出限为0.0003%～0.0051%,精密度(RSD,n=11)为0.88%～4.78%。用标准物质验证,测定值与标准值相符;与国标法对比验证,测定结果相符。该方法样品分解充分,对样品的粒度适应范围宽,可满足生产控制快速检测的要求。 相似文献
7.
文章介绍了ＥＳＲ谱仪低温杜瓦差的研制原理和方法以及应用它在液氮温度下研究孔雀石中的Ｃｕ＾２＋和天然刚玉中Ｔｉ＾３＋存在形式的实验结果。 相似文献
8.
山东刚玉巨晶中包裹体研究Ⅱ：氯化物与地幔液相的物质组成 总被引：5，自引：0，他引：5
利用电子探针,扫描电镜在山东碱性玄武岩中产出的刚玉巨晶中发现了许多氯化物包裹体,这些氯化物可能以石盐为主,它的发现表明在较浅深度的地幔液相中也存在较多的氯。 相似文献
9.
明溪蓝刚中Fe主要以Fe^3 形式存在，Fe^3 的d-d电子跃迁和Fe^2 -Ti^4 /Fe^3 -Ti^3 、O^2-Fe^3 间电荷转移是致色的主要因素；浓度差可以作为扩散动力；氢含量的提高可以促进蓝色致因子的形成。采用高温高压水溶液方法对蓝刚玉进行改色处理，可消除刚玉中的杂色调，使颜色向纯蓝色方向变化。 相似文献
10.
“V^2＋离子在刚玉中的位置的研究 总被引：4，自引：0，他引：4
据Ｖ＾２＋离子在刚玉中的电子顺磁共振谱，我们研究了它在刚玉中的位置，研究结果表明：Ｖ＾２＋离子并不占据准确的Ａｌ＾３＋离子位置，而是沿着ｃ轴向氧八面体中心位移大约０．００４ｎｍ。位移方向和本文提出的刚玉中的杂质离子位移模型是一致的。 相似文献