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Ladda Tangwattananukul Daizo Ishiyama Osamu Matsubaya Toshio Mizuta Punya Charusiri Hinako Sato Koichiro Sera 《Resource Geology》2014,64(2):167-181
The Chatree deposit is located in the Loei‐Phetchabun‐Nakhon Nayok volcanic belt that extends from Laos in the north through central and eastern Thailand into Cambodia. Gold‐bearing quartz veins at the Q prospect of the Chatree deposit are hosted within polymictic andesitic breccia and volcanic sedimentary breccia. The orebodies of the Chatree deposit consist of veins, veinlets and stockwork. Gold‐bearing quartz veins are composed mainly of quartz, calcite and illite with small amounts of adularia, chlorite and sulfide minerals. The gold‐bearing quartz veins were divided into five stages based on the cross‐cutting relationship and mineral assemblage. Intense gold mineralization occurred in Stages I and IV. The mineral assemblage of Stages I and IV is characterized by quartz–calcite–illite–laumontite–adularia–chlorite–sulfide minerals and electrum. Quartz textures of Stages I and IV are also characterized by microcrystalline and flamboyant textures, respectively. Coexistence of laumontite, illite and chlorite in the gold‐bearing quartz vein of Stage IV suggests that the gold‐bearing quartz veins were formed at approximately 200°C. The flamboyant and brecciated textures of the gold‐bearing quartz vein of Stage IV suggest that gold precipitated with silica minerals from a hydrothermal solution that was supersaturated by boiling. The δ18O values of quartz in Stages I to V range from +10.4 to +11.6‰ except for the δ18O value of quartz in Stage IV (+15.0‰). The increase in δ18O values of quartz at Stage IV is explained by boiling. PH2O is estimated to be 16 bars at 200°C. The fCO2 value is estimated to be 1 bar based on the presence of calcite in the mineral assemblage of Stage IV. The total pressure of the hydrothermal solution is approximately 20 bars at 200°C, suggesting that the gold‐bearing quartz veins of the Q prospect formed about 200 m below the paleosurface. 相似文献
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关于成岩作用与变质作用界线的讨论：从沸石相谈起 总被引：15，自引：1，他引：15
成岩作用与变质作用界线的划分是当前地质学界关注的焦点之一。传统的观点将沸石相作为最低级变质相，本文以鄂尔多斯盆地东部上三叠统延长组的浊沸碱玫吐鲁番－哈密盆地哈密凹陷三叠系的浊沸石为例，提出浊沸石的形成为高ｐＨ值，低Ｐｃｏ２和Ｘｃｏ２高钙离子活度，高ＳｉＯ２活性的高盐度等，稳定在从８０℃到２００℃左右的广大温度范围内，常与油气生成带一致，属成岩矿物相，取消沸石相，用明确的综合划分标志来确定成岩作用与 相似文献
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Abstract. Sandstones with high reservoir quality occur in the Paleogene and Upper Cretaceous coal measures off Sanriku and Sohma in the Pacific coast of northeast Honshu. The sandstone porosity was generally produced by the dissolution of calcite cement and clastic grains such as feldspar and glassy volcanics. The most probable cause of dissolution is the organic acids generated from the maturation of coal and coaly matter in the deeply subsiding source area prior to thermogenic hydrocarbon generation. The pore fluid including organic acids dissolved calcite and clastic silicates to form a small amount of laumontite and kaolinite at around 60C. The acidic and not neutralized pore fluid was responsible for the formation of kaoli-nite. On the other hand, laumontite was formed when the acidic pore fluid was neutralized and then made alkaline after the reaction with minerals such as plagioclase, glassy volcanics and calcite cement. Therefore, laumontite and kaolinite generally occur separately. Laumontite is 0.6–4.6 % by volume, whereas kaolinite is 0.6–9.8 % and the sandstone porosity remains from 10 to 22 %. This type of laumontization after the secondary pore formation might not give a severe damage to the reservoir property of the Paleogene and Upper Cretaceous coal measures in the Pacific coast of northeast Honshu and indicates further exploration possibility. 相似文献
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A discussion on the boundary between diagenesis and metamorphism with reference to zeolite facies 总被引：1，自引：0，他引：1
Abstract A Triassic formation in the Turpan-Hami and Ordos basin of China gives two typical examples of occurrence of laumontite belonging to diagenetic facies. Sandstones of the Upper Triassic Yanchang Formation in the eastern sector of the Ordos basin are formed at the mature stage of mesodiagenesis at temperatures in the range of 71-120°C, while the temperatures of the oil-bearing beds Chang-6 and Chang-7 where laumontite is present are about 81-88°C. The laumontite-bearing beds of the Middle Triassic in the Hami depression are presently at the supermature stage of organic matter, the corresponding diagenetic temperature being about 140 °C. The term zeolite facies should be rejected, and the features of metamorphic stage should be clearly denned, such as closely packed grains, absence of pores and cements, and characteristic mineral assemblages including sericite, epidote, muscovite, illite (2M1 ), chlorite (IIb, β= 97°), dickite, pyrophyllite, graphite, chlorozeolite formed at temperatures of 200°C and Ro values of 2.5%; the stage is also characterized by schistosity and illite crystallinity of IC = 0.42°Δ 2θ. The anchimetamorphic zone is characterized by some characteristic minerals such as paragonite, rectorite, albite, laumontite, illite (1M), chlorite (Ib, P = 90°+ IIb, β= 97°) formed at temperatures of 130-200°C and Ro values of 1.3-2.5% as well as other quantitative parameters of organic matter. 相似文献
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Six different Ca‐zeolite minerals are widespread in various assemblages in late fissures and fractures in granites and gneisses of the Swiss Alps. The zeolites formed as a result of water–rock interaction at relatively low temperatures (<250 °C) in the continental upper crust. The zeolites typically overgrow earlier minerals of the fissure assemblages, but zeolites also occur as monomineralic fissure fillings. They represent the youngest fissure minerals formed during uplift and exhumation of the Alpine orogen. A systematic study of zeolite samples showed that the majority of finds originate from three regions particularity rich in zeolite‐bearing fissures: (i) in the central and eastern part of the Aar‐ and Gotthard Massifs; (2) Gibelsbach/Fiesch, in a fissure breccia located at the boundary of Aar Massif and Permian sedimentary rocks; and (3) in Penninic gneisses of the Simano nappe at Arvigo (Val Calanca). Rail and road tunnel construction across the Aar‐ and Gotthard Massif provided excellent data on zeolite frequency in Alpine fissures. It was found that 32% (Gotthard NEAT rail base tunnel, Amsteg section) and 18% (Gotthard road tunnel) of all studied fissures are filled with zeolites. The number of different zeolites is limited to six species: laumontite, stilbite and scolecite are abundant and common, whereas heulandite, chabazite and epistilbite occur occasionally. Calcium is the dominant extra‐framework cation, with minor K and Na. Heulandite and chabazite contain Sr up to 29 and 10 mol.% extra‐framework cations respectively. Na and K contents in zeolites tend to increase during growth as a result of changes in fluid composition and/or temperature. The K enrichment of stilbite found in surface outcrops compared to subsurface samples may indicate late stage cation exchange with surface water. Texture data, relative age sequences derived from fissure assemblages and equilibrium calculations show that the Ca‐dominated zeolites precipitated from fluid with decreasing temperature in the order (old to young = hot to cold): scolecite, laumontite, heulandite, chabazite and stilbite. The necessary components for zeolite formation are derived from dissolving primary granite and gneiss minerals. The nature of these minerals depends, among other factors, on the metamorphic history of the host rock. Zeolites in the Aar Massif derived from the dissolution of epidote, secondary calcite and albite that were originally formed during Alpine greenschist metamorphism from primary granite and gneiss assemblages. Zeolite fissures occur in areas of H2O‐dominated fluids. This is consistent with equilibrium calculations that predict a low CO2 tolerance of zeolite assemblages, particularly at low temperature. 相似文献
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松辽盆地北部深层碎屑岩浊沸石成因、演化及与油气关系研究 总被引：8，自引：0，他引：8
浊沸石作为松辽盆地深层最重要的一种成岩自生矿物，分布广泛，后期受成岩改造强烈，形成了高产的次生孔隙气藏。通过X射线衍射分析、X射线粉晶分析、红外光谱分析和显微热台等分析，确定了松辽盆地深层碎屑岩内浊沸石含量及矿物学特征，探讨了浊沸石的成因；利用扫描电镜和图像分析仪系统研究了浊沸石溶孔特征和深层有机酸与浊沸石次生孔隙的成因关系，指出浊沸石溶孔在纵向上呈发育到较发育到不发育的旋回性变化，溶孔发育段厚度一般2～3m，平面上升平-汪家屯和昌德地区浊沸石溶孔可能连片；浊沸石次生孔隙形成期与天然气主运聚期具较好的匹配关系，并使被浊沸石胶结的砂岩表现出双重性：早期封盖，晚期储集．表明次生孔隙发育带最有可能成为高产油气层。 相似文献