高温高压下Mg2SiO4-MgAlO4体系相变的实验研究     

翟双猛  陈汉林  费英伟  杨树锋 《矿物学报》2003,23(3):267-272

采用多顶砧高压实验装置研究了Mg2SiO4-MgAl2O4体系在压力为22 GPa,温度为1550～1750℃条件下的相变,并考查了Al2O3在γ相中的固溶度.结果表明,随着体系中MgAl2O4组分含量的增加,相组合发生了变化,依次为γ相+镁铝硅酸盐固溶体+方镁石→镁铝硅酸盐固溶体+方镁石→镁铝硅酸盐固溶体+方镁石+刚玉固溶体;镁铝硅酸盐固溶体具有石榴子石结构,其化学成分随着体系中共存相的改变而有所变化;Al2O3在γ相中的固溶度很低(其重量百分比＜0.8%),因此,在Mg2SiO4-MgAl2O4体系中Al2O3可能对γ相超尖晶石分解转变的压力不会有很大的影响.  相似文献   

Elasticity of pyrope and majorite-pyrope solid solutions to high temperatures     

Stanislav V. Sinogeikin  Jay D. Bass 《Earth and Planetary Science Letters》2002,203(1):549-555

Majorite-garnet solid solutions are major mineral phases in the Earth’s upper mantle and transition zone. Here we present the first Brillouin scattering measurements of the elasticity of majorite (Mj, Mg₄Si₄O₁₂)-pyrope (Py, Mg₃Al₂Si₃O₁₂) solid solutions (Mj₅₀Py₅₀ and Mj₈₀Py₂₀) and single-crystal elasticity of pure synthetic pyrope at temperatures up to 800°C. The temperature derivatives of the adiabatic bulk (K_S) and shear (μ) moduli for all compositions along the Mj-Py join are the same within the experimental uncertainties (−∂K_S/∂T=14.0-14.5(20) MPa/K, −∂μ/∂T=8.3-9.2(10) MPa/K). The temperature dependence of the acoustic velocities for Mj-Py solid solutions is about half that of other major transition zone minerals. This implies that temperature variations in the transition zone, inferred from lateral velocity heterogeneity, can be significantly underestimated if the properties of majoritic garnet are not taken into account.  相似文献   

Titanium solubility in coexisting garnet and clinopyroxene at very high pressure: the significance of exsolved rutile in garnet   总被引：3，自引：0，他引：3  

R.Y. Zhang  S.M. Zhai  J.G. Liou 《Earth and Planetary Science Letters》2003,216(4):591-601

Exsolution microstructures including ilmenite±garnet in clinopyroxene and rutile in garnet are common in clinopyroxenite and eclogite from the Sulu ultrahigh-pressure (UHP) terrane. In order to understand the phase relations and Ti solubility in both garnet and clinopyroxene in a natural TiO₂-bearing system, several experiments at 5-15 GPa, 1000-1400°C were carried out using the multianvil high-pressure apparatus. The Hujianlin ilmenite-rich garnet clinopyroxenite showing exsolution microstructure was selected as starting material, because it closely approaches a composition lying in the TiO₂-CaO-MgO-FeO-Al₂O₃-SiO₂ system. Except for minor melt in one experiment at 1400°C and 5 GPa, other run products contain majoritic garnet+clinopyroxene±ilmenite (or rutile) and exhibit neoblastic texture. With increasing pressure, Ti and Ca, Mg and Si contents of neoblastic garnet increase with decreasing Al. The principal coupled substitutions are Ca²⁺Ti⁴⁺→2Al³⁺ and Si⁴⁺Mg²⁺→2Al³⁺ responding to majorite component increase. Titanium solubility (0.8-4.5 wt% as TiO₂) in garnet and Grt_Ti/Cpx_Ti ratio have a pronounced positive correlation with pressure between 5 and 15 GPa. On the other hand, the coexisting clinopyroxene contains low Ti (0.17-0.53 wt% as TiO₂), and shows no significant pressure effect. Rutile exsolution in garnet is coupled to that of pyroxene exsolution; both are exsolved from majoritic garnet on decompression. Therefore, the amount of such exsolved lamellae is a potential indicator of high-pressure metamorphism in exhumed rocks, whereas the TiO₂ content of clinopyroxene coexisting with garnet is not sensitive to pressure change.  相似文献   

安徽栏杆含金刚石基性岩中石榴子石矿物学特征     

蔡逸涛  张洁  康丛轩  杨献忠  曹正琦  董钟斗  马玉广  施建斌 《地质通报》2019,38(1):110-120

在中国东部皖北地区分布着新元古代镁铁质岩,其中一些碱性基性岩为金刚石的赋矿岩石。为了确定安徽栏杆金刚石矿区的石榴子石种类,对矿区内不同类型的石榴子石进行系统采样,测定了62件石榴子石微区化学成分。结果显示,安徽栏杆石榴子石矿物化学式A_3~(2+)B_2~(3+)(SiO_4)_3中的A组阳离子由Mg~(2+)、Fe~(2+)和Ca~(2+)离子占位,B主要由Al~(3+)、Fe~(3+)、Mn~(3+)和Cr~(3+)离子占位,三价阳离子主要为Al~(3+),二价阳离子主要为Ca~(2+),表明研究区石榴子石主要为钙铝-钙铁-镁铝石榴子石系列。在62个样品中,发现了超硅石榴子石。经过计算其形成的压力范围为12.1～12.8GPa,深度可达300km。  相似文献