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ZHI Xiachen CHEN Peng LIN Chengzhong CHEN Shuqing ZHANG Guilan LI Yuzhi LIN Lei 《《地质学报》英文版》2001,75(1):51-58
The Mössbauer spectra of natural megacrystal clinopyroxene are usually fitted by 4 sets of symmetric doublets, A‐A', B‐B', C‐C' and D‐D', respectively, in terms of increasing Qs value in literature. But the assignments of those doublets are quite different, except the D‐D' doublet assigned to Fe3+at the lattice site M***1 in previous papers. Particularly, the assignment and interpretation of the C‐C' doublet are diverse. The oxidation experiments of natural megacrystal clinopyroxene collected from the Hannuoba basalt, North China, were performed under controlled conditions of temperature at 1000°C and oxygen fugacity of FMQ buffer in 1, 2, ***3 and 5 days respectively. The oxidized samples were then measured by X‐ray diffraction spectrometry and Mössbauer spectrometry. The oxidation of clinopyroxene is characterized by Fe2+ → Fe3+at M1 under the subsolidus conditions, which is consistent with the increase of the area of the D‐D' doublet when the heating time increases. Accordingly, the area of the A‐A' and B‐B' doublets decreases with the increasing heating time. However, the area of C‐C' keeps almost constant. Therefore, the 4 sets of doublets can be assigned correctly as follows: A‐A' doublet to Fe+2at M1, B‐B' Fe2+at M1, C‐C' Fe2+at M2, and D‐D' Fe3+at M1. The M1 site splitting is due to the NNN (Next Nearest Neighbour) effect of the M2 site. The amount of Fe3+at the tetrohedral site of megacrystal clinopyroxene is negligible according to this study. 相似文献
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ZHI Xiachen CHEN PengDepartment of Earth Space Sciences University of Science Technology of Chin Laboratory of Chemical Geodynamics USTC Advanced Research Center for Earth Science Astronomy in USTC Third World Academy of Science Hefei LIN Chengzhong CHEN Shuqing ZHANG GuilanInstitute of Mineral Resources Chinese Academy of Geology Sciences Beijing LI Yuzhi LIN Lei Open Laboratory of Structure Analysis USTC Hefei 《《地质学报》英文版》2001,75(1)
The Mossbauer spectra of natural megacrystal clinopyroxene are usually fitted by 4 sets of symmetric doublets, A-A', B-B', C-C' and D-D', respectively, in terms of increasing Qs value in literature. But the assignments of those doublets are quite different, except the D-D' doublet assigned to Fe3+ at the lattice site Ml in previous papers. Particularly, the assignment and interpretation of the C-C' doublet are diverse.The oxidation experiments of natural megacrystal clinopyroxene collected from the Hannuoba basalt, North China, were performed under controlled conditions of temperature at 1000℃ and oxygen fugacity of FMQ buffer in 1, 2, 3 and 5 days respectively. The oxidized samples were then measured by X-ray diffraction spectrometry and Mossbauer spectrometry. The oxidation of clinopyroxene is characterized by Fe2+→ Fe3+ at Ml under the subsolidus conditions, which is consistent with the increase of the area of the D-D' doublet when the heating time increases. Accordingly, the area of the A-A' and B 相似文献
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英安岩中高压辉石巨晶的发现及其意义 总被引：5，自引：0，他引：5
在吉林省九台市官马山晚侏罗世英安岩中发现了辉石巨晶。研究表明。该巨晶不是英安岩浆的结晶产物，英安岩的岩相关及地球化学特征显示，它是酸性流纹岩浆与基性偏碱性的玄武岩浆经混合作用形成的，辉石巨晶是后一种岩浆在高压条件下结晶的产物，对辉石巨晶的温压计算结果表明，该矿物结晶温度为１２７６℃，压力为１．２７ＧＰａ。这一深度可相当于该区软流层的顶界。可以认为，晚侏罗－早白垩世火山岩形成于地壳较厚的环境。 相似文献
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利用电子探针、扫描电镜分析技术在产自山东碱性玄武岩的刚玉巨晶中发现了尖晶石族氧化物包体,并有许多刚玉、钛铁矿、高硅氧化物、辉石、长石、方解石等包体.这些包体矿物的化学成分明显与该地区相应的巨晶矿物不同,具有深源性的特征.刚玉巨晶具有世代现象,其生长具有明显的阶段性,是在一种高度演化的富含SiO_2岩浆中生成,生长过程极其复杂. 相似文献
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ZHI Xiachen CHEN PengDepartment of Earth Space Sciences University of Science Technology of Chin Laboratory of Chemical Geodynamics USTC Advanced Research Center for Earth Science Astronomy in USTC Third World Academy of Science Hefei LIN Chengzhong CHEN Shuqing ZHANG GuilanInstitute of Mineral Resources Chinese Academy of Geology Sciences Beijing LI Yuzhi LIN Lei Open Laboratory of Structure Analysis USTC Hefei 《《地质学报》英文版》2001,75(1)
The Mossbauer spectra of natural megacrystal clinopyroxene are usually fitted by 4 sets of symmetric doublets, A-A', B-B', C-C' and D-D', respectively, in terms of increasing Qs value in literature. But the assignments of those doublets are quite different, except the D-D' doublet assigned to Fe3+ at the lattice site Ml in previous papers. Particularly, the assignment and interpretation of the C-C' doublet are diverse.The oxidation experiments of natural megacrystal clinopyroxene collected from the Hannuoba basalt, North China, were performed under controlled conditions of temperature at 1000℃ and oxygen fugacity of FMQ buffer in 1, 2, 3 and 5 days respectively. The oxidized samples were then measured by X-ray diffraction spectrometry and Mossbauer spectrometry. The oxidation of clinopyroxene is characterized by Fe2+→ Fe3+ at Ml under the subsolidus conditions, which is consistent with the increase of the area of the D-D' doublet when the heating time increases. Accordingly, the area of the A-A' and B 相似文献
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巨晶锆石由于稳定性强，能够很好地保存其形成时的标型和化学特征而成为最重要的矿物地球化学探针之一。本文在通过对冀东马兰峪腰岭子花岗闪长岩中锆石矿物进行阴极射线致发光（CL）图像分析、晶体形态学统计学分析的基础上，结合等离子质谱（LA-ICP-MS）测试工作，解析了马兰峪金矿花岗闪长岩中巨晶锆石的微量元素组成特征，并依据Pupin等（1980）提出的锆石类型分类的主型和亚型及其地质温度表，研究结果表明：巨晶锆石的形成温度650~850℃，巨晶锆石的LA-ICP-MS分析显示Ce正异常和不明显Eu的负异常，并且富集重稀土元素；巨晶锆石可能与区内峪耳崖式金矿存在成因联系。 相似文献
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