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不同温度、羧酸溶液中长石溶解模拟实验 总被引：24，自引：2，他引：22
报道了在100℃、140℃下微斜长石在不同羧酸溶液中的溶解实验数据。通过实验表明1)反应温度增高,可增强溶液中阳离子的活性和迁移性,加快长石溶解的反应速率,促进长石的溶解。2)在强酸性条件下,pH值的变化可影响长石的溶解。但在中等酸性条件下,pH值对长石的溶解影响很小。3)羧酸(乙二酸)可不同程度地促进长石溶解,可通过形成乙二酸络合物的形式,增加离子在溶液中的溶解度。但乙酸络合物的作用不明显。长石溶蚀导致岩石孔隙度变大,并且改善孔喉性质。同时,由于乙二酸络合物的存在,增加了Si在溶液中的溶解度,阻止了石英加大和其它成因SiO2的生成,有利于次生孔隙和原生孔隙的保存。4)长石溶解使溶液中Al的浓度较高,但由于铝-羧酸络合物的亲油性比亲水性强,故有一部分Al被分配到油相中,这也是目前大多数油田水中Al浓度偏低的主要原因。 相似文献
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本文首次系统总结了钾交代型铀矿床的标型矿物——犬牙状微斜长石的五项标型特征。它们是:色深、浑浊;晶体由几组平行双面组成的似菱柱体聚形、鱼鳞状,叠瓦状集合体;三斜对称,T_(10)位铝含量高达0.91％;高钾、低钠、含铀和富铁;较小的折光率和比重。同时,建立了与标型特征相对应的矿床形成的地质地球化学条件。 相似文献
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本文利用超高压透射电子显微镜对在相当于角闪岩相条件下天然变形的微斜长石进行了初步研究。研究发现,光学显微镜下看到的一组平行细纹不是出浴条纹,而是变形条带。另一种超显微构造——滑动小叶片见于变形条带邻区,它们和另一相矿物出港或沉淀形成的小叶片不同,是由矿物的变形造成的。变形条带、滑动小叶片以及比较常见的堆垛层错都相互平行,看来都是由分位错沿同一类型的滑移面运动形成的。 相似文献
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花岗岩中的钾长石巨晶:以南岭佛冈花岗质杂岩体中微斜长石巨晶为例 总被引：10，自引：1，他引：10
野外地质观察和岩石显微结构研究表明，佛冈花岗质杂岩体中微斜长石巨晶是岩浆结晶的产物，不是交代斑晶，也不是变斑晶，它们与基质中的微斜长石构成双峰式粒径，反映了岩浆的两阶段结晶历史，由于微斜长石是钾长石的低温变体，因此一种可能的机制是佛冈花岗质杂岩岩浆在侵位和基本固结后，冷却缓慢，使早结晶的正长石转变为微斜长石，此外，在新近的研究中，还发现了罕见的，但在佛冈花岗杂岩体中为数不少的“十字”贯穿式双晶微斜长石，以及微斜长石巨晶的“环斑”和“珠边”结构。 相似文献
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A. J. Mauger K. Ehrig A. Kontonikas-Charos C. L. Ciobanu N. J. Cook V. S. Kamenetsky 《Australian Journal of Earth Sciences》2016,63(8):959-972
Twenty thousand metres of diamond drill core representing a 14 km cross-section from weakly to intensely altered Roxby Downs Granite through the Olympic Dam Breccia Complex, host to the Olympic Dam iron-oxide–copper–gold–uranium deposit in South Australia, was analysed using the HyLogger-3 spectral scanner. Thermal and shortwave infrared spectroscopy results from 30 drill holes provide insight into the spatial relationships between quartz, orthoclase–microcline, albite–oligoclase and progressively changing sericite and chlorite compositions. The relative proportions of quartz, feldspars and phyllosilicates were mapped with thermal infrared spectroscopy. Variations in the chemistry of sericite and chlorite were extracted by proxy from their shortwave infrared spectral response, together with their relative spatial distribution. HyLogger scanning has revealed four deposit-scale mineralogical trends, progressing from least-altered Roxby Downs Granite into mineralisation where most of the feldspar has been replaced by sericite + hematite + quartz: (1) a progressive Al–OH wavelength shift of 2205 nm to 2210 nm for sericite, followed by a spatially rapid reversal corresponding to lower phengite/muscovite abundance ratios; (2) progressive Mg/Fe–OH wavelength shift of 2248 nm to 2252 nm reflecting an increase in the Fe:Mg ratio of chlorite; (3) increasing ratio of microcline to orthoclase followed by a rapid decrease; and (4) slightly decreasing ratio of albite to oligoclase followed by plagioclase destruction prior to albite replacement by sericite. The HyLogger feldspar results support recent petrographic evidence for hydrothermal albite and K-feldspar at the Olympic Dam deposit, not previously reported. The spectral results from continuous HyLogger scans also show that the microscopic observations and proposed feldspar replacement reactions are not locally isolated phenomena, but are applicable at the deposit and regional-scale. A modified quartz–K-feldspar–plagioclase ternary diagram utilising mineralogy interpreted from HyLogger thermal infrared spectra (QAPTIR) diagram along with supporting data on the abundance ratios of orthoclase/microcline and albite/plagioclase, and the wavelength shifts in characteristic absorption features for sericite and chlorite, can be used as empirical vectors towards mineralisation within the Olympic Dam mineral system, with potential application to other IOCG ore-forming systems. Intrusion of Gairdner Dyke Swarm dolerite dykes into sericite ± hematite altered Roxby Downs Granite results in retrograde albite–chlorite–magnetite alteration envelopes (up to tens of metres thick) overprinting the original sericite ± hematite alteration zone and needs to be carefully evaluated to ensure that such areas are not falsely downgraded during exploration. 相似文献