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The precipitation/replacement of Ca‐phosphate is a complex process that commonly takes place during the early diagenesis in marine sediments. The unusual occurrence of shallow marine, early diagenetic phosphatic deposits associated with glassy tuffs in the Neogene Gaiman Formation, in the Chubut Province, Patagonia, Argentina, constitutes a good case example for the study of replacement and precipitation of Ca‐phosphate on an unstable substrate. Isocon diagrams illustrate that chemical changes during glass diagenesis include gains in loss on ignition and Ca, and losses of K. These changes are the result of glass hydration during sea water–glass interaction, together with adsorption and diffusion of ions into the bulk shard; combined, these represent an incipient process of volcanic glass replacement by Ca‐phosphate. Subsequent early diagenetic P enrichment in the pore solutions led to phosphate precipitation, associated with pitting on the glass shards and pumice. The associated development of a reactive surface promoted the incorporation of P and Ca into their margins. Lastly, precipitation of calcium phosphate filled the vesicles and other open cavities, inhibiting further glass dissolution. The high porosity and reactivity of the volcanic glass provided an appropriate substrate for phosphate precipitation, leading to the development of authigenic apatite concretions in the volcanic‐glass bearing strata of the Gaiman Formation. This research is of significance for those concerned with marine phosphatic deposits and sheds light on the processes of early diagenetic phosphate precipitation by replacement of an atypical, unstable substrate like hydrated volcanic glass. 相似文献
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Hard inorganic substrates (rock clasts and rocky bottom) belonging to the Ka
k Member of the Korycany Formation (upper Cenomanian–?lower Turonian) and to the Bílá Hora Formation (lower Turonian) have offered a good opportunity for the study of encrusting faunas of the Cenomanian–Turonian boundary interval. Distributional features of cemented epibionts and the recorded period of phosphogenesis enabled the differentiation of two-phases in the Ka
k Member conglomerate formation. During the first phase, the rock substrates were occupied by a so-called A-association of encrusters (29 species, with dominance of oysters and bryozoans). This fauna partly changed during the subsequent phosphogenic period and not only survived the following period of reworking and the second phase of conglomerate formation, but also persisted until the onset of calmer sedimentation in the early Turonian. This changed community is named theAtreta-Bdelloidinacommunity (23 species). The opportunistic agglutinated foraminifersBdelloidina cribrosaand/orAcruliammina longalocally dominated the respective communities during several physico-chemically stressed episodes. On sloping substrates, the bivalvesAtretaandSpondylusattached themselves in a preferred orientation (so-called slope orientation). This feature indicates the original position in which some mobile substrates were colonized. Other questions, such as the taphonomy of encrusters and the character of their substrates are also briefly discussed. 相似文献
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新元古代末期历经“雪球地球”和大气、海洋增氧事件后,发生了全球性成磷事件,贵州省震旦系陡山沱组大规模磷矿床沉积是本次成磷事件的典型代表。然而现阶段对贵州陡山沱组磷块岩成磷作用机制研究存在诸多争议,成磷事件与同期古海洋环境转变之间的关联研究也较为薄弱。作者以贵州省瓮安、遵义和丹寨地区陡山沱组原生磷块岩为研究对象开展的沉积学、岩石学、矿物学和地球化学特征研究表明: 陡山沱早期成磷作用被限制在浅水海岸,瓮安地区A矿层球粒磷块岩中大量的含铁自生矿物黄铁矿、海绿石以及无Ce负异常指示的贫氧沉积水体环境均表明,Fe-氧化还原泵成磷模式在富磷过程中发挥了重要作用;陡山沱晚期磷块岩分布扩散至较深水陆棚—斜坡沉积相区,磷块岩与富有机质岩层共生,矿物晶体形态特征与矿石内富含的大量生物化石均表明,有机质沉降聚磷作用和生物成磷作用促使磷块岩大量沉积,较明显的Ce负异常值也指示了海水氧气含量的提升。成磷作用模式的转变和磷块岩分布的扩展是对海洋增氧事件的沉积响应,同时造成的多细胞动物演化也影响了深部水体的氧化还原状态,进而反映了贵州省陡山沱组磷块岩大规模沉积与新元古代末期氧化事件(NOE)密切的耦合关系。 相似文献
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The Maltese archipelago and south‐eastern Sicily include an Uppermost Oligocene to Upper Miocene hemipelagic sedimentary succession representing the Malta‐Hyblean plateau, which limits the eastern Mediterranean to the west. This succession hosts a unique and well‐exposed series of condensed and allochthonous phosphate‐rich beds, which were formed in a sedimentary regime of erosion, sediment reworking and frequent gravity‐flow deposition. The combination of nannofossil biostratigraphy and 87Sr/86Sr isotope stratigraphy allows for the precise attribution of ages to the phosphate deposits and for the distinction of three periods of major phosphogenesis. The first phase occurred between 24·5 and 21 Ma and 25 and 18·9 Ma (clustering of ages between 25 and 22·5 Ma) on Malta and Sicily, respectively. The second and third phases of phosphogenesis are documented from the Maltese Islands and are dated as 17·2 to 13·1 Ma and 10·9 to 9·8 Ma, respectively. The phosphate‐rich beds are associated with hiatuses and phases of important condensation which, for the oldest phosphogenic period, envelop the time period of 23·2 to 22 Ma for the Fomm Ir Rhi Bay section (Malta) and from 19·1 to 16·3 Ma for the sections of Sampieri and Modica (Sicily). For the second phase of phosphogenesis on the Maltese Islands, a consistent hiatus was found which embraces the time period of approximately 17 to 15 Ma. Also the third phase of phosphogenesis appears to be associated with a major hiatus, which probably envelops the time period between 12·5 and 10·9 Ma, but a better age control is needed here. The correspondence in timing of the Maltese‐Sicilian phases of phosphogenesis with major phases of phosphogenesis outside the Mediterranean realm, to maxima in oceanic phosphorus‐burial rates and maxima in the δ13C benthic foraminiferal record suggests that the palaeoceanographic evolution of the eastern Mediterranean was well in phase with that of other ocean basins until at least the early Late Miocene, despite its increasing isolation due to the gradual closure of the Eurasian‐Arabian Strait and progressive sea‐level fall. 相似文献
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Phosphogenesis of phosphorite from the Sinian Doushantuo Formation in Guizhou Province and its coupling relation with the Neoproterozoic Oxygenation Event 
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下载免费PDF全文 Phosphate deposits of the Ediacaran Doushantuo Formation accumulated in the central Guizhou Province are the typical phosphate-rich sediments during the Neoproterozoic Phosphogenic Episodes,which occurred after the “Snowball Earth”period and Neoproterozoic Oxygenation Event. However,the mechanisms of phosphate enrichment in seawater have always been hotly debated,and the research for correlations between phosphogenesis and transition of Ediacaran palaeo-ocean environments is still unsubstantial. This study focused on the sedimentological,petrological,mineralogical and geochemical analyses on the Doushantuo pristine phosphorite in Weng'an,Zunyi and Danzhai area. Documented by spherulitic phosphorites in the Lower Phosphorite beds from Weng'an area that contain abundant autogenetic Fe-bearing minerals such as pyrite and glauconite and show weak Ce negative anomaly,Fe-redox pumping in low-oxygen environments are the important phosphogenesis mechanism but only limited in coastal waters in the Early Doushantuo Period. Phosphorite in the Upper Phosphorite beds deposited within organic-rich beds and contain massive biological fossils suggests that phosphogenesis might have been triggered by degradation of organic matter and biological action in the Late Doushantuo Period,and distribution of phosphatic sediments extended to the deeper shelf to slope setting. Obvious Ce negative anomaly implies the increase of oxygen content in seawater. The transition of phosphogenesis mechanisms and the expansion of phosphorite deposits are the sedimentary response of ocean oxygenation,and the associated evolution of metazoans also changed the redox conditions of the deep seawater. These sedimentary and geochemistry data reflect the closed coupling relation between Doushantuo phosphorite in Guizhou Province and the Neoproterozoic Oxygenation Event. 相似文献
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