Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers     

Chen Wang  Martin A. Briggs  Frederick D. Day-Lewis  Lee D. Slater 《水文研究》2021,35(5):e14184

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.  相似文献   

Spatial and temporal patterns of stable water isotopes along the Yangtze River during two drought years          下载免费PDF全文

Huawu Wu  Jing Li  Fan Song  Yanan Zhang  Haixia Zhang  Cicheng Zhang  Bin He 《水文研究》2018,32(1):4-16

Changes in the level of the Yangtze River caused by anthropogenic water regulation have major effects on the hydrological processes and water cycle in surrounding lakes and rivers. In this study, we obtained isotopic evidence of changes in the water cycle of Yangtze River during the two drought years of 2006 and 2013. Isotopic evidence demonstrated that the δ¹⁸O and δD levels in Yangtze River exhibited high spatial heterogeneity from the upper to lower reaches, which were controlled by atmospheric precipitation, tributary/lake water mixing, damming regulation, and water temperature. Both the slope and intercept of Yangtze River evaporative line (δD = 7.88 δ¹⁸O + 7.96) were slightly higher than those of local meteoric water line of Yangtze River catchment (δD = 7.41 δ¹⁸O + 6.01). Most of the river isotopic values were located below the local meteoric water line, thereby implying that the Yangtze River water experienced a certain degree of evaporative enrichment on isotopic compositions of river water. The high fluctuations in the isotopic composition (e.g., deuterium excess [d‐excess]) in the middle to lower reaches during the initial stage of operation for the Three Gorges Dams (2003–2006) were due to heterogeneous isotopic signatures from the upstream water. In contrast to the normal stage (after 2010) characterized by the maximum water level and largest water storage, a relatively small variability in the deuterium excess was found along the middle to lower reaches because of the homogenization of reservoir water with a longer residence time and complete mixing. The effects of water from lakes and tributaries on the isotopic compositions in mainstream water were highlighted because of the high contributions of lakes water (e.g., Dongting Lake and Poyang Lake) efflux to the Yangtze River mainstream, which ranged from 21% to 85% during 2006 and 2013. These findings suggest that the retention and regulation of the Three Gorges Dams has greatly buffered the isotopic variability of the water cycle in the Yangtze catchment, thereby improving our understanding of the complex lake–river interactions along the middle to lower reaches in the future.  相似文献   

Beaver dam analogues drive heterogeneous groundwater–surface water interactions     

Jeffrey Wade  Laura Lautz  Christa Kelleher  Philippe Vidon  Julianne Davis  Julio Beltran  Casey Pearce 《水文研究》2020,34(26):5340-5353

Beaver dam analogues (BDAs) are a cost-effective stream restoration approach that leverages the recognized environmental benefits of natural beaver dams on channel stability and local hydrology. Although natural beaver dams are known to exert considerable influence on the hydrologic conditions of a stream system by mediating geomorphic processes, nutrient cycling, and groundwater–surface water interactions, the impacts of beaver-derived restoration methods on groundwater–surface water exchange are poorly characterized. To address this deficit, we monitored hyporheic exchange fluxes and streambed porewater biogeochemistry across a sequence of BDAs installed along a central Wyoming stream during the summer of 2019. Streambed fluxes were quantified by heat tracing methods and vertical hydraulic gradients. Biogeochemical activity was evaluated using major ion porewater chemistry and principal component analysis. Vertical fluxes of approximately 1.0 m/day were observed around the BDAs, as was the development of spatially heterogeneous zones of nitrate production, groundwater upwelling, and anaerobic reduction. Strong contrasts in hyporheic zone processes were observed across BDAs of differing sizes. This suggests that structures may function with size-dependent behaviour, only altering groundwater–surface water interactions after a threshold hydraulic step height is exceeded. Patterns of hyporheic exchange and biogeochemical cycling around the studied BDAs resemble those around natural beaver dams, suggesting that BDAs may provide comparable benefits to channel complexity and near-stream function over a 1-year period.  相似文献   

Spectral analysis of continuous redox data reveals geochemical dynamics near the stream–aquifer interface     

Corey D. Wallace  Audrey H. Sawyer  Rebecca T. Barnes 《水文研究》2019,33(3):405-413

Changes in streamflow and water table elevation influence oxidation–reduction (redox) conditions near river–aquifer interfaces, with potentially important consequences for solute fluxes and biogeochemical reaction rates. Although continuous measurements of groundwater chemistry can be arduous, in situ sensors reveal chemistry dynamics across a wide range of timescales. We monitored redox potential in an aquifer adjacent to a tidal river and used spectral and wavelet analyses to link redox responses to hydrologic perturbations within the bed and banks. Storms perturb redox potential within both the bed and banks over timescales of days to weeks. Tides drive semidiurnal oscillations in redox potential within the streambed that are absent in the banks. Wavelet analysis shows that tidal redox oscillations in the bed are greatest during late summer (wavelet magnitude of 5.62 mV) when river stage fluctuations are on the order of 70 cm and microbial activity is relatively high. Tidal redox oscillations diminish during the winter (wavelet magnitude of 2.73 mV) when river stage fluctuations are smaller (on the order of 50 cm) and microbial activity is presumably low. Although traditional geochemical observations are often limited to summer baseflow conditions, in situ redox sensing provides continuous, high‐resolution chemical characterization of the subsurface, revealing transport and reaction processes across spatial and temporal scales in aquifers.  相似文献   

The role of antecedent groundwater heads in controlling transient aquifer storage and flood peak attenuation in karst watersheds     

Patricia Spellman  Jason Gulley  Jonathan B. Martin  Jeremy Loucks 《地球表面变化过程与地形》2019,44(1):77-87

Transient storage of floodwaters in aquifers is known to attenuate peak flows in rivers and drive subsurface dissolution. Transient aquifer storage could be enhanced in watersheds overlying karst aquifers where caves facilitate surface and groundwater exchange. Few studies, however, have examined controls on, or magnitudes of, transient aquifer storage or flood peak attenuation in karstic watersheds. Here we evaluate flood peak attenuation with multiple linear regression analyses of 10 years of river and groundwater data from the Suwannee River, which flows over the karstic upper Floridan aquifer in north-central Florida and experiences frequent flooding. Regressions show antecedent river stage exerts the dominant control on magnitudes of transient aquifer storage, with recharge and time to peak having secondary controls. Specifically, low antecedent stages result in larger magnitudes of transient aquifer storage and thus greater flood attenuation than conditions of elevated antecedent stage. These findings suggest subsurface weathering, including cave formation and enlargement, caused by transient aquifer storage could occur on a more frequent basis in aquifers where groundwater table elevation is lowered due to anthropogenic or climatic influences. Our work also shows that measures of groundwater table elevation prior to an event could be used to improve predictive flood models. © 2018 John Wiley & Sons, Ltd.  相似文献   

Characterizing hydrological processes within kettle holes using stable water isotopes in the Uckermark of northern Brandenburg,Germany     

Stuart Andrew Vyse  Majid Taie Semiromi  Gunnar Lischeid  Christoph Merz 《水文研究》2020,34(8):1868-1887

Understanding the hydrologic connectivity between kettle holes and shallow groundwater, particularly in reaction to the highly variable local meteorological conditions, is of paramount importance for tracing water in a hydro(geo)logically complex landscape and thus for integrated water resource management. This article is aimed at identifying the dominant hydrological processes affecting the kettle holes' water balance and their interactions with the shallow groundwater domain in the Uckermark region, located in the north-east of Germany. For this reason, based on the stable isotopes of oxygen (δ¹⁸O ) and hydrogen (δ²H ), an isotopic mass balance model was employed to compute the evaporative loss of water from the kettle holes from February to August 2017. Results demonstrated that shallow groundwater inflow may play the pivotal role in the processes taking part in the hydrology of the kettle holes in the Uckermark region. Based on the calculated evaporation/inflow (E/I) ratios, most of the kettle holes (86.7%) were ascertained to have a partially open, flow-through-dominated system. Moreover, we identified an inverse correlation between E/I ratios and the altitudes of the kettle holes. The same holds for electrical conductivity (EC) and the altitudes of the kettle holes. In accordance with the findings obtained from this study, a conceptual model explaining the interaction between the shallow groundwater and the kettle holes of Uckermark was developed. The model exhibited that across the highest altitudes, the recharge kettle holes are dominant, where a lower ratio of E/I and a lower EC was detected. By contrast, the lowest topographical depressions represent the discharge kettle holes, where a higher ratio of E/I and EC could be identified. The kettle holes existing in between were categorized as flow-through kettle holes through which the recharge takes place from one side and discharge from the other side.  相似文献   

Researching and Teaching the Anthropocene     

Kenneth R. Young 《Geographical review》2019,109(2):258-264

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Interannual and Decadal Changes in Tropospheric Ozone in China and the Associated Chemistry–Climate Interactions: A Review     

Yu FU  Hong LIAO  Yang YANG 《大气科学进展》2019,36(9):975-993

China has been experiencing widespread air pollution due to rapid industrialization and urbanization in recent decades.The two major concerns of ambient air quality in China are particulate matter(PM) and tropospheric ozone(O_3). With the implementation of air pollution prevention and control actions in the last five years, the PM pollution in China has been substantially reduced. In contrast, under the conditions of the urban air pollution complex, the elevated O_3 levels in city clusters of eastern China, especially in warm seasons, have drawn increasing attention. Emissions of air pollutants and their precursors not only contribute to regional air quality, but also alter climate. Climate change in turn can change chemical processes, long-range transport, and local meteorology that influence air pollution. Compared to PM, less is known about O_3 pollution and its climate effects over China. Here, we present a review of the main findings from the literature over the period 2011–18 with regard to the characteristics of O_3 concentrations in China and the mechanisms that drive its interannual to decadal variations, aiming to identify robust conclusions that may guide decision-making for emissions control and to highlight critical knowledge gaps. We also review regional and global modeling studies that have investigated the impacts of tropospheric O_3 on climate, as well as the projections of future tropospheric O_3 owing to climate and/or emission changes.  相似文献   

Mediterranean cities under fire. A critical approach to the wildland–urban interface     

《Applied geography (Sevenoaks, England)》2015

Wildfires are widely reviewed as key inputs to Mediterranean ecosystems. However, research is often flawed by major biases. (1) The approach adopted by most planners focusing on forest fires dismisses the human dimension of fire as a component of agricultural production systems. (2) The Wildland–Urban Interface (WUI) concept postulates that cities and wildlands/wildfires are, and should remain, worlds apart, a statement whose truth is increasingly questioned by recent disastrous “urban wildfires”. (3) The Mediterranean Basin as a fire-prone area is all the more fantasized, as it is almost never studied as a whole.The present paper takes a critical view of city–wildland/wildfire interrelationships through a large-scale study of the Mediterranean Basin based on MODIS MCD12Q1 (Land Cover Type) and MCD45A1 (Burned Area Product) data collected between 2001 and 2013. The Mediterranean is an ideal place to investigate, as its human-dominated and urbanized landscapes are known to be extremely vulnerable to fire hazards. Data processing reveals that (wild)fires and cities maintain indissoluble ties, as if both elements could not be considered mutually exclusive on a geographical basis. Urban sprawl, reduced rural autonomies, changes in forest covers, old agricultural practices, and military conflicts provide the framework for an extended mitigation process challenging the WUI concept as a space divider.  相似文献   

基于人地关系的旅游地理学理论透视与学术创新   总被引：13，自引：6，他引：7  

黄震方  黄睿 《地理研究》2015,34(1):15-26

针对旅游地理学理论研究比较薄弱和研究内容相对泛化的现状,提出将旅游人地关系作为旅游地理学研究的核心,阐述了旅游人地关系的理论内涵,认为旅游地理学是研究地球表层人类旅游活动与地理环境关系并服务于人类生活和社会经济发展的一门科学,其研究对象是"旅游地域系统"。基于人地关系的理论视角,按照旅游地理学理论体系化和科学化的发展要求,充分考虑旅游地理学旅游性、区域性、综合性和应用性的学科属性,初步构建了以旅游活动系统和地理环境系统为基础,以人地关系理论为核心,融合相关学科理论的旅游地理学理论框架。论文还梳理了旅游地理学的基本研究内容、主要科学问题和重要研究方法,强调应大力倡导地理学科学精神,改变低水平应用导向和过于偏重技术导向的研究现状,切实运用旅游地理学研究和解决国家与地方旅游发展中的重要现实问题,并在此基础上强化理论导向的思想型研究,将深刻揭示旅游人地关系地域系统的基本特征、功能结构、时空演化、基本规律、动力机制和调控途径作为旅游地理学研究的重点,通过学科特色创新、研究范式创新、理论成果创新、研究方法创新和应用价值创新,推动旅游地理学理论研究的深化、学术水平的提高和学科体系的完善,促进现代旅游地理学的本土化和中国旅游地理研究的国际化。  相似文献