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Consequences of anthropogenic activity for two remote alpine lakes in NW Slovenia as tracked by sediment geochemistry
Authors:Gregor Muri  Branko Čermelj  Radojko Jaćimović  Dragomir Skaberne  Andrej Šmuc  Martina Burnik Šturm  Janja Turšič  Polona Vreča
Institution:1. Slovenian Environment Agency, Vojkova 1b, 1000, Ljubljana, Slovenia
6. Institute of Public Health Kranj, Gosposvetska 12, 4000, Kranj, Slovenia
2. Marine Biology Station, National Institute of Biology, Forna?e 41, 6330, Piran, Slovenia
3. Jo?ef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia
4. Geological Survey of Slovenia, Dimi?eva 14, 1000, Ljubljana, Slovenia
5. Department of Geology, Faculty of Natural Sciences and Engineering, University of Ljubljana, A?ker?eva 12, 1000, Ljubljana, Slovenia
7. Research Institute of Wildlife Ecology, University of Veterinary Medicine Vienna, Savoyenstra?e 1, 1160, Vienna, Austria
Abstract:Several geological and geochemical parameters were determined in the sediments of the 5th (5 J) and 6th (6 J) Triglav Lakes, Julian Alps (NW Slovenia), in order to study the impact of natural catchment characteristics and anthropogenic activity. Fish were introduced into both lakes in 1991 and a mountain hut lies on the shore of 5 J. Sedimentary grain size (GS) was distinctly coarser in 5 J than 6 J, with arithmetic means ranging between 46 and 60 and 23–36 μm, respectively. In contrast, the mineralogical composition of the two sediments was similar. Calcite predominated strongly, comprising more than 77 % of total minerals, while dolomite and quartz were rare. Organic carbon (OC) and total nitrogen (TN) concentrations were highest in surficial sediments, with levels of 14.4 and 1.8 %, and 19.3 and 2.4 % observed in 5 J and 6 J, respectively. C/N ratios (atomic) were lowest in the same surface sediments, with the two lakes characterized by similar values (9.6 vs. 9.4, respectively), suggesting a predominance of autochthonous organic matter (OM) in both lakes. Contemporary δ13C values were lower in 5 J (?21.0 ‰) than 6 J (?18.5 ‰) sediments. Considerable changes in these four parameters were observed in recently deposited material, reflecting a shift in the trophic status of both lakes that was likely induced by the introduction of fish. In addition, the smaller and shallower 6 J seemed to respond to changes faster than the larger and deeper 5 J, indicating the higher sensitivity of the former. δ15N values in surface sediments of 5 J and 6 J were ?2.9 and ?4.4 ‰, respectively, with levels increasing gradually with depth to approximately +1.0 ‰ in deeper sediments. The observed changes could most likely be attributed to the atmospheric deposition of reactive nitrogen. The mountain hut has seemingly not had a significant enough impact on the lakes to be recorded in their sediments.
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