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Indications of fluid immiscibility in glass from West Clearwater Lake impact crater,Quebec, Canada |
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| Authors: | M R Dence W von Engelhardt A G Plant L S Walter |
| Institution: | 1. Gravity Division, Earth Physics Branch, Department of Energy, Mines & Resources Ottawa, K1A OE4, Ontario, Canada 2. Mineralogisch-Petrographisches Institut der Universit?t Tübingen, 74 Tübingen, Germany 3. Geological Survey of Canada, K1A OE8, Ottawa, Ontario, Canada 4. Laboratory for Meteorology and Earth Sciences, NASA Goddard Space Flight Center, 20771, Greenbelt, Maryland, USA |
| Abstract: | Glass from the West Clearwater Lake hypervelocity impact crater contains numerous spheroids, 10 to 500 μm across, which appear to have formed at high temperatures as fluids immiscible in the enclosing melt. The spheroids are distinguished from small, normal, largely void gas vesicles, which are also present, by being completely filled in all cases; by having fillings which vary in composition from spheroid to spheroid, even between spheroids in close association; and by indications that the present fillings are representative of the contents present before the matrix melt chilled. Most of the spheroids are classified petrographically into three types. Type I, the most numerous, includes all spheroids>100 μm and are filled with uncommon pale brown to yellow montmorillonites with an unusual structure intermediate between dioctahedral montmorillonite and saponite. Type II, brown and green, are filled with Fe-rich montmorillonites, while Type III are aluminia-rich montmorillonites crystallized into mica-like sheaves. Rare, small spheroids are filled with calcite or silica. In a few cases one spheroid encloses another of similar or different type. Electron microprobe analyses indicate that with few exceptions Types I and III spheroids belong to a Mg series of montmorillonites in which the main chemical variation is the substitution of Mg for Al. A second Fe-K series includes Type II and a few Type I spheroids and shows substitution of Fe by Al, relatively high K2O and, in the alumina-rich members, low SiO2. The close association of spheroids with deformed, embayed lechatelierite inclusions indicates that they formed while the latter were liquid, i.e. at temperatures above 1700°C, as rapidly moving impact melt engulfed highly shocked inclusions of quartz-bearing country rock. The preservation of spheroids in the West Clearwater Lake glass is attributed mainly to the position of the glass masses within the breccias lining the crater floor. It is considered that the glass in this location did not achieve free flight but, as part of a large mass, cooled relatively slowly through the high temperature regime in which the spheroids were generated, and then, when detached, chilled rapidly to preserve a record of this transient stage in their history. |
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