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Hydrogeology and hydrogeochemistry at a site of strategic importance: the Pareja Limno-reservoir drainage basin (Guadalajara,central Spain)
Authors:Eugenio Molina-Navarro  Antonio Sastre-Merlín  Rosa Vicente  Silvia Martínez-Pérez
Institution:1. Department of Geology, Geography and Environment, University of Alcalá, Ctra. Madrid-Barcelona km. 33.6, C.P. 28871, Alcalá de Henares, Madrid, Spain
Abstract:A small calcareous basin in central Spain was studied to establish the role of groundwater in the Pareja Limno-reservoir. Limno-reservoirs aim to preserve a constant water level in the riverine zone of large reservoirs to mitigate the impacts arising from their construction. Groundwater flow contribution (mean 60 %) was derived by recharge estimation. In situ measurements (spring discharge, electrical conductivity and sulfate) were undertaken and spring discharge was compared with a drought index. Twenty-eight springs were monitored and three hydrogeological units (HGUs) were defined: a carbonate plateau (HGU1), the underlying aquitard (HGU2), and the gypsum-enriched HGU3. HGU1 is the main aquifer and may play a role in the preservation of the limno-reservoir water level. Hydrogeochemical sampling was conducted and the code PHREEQC used to describe the main geochemical processes. Weathering and dissolution of calcite and gypsum seem to control the hydrogeochemical processes in the basin. Water progresses from Ca2+–HCO3 in the upper basin to Ca2+–SO4 2– in the lower basin, where HGU3 outcrops. A clear temporal pattern was observed in the limno-reservoir, with salinity decreasing in winter and increasing in summer. This variation was wider at the river outlet, but the mixing of the river discharge with limno-reservoir water buffered it.
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