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Geochemical behavior of uranium in soils,part II. Distribution of uranium in hydromorphic soils and soil sequences. Applications for surficial prospecting
Institution:1. School of Sciences and Resources, China University of Geosciences, Beijing 100083, PR China;2. Key Laboratory of Ecological Geochemistry, Ministry of Land and Resources, Beijing 100037, PR China;3. Ningxia Institute of Land Resources Survey and Monitor, Yinchuan 750004, PR China;1. University of Trás-os-Montes e Alto Douro, UTAD, School of Life Sciences and the Environment, Quinta de Prados, 5000-801 Vila Real, Portugal;2. MARE, Marine and Environmental Sciences Centre, Faculty of Sciences and Technology, University of Coimbra, 3004-517 Coimbra, Portugal;3. University of Coimbra, Faculty of Sciences and Technology, Department of Earth Sciences, 3001-401 Coimbra, Portugal;4. Instituto de Geologia e Petróleo de Timor Leste, Timor-Leste;5. University of Calcutta, Department of Marine Science, 35, Ballygunge Circular Road, Calcutta 700019, West Bengal, India;6. Periyar University, Department of Biotechnology, Salem 636 011, TN, India
Abstract:The vertical distribution of U in hydromorphic soils is not related to climatic conditions and weathering rates but it depends essentially on local factors, i.e. water-table characteristics and topography.While topography may permit the transfer of uranyl species on a large scale, the water table induces specific conditions of redox potential involving two major processes for U fixation: retention with organic components in reduced layers and fixation on amorphous oxyhydroxides in oxidized layers.The analysis of four soil sequences of the temperate zone (France) show that the topography modifies the typical distribution pattern of U. Thus, depletion of U is limited in aerated soils situated on a slope, compared to their analogues located in plains, and enrichment of U is observed in hydromorphic soils, located down this slope.From this study, it is clear that U distribution in soils is related to pedogenetic processes and that soil analysis for U may be successful in evaluating the U content of underlying rock. Therefore some applications for the geochemical prospecting of U from soils are developed.
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