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Flocculation of heavy metals during mixing of freshwater with Caspian Sea water
Authors:A R Karbassi  J Nouri  N Mehrdadi  G O Ayaz
Institution:(1) Graduate Faculty of the Environment, University of Tehran, P.O. Box 14155-6135, Tehran, Iran;(2) Department of Environmental Health Engineering and Center for Environmental Research, Medical Sciences/University of Tehran, Tehran, Iran;(3) Department of Environmental Science, Graduate School of the Environment and Energy, Science and Research Campus, IAU, Tehran, Iran
Abstract:Flocculation of colloidal size fraction for Cu, Zn, Pb, Ni and Mn was investigated on a series of mixtures with water salinities ranging from 1.5 to 9.5‰ during mixing of Haraz River with the Caspian Sea water. The flocculation trend of Zn (85.5%) > Mn (55.2%) > Cu (39.6%) > Pb (33.7%) > Ni (11.3%) indicates that Cu, Zn, Pb and Mn have non-conservative behavior and Ni has relatively conservative behavior during estuarine mixing. Highest flocculation of heavy metals occurs between salinities of 1.5 and 4.5‰. Statistical analysis indicates that the flocculation of Cu, Zn and Ni is governed by pH and total nitrogen.
Keywords:Flocculation  Heavy metals  Saline water  Estuary  Caspian Sea
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