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Effects of P, f(O2) and Mg/Fe Ratio on Dehydration Melting of Model Metagreywackes
Authors:PATINO DOUCE  ALBERTO E; BEARD  JAMES S
Institution:1DEPARTMENT OF GEOLOGY, UNIVERSITY OF GEORGIA ATHENS, GA 30602, USA
2VIRGINIA MUSEUM OF NATURAL HISTORY MARTINSVILLE, VA 24112, USA
Abstract:We present results of dehydration melting experiments 3–15kbar, 810–950C f(O2) ≤ QFM (quartz-fayalite-magetite)and ≥ Ni-NiO] on two Fe-rich mixtures of biotite (37%), plagioclaseAn38 (27%), quartz (34%) and ilmenite (2%), which differ onlyin their biotite compositions (mg-number 23 and 0.4). Dehydrationmelting of metagreywackes of constant modal composition generatesa wide range of melt fractions, melt compositions and residualassemblages, through the combined effects of pressure, Fe/Mgratio and f(O2). Crystallization of garnet is the chief controlon melting behavior, and is limited by two reactions: (1) thebreakdown of garnet + quartz to orthopyroxene + plagioclaseat low P, and (2) the oxidation of garnet to magnetite + anorthite+ quartz (enstatite), which is sensitive to both f(O2) andP. Because of these reactions, melting of Mg-rich metagreywackesis rather insensitive to f(O2) but strongly sensitive to P;the converse is true for Fe-rich metagreywackes. Garnet crystallizationrequires that plagioclase break down incongruently, liberatingalbite. This increases the Na2O content of the melts and enhancesmelt production. Thus, melting of metagreywacke in a reducingdeep-crustal environment (with garnet stable) would producemore, and more sodic, melt than would garnet-absent meltingof the same source material in a relatively oxidizing, shallow-crustalenvironment. KEY WORDS: anatexis; metasediments; gneisses; granites; garnet *Corresponding author. Telephone: 706-542-2394; fax: 706-542-2425; e-mail: alpatino{at}uga.cc.uga.edu
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