Acidification and sediment aluminium: palaeolimnological interpretation |
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| Authors: | John F Boyle |
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| Institution: | (1) Dept. of Geography, University of Liverpool, PO Box 147, L69 3BX Liverpool, UK |
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| Abstract: | A study of acid-labile (A-L) aluminium in modern surface sediments and cores from lakes in Norway, shows surface depletions indicating sharply reduced retention of aluminium where lake pH is below 4.8–5.0. This result complements previous palaeolimnological studies of acid-labile sediment aluminium (A-L aluminium) in acidified lakes, which have focused on up-core concentration increases attributed to enhanced supply of catchment derived aluminium.The surface sediments, while showing great inter-site variation, have on average lower concentrations of A-L aluminium at acidic sites. Further, for lakes with pH<5.0, there is a significant positive correlation of A-L aluminium with pH. The palaeolimnological data show reduced A-L aluminium concentration where diatom inferred pH is below about 4.8–5.0.Because there are both positive and negative effects of acidification, variation in A-L aluminium concentration in cores reveals more information about acidification than was previously supposed. In addition to indicating the time of enhancement of catchment aluminium supply, evidence of whether (and if so when) the water pH fell below 4.9 is also indicated. |
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