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Carbon-isotope records of the Early Jurassic (Toarcian) oceanic anoxic event from the Valdorbia (Umbria–Marche Apennines) and Monte Mangart (Julian Alps) sections: palaeoceanographic and stratigraphic implications
Authors:NADIA SABATINO  RODOLFO NERI  ADRIANA BELLANCA  HUGH C JENKYNS†  FRANÇOIS BAUDIN‡  GUIDO PARISI§  DANIELE MASETTI¶
Institution:Dipartimento di Chimica e Fisica della Terra (CFTA), Universitàdi Palermo, Via Archirafi 36, 90123 Palermo, Italy (E-mail: );
Department of Earth Sciences, University of Oxford, Parks Road, Oxford OX1 3PR, UK;
Département de Géologie Sédimentaire et CNRS-UMR 7072, UniversitéPierre et Marie Curie-Paris 6, 4 place Jussieu, 75252 Paris Cedex 05, France;
Dipartimento di Scienze della Terra, Universitàdi Perugia, Piazza Università, 06100 Perugia, Italy;
Dipartimento di Scienze della Terra, Universitàdi Ferrara, Via Saragat 1, 44100, Ferrara, Italy
Associate Editor: Adrian Immenhauser
Abstract:The Toarcian oceanic anoxic event ( ca 183 Ma) coincides with a global perturbation marked by enhanced organic carbon burial and a general decrease in calcium carbonate production, probably triggered by changes in the composition of marine plankton and elevated carbon dioxide levels in the atmosphere. This study is based on high-resolution sampling of two stratigraphic successions, located in Valdorbia (Umbria–Marche Apennines) and Monte Mangart (Julian Alps), Italy, which represent expressions of the Toarcian oceanic anoxic event in deep-water pelagic sediments. These successions are characterized by the occurrence of black shales showing relatively low total organic carbon concentrations (compared with coeval strata in Northern Europe), generally < 2%, and low hydrogen indices. On this basis, they are similar to other Toarcian black shales described from the Tethyan region. The positive and negative carbon-isotope records from the two localities permit a high-resolution correlation such that ammonite biostratigraphy information from Valdorbia can be transferred to those parts of the Monte Mangart section that lack these fossils. Spectral analyses of δ13Corg values and of CaCO3 percentages from the sedimentary records of both the Valdorbia and Monte Mangart sections reveal a strong cyclic pattern, best interpreted as an eccentricity signal which hence implies a duration of ca 500 kyr for the negative carbon-isotope excursion. Based on the carbon-isotope curves obtained, the high-resolution correlation between the Italian successions and a section in Yorkshire (Northern Europe) confirms the supposition that the apparent mismatch between the dating of the Toarcian oceanic anoxic event in the Boreal and Tethyan realms is an artefact of biostratigraphy.
Keywords:Carbon isotopes  cyclostratigraphy  Early Jurassic  oceanic anoxic event  stratigraphic correlation
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