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白水黄土-红粘土化学风化强度的剖面特征与粒度效应
引用本文:熊尚发,朱园健,周茹,卢海建,丁仲礼.白水黄土-红粘土化学风化强度的剖面特征与粒度效应[J].第四纪研究,2008,28(5):812-821.
作者姓名:熊尚发  朱园健  周茹  卢海建  丁仲礼
作者单位:1. 中国科学院地质与地球物理研究所新生代地质与环境重点实验室,北京,100029
2. 中国科学院地质与地球物理研究所新生代地质与环境重点实验室,北京,100029;中国科学院研究生院,北京,100049
基金项目:国家自然科学基金项目(批准号:40672117);中国科学院知识创新工程重要方向项目(批准号:KZCX2-YW-130)资助
摘    要:白水剖面黄土-红粘土全样化学分析表明,以CIA指数为代表的化学风化强度从剖面下部往上逐步变弱,波动增大,总体趋势与深海氧同位素代表的全球冰量变化可以很好对比。分粒级组分化学分析则显示,黄土-红粘土主要元素迁移及化学风化强度与粒度强烈相关,CIA指数表征的化学风化强度变化在相当程度上受到粒度变化的控制。总体上,黄土-红粘土各粒级颗粒的风化程度都不高,而且沉积之后的成土风化作用对其主要元素含量的影响有限,黄土-红粘土化学成分的长期变化趋势主要受到物源的新加入和混合过程的影响。从剖面变化看,粗粒级部分(5~20μm和20~63μm)的风化指数的变化特征与细粒级部分(<5μm)不完全相同,表明不同粒级组分接受化学风化以及在物源区停留的历史不尽相同。1Ma以来,各粒级CIA指数都整体降低,显示物源区新鲜、弱风化碎屑影响到各粒级颗粒的混合过程。进一步对细粒级部分(<5μm)化学成分演化进行的分析显示,其元素含量呈现不同组分递次变化的"序列模式",从红粘土下部(约4.5Ma)到黄土上部(约0.6Ma),K2O/Al2O3,Na2O/Al2O3,CaO/Al2O3和MgO/Al2O3比率的变化依次出现转折,这很可能与晚新生代黄土-红粘土物源区构造抬升、冰川剥蚀能力不断加大,使得新鲜基岩不断被剥蚀、去顶,由此造成主要造岩矿物顺序剥蚀、接受风化,成为粉尘新物源有关。

关 键 词:黄土-红粘土  化学风化  CIA  粒度效应
收稿时间:2008-02-11
修稿时间:2008-04-12

CHEMICAL WEATHERING INTENSITY AND ITS GRAIN-SIZE DEPENDENCE FOR THE LOESS-RED CLAY DEPOSIT OF THE BAISHUI SECTION,CHINESE LOESS PLATEAU
Xiong Shangfa,Zhu Yuanjian,Zhou Ru,Lu Haijian,Ding Zhongli.CHEMICAL WEATHERING INTENSITY AND ITS GRAIN-SIZE DEPENDENCE FOR THE LOESS-RED CLAY DEPOSIT OF THE BAISHUI SECTION,CHINESE LOESS PLATEAU[J].Quaternary Sciences,2008,28(5):812-821.
Authors:Xiong Shangfa  Zhu Yuanjian  Zhou Ru  Lu Haijian  Ding Zhongli
Institution:1. Key Laboratory of Cenozoic Geology and Environment, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049
Abstract:Chemical(major element)analyses of the Baishui loess-red clay sequence(35° 24'10″N,106°54'43″E,Gansu Province,China)reveal that,the chemical weathering intensities inferred from CIA(chemical index of alteration)value have undergone a progressively upward weakening with amplifying magnitudes of fluctuation,and the general trend of CIA can be correlated well with oxygen isotope variations of deep sea sediments.Analyses on size-fractions(<5μm,5~20μm,and 20~63μm)of the samples indicate that CIA and the major element abundances are of strongly grain-size dependence.It is estimated that the chemical alternations on all the three size fractions are relatively weak,and the long-term variation in chemical composition of the loess-red clay is mainly controlled by the input of fresh detritus and mixing process with different sources of deposits.Variation patterns of CIA for the coarse fractions(5~20μm and 20~63μm)along the section is apparently different from that for the fine fraction(<5μm),implying different histories through erosion-transportation-deposition-weathering processes.From 1Ma onward,CIA values for each size fraction of the samples have all decreased,indicating an increasing input of fresh or poorly weathered detritus into the source regions of loess deposits.Further analyses on the fine fraction(<5μm)display a pattern of sequential variations in K2O/Al2O3,Na2O/Al2O3,CaO/Al2O3,and MgO/Al2O3 ratios from 4.5Ma to about 0.6Ma,probably reflecting a progressively strengthened erosion with new crustal addition,due to progressive unproofing in the uplifted source regions and increasing glaciations associated with the Late Cenozoic global cooling.
Keywords:loess-red clay  chemical weathering  CIA  grain-size effect
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