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Zoned Pyroxenes from Shoshonite Lavas of Lesbos, Greece: Inferences concerning Shoshonite Petrogenesis
Authors:PE-PIPER  GEORGIA
Institution:Department of Geology, Saint Mary's University Halifax, N.S., B3H 3C3, Canada
Abstract:Samples from several stratigraphic levels in the Miocene volcanicsuccession on Lesbos, Greece, contain complexly zoned clinopyroxeneand feldspar phenocrysts. Electron microprobe analyses havebeen made of zoned clinopyroxenes and feldspars, and their inclusions;and phenocryst mineralogy is compared with host-rock chemicalcomposition. The commonest pyroxene zoning sequence is coresof greenish salite or augite mantled by diopside which, in turn,may be rimmed by augite, with each type of pyroxene in opticaland chemical discontinuity with the next. None of the pyroxeneshas high pressure characteristics. The Ts content of phenocrystcores is correlated with the K-content of the host rock; andthe most diopsidic overgrowths also occur in the most K-richrocks. Augite rims occur only in Al-rich rocks. Most of the features of the pyroxenes can be accounted for bya hypothetical fractional crystallization scheme. However, twoobservations suggest that mixing of small magma batches mayalso be important. The earliest crystallized diopsides thatrim salite are rich in Cr2O3, suggesting precipitation froman unfractionated magma. Anorthoclase (implying advanced crystallizationof feldspars) occurs as cores to feldspar phenocrysts and asinclusions in clinopyroxene cores in several samples.
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