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Chlorite-illite/muscovite interlayered and interstratified crystals: A TEM/STEM study
Authors:Jung Hoo Lee  Donald R Peacor  Daniel D Lewis  Robert P Wintsch
Institution:(1) Department of Geological Sciences, The University of Michigan, 48109 Ann Arbor, Michigan, USA;(2) Department of Geology, Indiana University, 47405 Bloomington, Indiana, USA;(3) Present address: Exon Company USA, P.O. Box 120, 80201 Denver, Colorado, USA
Abstract:Phyllosilicates in rocks which are transitional from mudstone to slate from Lehigh Gap, Pa., have been studied by a variety of techniques, including high resolution Transmission Electron Microscopy and Analytical Electron Microscopy. The principal minerals are ldquowhite micardquo which is transitional from illite in mudstone to ordered twolayer mica in slate, and chlorite. 7Å berthierine occurs more rarely. Dioctahedral and trioctahedral layers are shown to be interleaved in individual crystals at all scales between the following two end members: (1) both random and regular 1ratio1 interlayering at the scale of individual layers, as shown, in part, by lattice fringe images. (2) packets of trioctahedral and dioctahedral layers up to a few thousand Ångstroms or microns in thickness, detectable with ordinary optical techniques. The complete range of intermediate structures is represented in samples which are in transition to slate. Bulk analytical (EMPA), X-ray diffraction or other measurements are shown to result in averages over both kinds of layers when TEM techniques are not used.Contribution No. 400 from the Mineralogical Laboratory, Department of Geological Sciences, The University of Michigan
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