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CCL吸附特性及孔隙率降低对污染物运移的影响
引用本文:张金利,栾茂田,杨庆.CCL吸附特性及孔隙率降低对污染物运移的影响[J].岩土力学,2008,29(5):1181-1187.
作者姓名:张金利  栾茂田  杨庆
作者单位:大连理工大学 海岸和近海工程国家重点实验室/土木水利学院岩土工程研究所,大连 116024
基金项目:国家自然科学基金 , 中国科学院武汉岩土力学研究所湖北省环境岩土工程重点实验室开放课题
摘    要:假定孔隙均匀地分布于土体的物质空间内和土骨架对污染物的吸附特性服从平衡线性,对基本体积质量关系进行分析,提出了由于土体对污染物的吸附而引起的孔隙率降低的估算公式。在考虑土体孔隙率变化的条件下,建立了污染物一维运移的控制方程,并考虑垃圾生物降解效应、压实黏土衬里(CCL)防渗层、下覆有限厚度含水层等实际情况,确定了初始条件和边界条件。对所建立的初边值问题进行了数值求解,且对某假想填埋场情况进行了变动参数与对比计算,结果表明,由于土颗粒对污染物的吸附所引起的孔隙率降低,显著地降低了污染物对压实黏土衬里的穿透能力。与常孔隙率情况相比,CCL中污染物的峰值浓度降低近10 %,含水层中污染物浓度降低更显著。当考虑土体孔隙率变化时,弥散对污染物运移具有控制作用,分布系数对污染物的运移具有重要影响。

关 键 词:孔隙率计算公式  压实黏土衬里(CCL)  含水层  污染物  穿透能力  
文章编号:1000-7598-(2008)05-1181-07
收稿时间:2006-07-16
修稿时间:2006年7月16日

Numerical analysis of one-dimensional contaminant transport considering linear sorption behaviour and variable porosity of compacted clay liner
ZHANG Jin-li,LUAN Mao-tian,YANG Qing.Numerical analysis of one-dimensional contaminant transport considering linear sorption behaviour and variable porosity of compacted clay liner[J].Rock and Soil Mechanics,2008,29(5):1181-1187.
Authors:ZHANG Jin-li  LUAN Mao-tian  YANG Qing
Institution:State Key Laboratory of Coastal and Offshore Engineering, Institute of Geotechnical Engineering, School of Civil and Hydraulic Engineering, Dalian University of Technology, Dalian 116024, China)
Abstract:It is assumed that voids are uniformly distributed in the substance space occupied by soils and the sorption of soil skeleton onto the contaminants behaves equilibrium and linear feature. Based on the analysis of basic interrelationship between volume and mass, an empirical formula is presented for evaluating the change of the porosity induced by sorption of soil skeleton. Under the condition of variable porosity, the governing equation for describing one-dimensional contaminant migration is established; and the initial conditions and boundary conditions are formulated for actual conditions including landfill profile, waste degradation and compacted clay liner (CCL) of finite depth in practice. The resulting initial boundary-values issue is numerically solved. Through parametric computations and comparative analyses, it is shown that the reduction of soil porosity induced by sorption of soil skeleton will decrease the breakthrough potential of contaminants into compacted clay liners. Compared with the case of constant porosity, the peak of concentration of contaminant transport in CCL will be reduced 10 % when the variable porosity due to sorption is considered. When the variable effect of soil porosity is taken into account, dispersion mechanism play a controlling role in the contaminant transport and the effect of the distribution coefficient in the sorption equation on contaminant migration is appreciable.
Keywords:approximate formula of sorption-induced porosity reduction  compacted clay liner(CCL)  aquifer  contaminant  breakthrough capacity  
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