Controversial Pb-Pb and Sm-Nd isotope results in the early Archean Isua (West Greenland) oxide iron formation: preservation of primary signatures versus secondary disturbances |
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| Institution: | 1. CAS Key Laboratory of Crust–Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China;2. School of Earth Sciences and Resources, China University of Geosciences, 29 Xueyuan Road, Beijing 100083, China;3. Division of Interdisciplinary Science, Faculty of Science, Kochi University, Kochi 780-8520, Japan;4. Facheinheit Mineralogie, Johann Wolfgang Goethe-Universität, 60438 Frankfurt Am Main, Germany |
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| Abstract: | Pb stepwise leaching (PbSL) determinations on two magnetite-enriched fractions of a BIF sample from the northeastern part of the Isua supracrustal belt (West Greenland) yield an isochron of 3691 ± 22 Ma (MSWD = 0.4). In combination with previously published geochronological constraints for a minimum deposition age of ～3.71 Ga for volcanic sequences (Nutman et al., 1997) comprising the studied BIFs, and supported by microtextural observations, this demonstrates an early Archean amphibolite facies metamorphic event in the supracrustal. PbSL data on magnetite from slightly discordant veins within the same iron stone, together with bulk Pb isotope values of paragenetically late pyrite, yield a 3.63 ± 0.07 Ga (MSWD = 8.6) errorchron, with significantly different Pb isotopic compositions from those obtained from the main magnetite layers, and this suggests that the discordant layers of magnetite and sulfides crystallized when externally derived fluids passed through the formation a few tens of million of years later. The fluids controlling this redistribution of magnetite can be tentatively correlated with metasomatic alteration features produced during the widespread intrusion of 3.6 Ga granitic into 3.7 Ga tonalitic Am??tsoq gneisses enclosing the belt. Tremolite-rich layers in the BIF are characterized by Sm/Nd ratios close to chondritic εNd(3800) of +1.7 and +2.1], within error of published results from adjacent basic units in the supracrustal suite. In contrast, the magnetite-dominated layers yield unrealistically high εNd(3800) of +14.8 and +14.4, indicative of Sm/Nd ratios resembling REE fractionated, continental sources. These high εNd(3800), together with radiogenic Sr leached from the magnetite-enriched separates, is ascribed to secondary hydroxyapatite, which predominantly forms as crystal overgrowths in the magnetite-rich bands. The timing of the hydrothermal event during which apatite was deposited within the BIF remains uncertain, but a TCHUR model age of 1.85 Ga from the apatite-dominated HCl leachate may point to a close genetic relationship with local Proterozoic metamorphism and granite formation by crustal remelting in the Isukasia area.Step leaching of magnetite from a similar silicate-oxide facies BIF from the western part of the Isua supracrustal belt yield a Pb-Pb isochron age of 2.84 ± 0.05 Ga (MSWD = 1.43). The agreement between the PbSL age and previously published field and isotopic evidence for a major late Archean metamorphic event affecting the western area suggests there was widespread equilibration accompanying the intrusion of the 2.75–2.83 Ga granodioritic Ikkattoq gneisses west and southwest of the western limb of the Isua supracrustal belt.We argue that the PbSL isochron ages date the peak of amphibolite facies metamorphic events which, respectively, affected the eastern and western sections of the Isua supracrustal belt during the early and late Archean. Our results give additional support to the suggestion that the scatter on published εNd(T) values from the Isua supracrustal belt and adjoining gneisses can be assigned to post-formational hydrothermal processes and underline the need for care in the interpretation of Sm-Nd bulk data from polymetamorphic rocks to constrain isotopic models of early Earth’s evolution. |
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