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Fractal-like adsorption kinetics of Pb^2+ in rocks
作者单位:XU Longjun1,ZHOU Zhengguo1,LIU Chenglun1,2,and XIAN Xuefu1 1 Key Laboratory for the Exploitation of Southwestern Resources and Environmental Disaster Control Engineering of Ministry of Education,Chongqing University,Chongqing 400044,China 2 College of Chemistry and Chemical Engineering,Chongqing University,400044,China
摘    要:The adsorption kinetics of Pb^2+ in rocks has been studied using ion selective electrodes and atomic absorption spectrophotometer. The results showed that the adsorption process is a fractal-like reaction. The adsorption rate was relatively high before 30 minutes, and then dropped. The saturated adsorption capacity (a) of Pb^2+ and kinetic parameters (b, a, D and k) increased with increasing initial concentrations of Pb^2+. These parameters (except a) decreased while Na^+ was present in the solution. Furthermore, the smaller the rocks were in grain size, the bigger these kinetic parameters would be, though the parameter a was almost constant.

关 键 词:动力学  吸附作用  角砾岩  砂岩
收稿时间:20 February 2008
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